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  • 1
    Online Resource
    Online Resource
    Proceedings of the National Academy of Sciences ; 1972
    In:  Proceedings of the National Academy of Sciences Vol. 69, No. 11 ( 1972-11), p. 3436-3439
    In: Proceedings of the National Academy of Sciences, Proceedings of the National Academy of Sciences, Vol. 69, No. 11 ( 1972-11), p. 3436-3439
    Abstract: The relation of the symmetry of the thermodynamic functions with respect to the critical density ρ c to the analyticity of the chemical potential above the critical temperature is discussed with the aid of thermo-dynamic considerations. Special consideration is given to the differential coefficients ([unk] 2 μ/[unk] T 2 )ρ and ([unk] 2 P /[unk] T 2 )ρ. The discussion is extended to the two-phase region, and some of the relations between critical exponents are analyzed. A proof is given that the vapor-pressure curve joins smoothly with the critical isochore. The behavior of the entropy along the coexistence curve is considered. Finally, an argument is presented that the Griffiths-Liberman inequality γ′ ≥ β(δ - 1) is an equality.
    Type of Medium: Online Resource
    ISSN: 0027-8424 , 1091-6490
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    Language: English
    Publisher: Proceedings of the National Academy of Sciences
    Publication Date: 1972
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  • 2
    Online Resource
    Online Resource
    Proceedings of the National Academy of Sciences ; 1969
    In:  Proceedings of the National Academy of Sciences Vol. 63, No. 4 ( 1969-08), p. 1055-1062
    In: Proceedings of the National Academy of Sciences, Proceedings of the National Academy of Sciences, Vol. 63, No. 4 ( 1969-08), p. 1055-1062
    Abstract: Momentum relationships involved in the motion of a sphere through a perfect fluid are considered. The mechanism, by which the momentum given to a sphere by an external impulsive force is transferred to the container as a whole, is traced through in some detail, and energy and momentum relationships are discussed. Comparison is made with a 3 He atom or a roton moving in superfluid 4 He.
    Type of Medium: Online Resource
    ISSN: 0027-8424 , 1091-6490
    RVK:
    RVK:
    Language: English
    Publisher: Proceedings of the National Academy of Sciences
    Publication Date: 1969
    detail.hit.zdb_id: 209104-5
    detail.hit.zdb_id: 1461794-8
    SSG: 11
    SSG: 12
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  • 3
    Online Resource
    Online Resource
    Proceedings of the National Academy of Sciences ; 1973
    In:  Proceedings of the National Academy of Sciences Vol. 70, No. 4 ( 1973-04), p. 1241-1245
    In: Proceedings of the National Academy of Sciences, Proceedings of the National Academy of Sciences, Vol. 70, No. 4 ( 1973-04), p. 1241-1245
    Abstract: It has often been assumed that the slope of the isotherm involving a pair of secondary variable vanishes along a λ line [for example, along a λ line in the pressure-volume plane ([unk] P /[unk] V ) T vanishes], and therefore that the specific heat for constant extensive variable (e.g., C V ) has the greatest possible value on the λ line and so obeys the Buckingham-Fairbank relation. