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  • The Electrochemical Society  (9)
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  • The Electrochemical Society  (9)
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  • 1
    Online Resource
    Online Resource
    The Electrochemical Society ; 2014
    In:  ECS Meeting Abstracts Vol. MA2014-01, No. 39 ( 2014-04-01), p. 1455-1455
    In: ECS Meeting Abstracts, The Electrochemical Society, Vol. MA2014-01, No. 39 ( 2014-04-01), p. 1455-1455
    Abstract: The demonstration of high mobility Ge n-MOSFETs has been a great challenge for high-performance Ge CMOS, because electron mobility was limited by a large amount of interface states density ( D it ) near the conduction band edge, which acts as Coulomb scattering centers. We significantly reduced D it ( 〈 10 11 eV -1 cm -2 ) at the Ge/GeO 2 interface with high-pressure oxidation (HPO), and very high electron mobility in Ge n-MOSFETs was demonstrated thanks to the dramatic reduction of Coulomb scattering. However, the rapid degradation of high- N s electron mobility in Ge n-MOSFETs is still one of the greatest concerns in Ge CMOS technology. Although there are many possible origins so far considered, the degradation mechanism is still unclear. In this work, we present (i) the atomically flat Ge(111) surface, followed by (ii) the layer-by-layer oxidation for achieving the atomically flat Ge/GeO 2 interface, and examine the effect of surface roughness (SR) scattering on high- N s electron mobility in Ge n-MOSFETs. The layer-by-layer oxidation on atomically flat Ge(111) surface was investigated. It was found that surface roughness was formed by conventional oxidation process, while low-temperature high-pressure oxidation provided the atomically flat Ge/GeO 2 interface. On the basis of this understanding, we have examined the effect of surface roughness scattering on high- N s electron mobility in Ge n-MOSFETs. The highest electron mobility of 582 cm 2 /Vs at N s =1x10 13 cm -2 was achieved by the formation of atomically flat Ge/GeO 2 interface thanks to the layer-by-layer oxidation.
    Type of Medium: Online Resource
    ISSN: 2151-2043
    Language: Unknown
    Publisher: The Electrochemical Society
    Publication Date: 2014
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  • 2
    In: ECS Transactions, The Electrochemical Society, Vol. 61, No. 3 ( 2014-03-26), p. 147-156
    Abstract: The rapid degradation of high- N s electron mobility in Ge n-MOSFETs is still one of the greatest concerns in Ge CMOS technology. Although there are many possible origins so far considered, the degradation mechanism is still unclear in spite of its importance. In this work, we clarify wafer-related origins for electron mobility degradation in Ge n-MOSFETs. High- N s electron mobility is dramatically improved thanks to (i) atomically flat Ge surface formation, followed by (ii) layer-by-layer oxidation. (iii) Oxygen-related neutral impurities in Ge substrates could be another origin of the mobility reduction on Ge wafers. By successfully eliminating these scattering sources in Ge n-MOSFETs, we demonstrate intrinsically high electron mobility in a wide range of N s .
    Type of Medium: Online Resource
    ISSN: 1938-5862 , 1938-6737
    Language: Unknown
    Publisher: The Electrochemical Society
    Publication Date: 2014
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  • 3
    Online Resource
    Online Resource
    The Electrochemical Society ; 2015
    In:  ECS Transactions Vol. 69, No. 5 ( 2015-09-08), p. 287-296
    In: ECS Transactions, The Electrochemical Society, Vol. 69, No. 5 ( 2015-09-08), p. 287-296
    Abstract: This paper discusses H 2 annealing effect of Ge substrate on carrier mobility and junction leakage current in Ge MOSFETs. We found that H 2 annealing of Ge wafer improved the electron mobility in Ge n-channel MOSFETs, while it degrades n + /p junction leakage current. Although we have not clarified the mechanisms causing such significant effects, we have found that the oxygen content in Ge surface region is phenomenologically related to above effects of Ge in H 2 annealing.
    Type of Medium: Online Resource
    ISSN: 1938-5862 , 1938-6737
    Language: Unknown
    Publisher: The Electrochemical Society
    Publication Date: 2015
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  • 4
    Online Resource
    Online Resource
    The Electrochemical Society ; 2013
    In:  ECS Meeting Abstracts Vol. MA2013-02, No. 33 ( 2013-10-27), p. 2227-2227
    In: ECS Meeting Abstracts, The Electrochemical Society, Vol. MA2013-02, No. 33 ( 2013-10-27), p. 2227-2227
    Abstract: Abstract not Available.
    Type of Medium: Online Resource
    ISSN: 2151-2043
    Language: Unknown
    Publisher: The Electrochemical Society
    Publication Date: 2013
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  • 5
    In: ECS Meeting Abstracts, The Electrochemical Society, Vol. MA2018-02, No. 31 ( 2018-07-23), p. 1018-1018
    Abstract: Strain engineering for pFETs has been conventionally enabled utilizing embedded SiGe in the source/drain regions to continuously boost the transistor current drive and transconductance [1]. Historically, for planar technologies, transconductance was monotonically improved by advancing the technology generations. However, this trend for transconductance, when properly normalized to the effective device width (fin perimeter) is no longer observed when FinFETs were introduced to the mainstream CMOS to improve the short channel effects for sub 30nm gate lengths [2] . The FinFET transconductance saturation or drop be attributed to ineffectiveness of the embedded SiGe stressors (in spite of higher mobility near-(110) surfaces) and/or increased contribution of the S/D resistance as the contacted gate pitch size aggressively scales down. Unless there is a strong and reliable method to externally apply gigantic strain to the Si fin channel, using strained SiGe (s-SiGe) channel, with built-in uniaxial compression, is a strong option to overcome this issue. In fact, SiGe has been utilized in CMOS industry as a knob to control the threshold voltage (V th ) and in part to boost the pFET reliability and transport [3]. Moreover, introduction of SiGe channel for planar pFET has improved reliability, resulting in further Capacitance-Equivalent-oxide-Thickness (CET) scaling over Si. For s-Si 1-x Ge x FinFETs, choice of Ge content (x) is not trivial. Adding more Ge can ideally build in more channel stress resulting increased hole mobility and current drive. However, epitaxial-defect-driven fin height control due to the critical thickness constraints, process thermal budget, bandgap reduction and gate-induced drain leakage (GIDL) control remain challenging. In particular, High-Ge-Content (HGC) s-SiGe FinFETs are of great interest for two reasons, from the transport point of view: First, very high level of strain (close to 3GPa) can be achieved when lattice matched to Si [4]. Second, if strain-relaxed buffer (SRB) SiGe with moderate Ge % is used to tensily strain Si nFET, higher Ge is required to compressively strain the pFET [5] . The GIDL issue can be mitigated by operating the high-performance (HP) device at a lower VDD, i.e. below 0.6V, in line with logic roadmap [4]. Controlling the H FIN , to be competitive with the state-of-the-art Si FinFETs, remains challenging. Above all, a major challenge is associated with the gate stack and interface trap control which is more pronounced in HGC SiGe than Si and pure Ge. In this talk, key process details to enable relatively tall fins and optimized replacement high-k metal gate (RMG) stacks in high-Ge-content SiGe will be discussed and their impact on key device characteristics will be presented. In particular, we review our recent advancement to achieve optimized RMG IL and passivation [6], high hole mobility and record performing short channel pMOS FinFETs. In additions, a metal gate work-function tuning solution will be presented utilizing an ultra-thin replacement metal-gate scheme to achieve target high-performance off current down to 15nm gate lengths. References: [1] T. Ghani et al., IEDM, 2003, p. 197. [2] P. Hashemi, et al., IEDM, 2017, p. 824. [3] S. Krishnan et al., IEDM, 2011, p. 634. [4] P. Hashemi et al., IEDM, 2014, p. 402. [5] R. Xie et al., IEDM, 2016, p. 47. [6] P. Hashemi et al., VLSI Tech. Symp., 2017, p. 120.
    Type of Medium: Online Resource
    ISSN: 2151-2043
    Language: Unknown
    Publisher: The Electrochemical Society
    Publication Date: 2018
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  • 6
    Online Resource
    Online Resource
    The Electrochemical Society ; 2015
    In:  ECS Meeting Abstracts Vol. MA2015-02, No. 18 ( 2015-07-07), p. 845-845
    In: ECS Meeting Abstracts, The Electrochemical Society, Vol. MA2015-02, No. 18 ( 2015-07-07), p. 845-845
    Abstract: A significant enhancement of electron mobility and understanding of carrier transport physics in Ge MOSFETs have been made thanks to significant reduction of major extrinsic carrier scattering sources such as D it and surface roughness, in addition to EOT scaling in Ge gate stacks. Since the phonon scattering is the dominant mechanism in Ge bulk, Ge substrate considerations have been out of scope for improving the carrier mobility in Ge MOSFETs. In this talk, however, we report that the peak electron mobility is dependent on how Ge substrates are treated. We found that H 2 annealing was quite effective for achieving the atomically flat surface of Ge substrates. In parallel with this effort, we recently found that H 2 annealing of Ge substrates could improve the peak electron mobility significantly, even though the peak electron mobility on as-received Ge substrates was poor. This fact indicates that there is definitely another origin of electron mobility degradation inside Ge bulk, because the peak electron mobility is not significantly affected by the surface roughness scattering. This fact indicates that electron mobility is not simply understood by considering the scattering mechanisms reported for Si MOSFETs. Here, we report the relationship between electron mobility and oxygen atom concentration in Ge substrate.  Furthermore, we discuss effects of oxygen atoms in Ge substrate on reverse-biased n + /p junction leakage current. The oxygen atoms in Ge substrates experimentally reduced the leakage current in n + /p junctions. This result is good news for Ge technology, but it is incompatible with high electron mobility in terms of achieving high performance MOSFETs. Then, we fabricated MOSFETs with selective areal profile of oxygen atoms along the channel and source/drain regions. This method has enabled us to achieve high electron mobility in n-channel Ge MOSFETs together with high I on / I off ratio. Although the junction leakage has been considered to be intrinsically poor in Ge due to a narrower energy band gap, this paper strongly suggests that Ge technology will be further improved for the best with the help of a rich heritage of Si technology.
    Type of Medium: Online Resource
    ISSN: 2151-2043
    Language: Unknown
    Publisher: The Electrochemical Society
    Publication Date: 2015
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  • 7
    Online Resource
    Online Resource
    The Electrochemical Society ; 2014
    In:  ECS Transactions Vol. 64, No. 8 ( 2014-08-09), p. 55-59
    In: ECS Transactions, The Electrochemical Society, Vol. 64, No. 8 ( 2014-08-09), p. 55-59
    Abstract: We demonstrate that Ge FETs show significantly high mobility of not only hole but also electron. In particular, this paper discusses what challenging issues are in n-channel FETs to achieve high electron mobility both in high electron density and in very thin EOT regions, by carefully considering electron scattering mechanisms in Ge MOS inversion channel. The results show us a promising future of Ge devices beyond Si FET technology.
    Type of Medium: Online Resource
    ISSN: 1938-5862 , 1938-6737
    Language: Unknown
    Publisher: The Electrochemical Society
    Publication Date: 2014
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  • 8
    Online Resource
    Online Resource
    The Electrochemical Society ; 2013
    In:  ECS Transactions Vol. 58, No. 9 ( 2013-08-31), p. 201-206
    In: ECS Transactions, The Electrochemical Society, Vol. 58, No. 9 ( 2013-08-31), p. 201-206
    Abstract: In germanium (Ge) MOSFET technology, surface planarization is a serious concern for mobility enhancement at high carrier density, reliability improvement of gate dielectrics and morphology control for non-planar FETs. In this work, (111)-oriented Ge substrates were annealed at 350-750 o C in pure H 2 atmosphere, and the surface structure and morphology were analyzed with atomic force microscopy. A step and terrace structure was observed on the surface after the H 2 annealing above 500 o C. The terrace width is controllable by the off-angle of the initial surface within 0.3 o at least. The roughness root mean square (RMS) at 100 x 100 nm on single terrace is ~0.05 nm which is almost our detection limit, which implies that the single terrace on H 2 annealed Ge (111) is atomically flat. Furthermore, even though the initial surface roughness RMS is intentionally increased up to 0.6 nm, atomically flat terrace structure could be obtained by the H 2 annealing.
    Type of Medium: Online Resource
    ISSN: 1938-5862 , 1938-6737
    Language: Unknown
    Publisher: The Electrochemical Society
    Publication Date: 2013
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  • 9
    Online Resource
    Online Resource
    The Electrochemical Society ; 2014
    In:  ECS Meeting Abstracts Vol. MA2014-02, No. 44 ( 2014-08-05), p. 2090-2090
    In: ECS Meeting Abstracts, The Electrochemical Society, Vol. MA2014-02, No. 44 ( 2014-08-05), p. 2090-2090
    Abstract: 1. Introduction The demonstration of high electron mobility in Ge n-MOSFETs is not an easy task due to unknown carrier scatterings in Ge inversion channel. The first step to clear the big hurdle is to improve the peak electron mobility by reducing the interface states density ( D it ). We have succeeded in the reduction of D it ( 〈 10 11 eV -1 cm -2 ) at Ge/GeO 2 interface by employing the high-pressure O 2 oxidation (HPO) [1, 2]. However, there still remain two critical challenges. One is how to suppress the significant degradation of high- Ns electron mobility ( Ns : carrier density). The other one is how to keep high electron mobility in the thin EOT region [3]. Those two are of paramount importance for pushing Ge CMOS in the real technology. 2. Reinvestigation of High- Ns Electron Mobility Coulomb scattering, phonon scattering, and surface roughness scattering are generally considered in MOS inversion layer. By employing HPO, Coulomb scattering has been dramatically reduced, resulting that the peak electron mobility in Ge n-FET is now x2.5 higher than that in Si case [1]. On the other hand, high- Ns electron mobility is generally understood from the interface roughness scattering. Here, not only the roughness height but also the roughness correlation length should be considered, according to the conventional roughness scattering theory [4, 5]. First, we have challenged to realize the atomically flat Ge (111) surface by using H 2 annealing [6] to reduce the roughness correlation length. Next, it is discussed how the atomically flat surface is affected by the oxidation. The results show that the step and terrace structure is maintained by selecting the temperature under a high-pressure oxidation [7]. Then, excellent high- Ns electron mobility has been demonstrated. 3. EOT Reduction Recently we have newly found two facts to breakthrough this challenge. The first one is that the low temperature HPO reduces the oxidation rate [8]. This fact enables us to achieve ~2 nm EOT GeO 2 on Ge with superior interface and bulk GeO 2 . The other one is to replace HPO-GeO 2 with high-k oxides which are thermodynamically appropriate for Ge. This means that we can use low oxygen potential oxides instead of HPO- GeO 2 . Then, we have reached a conclusion that Y 2 O 3 is one of the best candidates on Ge [9]. This material is actually what we have regarded as the Ge-friendly insulator for Ge gate stacks previously from experimental viewpoint [10] . Our recent results have shown that Y 2 O 3 -doped GeO 2 (YGO) is better than pure Y 2 O 3 on Ge [11]. The resultant electron effective mobility in Ge n-FETs at Ns =10 13 cm -2 is significantly improved down to sub-nm EOT region. Conclusion We can engineer the Ge interface through understanding both of thermodynamics in gate stack formation and of kinetics in surface planarization and oxidation. Thus, it is concluded that Ge CMOS is quite promising. Acknowledgements This work was partly supported by Grant-in-Aid for Scientific Research (A) by Japan Society for the Promotion of Science (JSPS), and by the JSPS Core-to-Core Program “International Collaborative Research Center on Atomically Controlled Processing for Ultra-large Scale Integration” References [1] C. H. Lee et al., TED- 58 (2011)1295. [2] K. Nagashio et al., MRS Symp. Proc. 1155 (2009) C06-02. [3] M. Caymax et al., IEDM 2009-461. [4] Y. Matsumoto and Y. Uemura, JJAP Suppl. 2 (1974) 367. [5] C. H. Lee et al., JJAP 51 (2012)104203. [6] T. Nishimura et al., APEX 5 (2012)121301. [7] C. H. Lee et al., IEDM 2013-32. [8] C. H. Lee et al., APEX 5 (2012)114001. [9] C. H. Lee et al., IEDM 2013-40. [10]A. Toriumi et al., “ Advanced Gate Stacks for High-Mobility Semiconductors ", pp. 257-267 (2007, Springer). [11] C. Lu et al., APL. 104 (2014) 092909.
    Type of Medium: Online Resource
    ISSN: 2151-2043
    Language: Unknown
    Publisher: The Electrochemical Society
    Publication Date: 2014
    detail.hit.zdb_id: 2438749-6
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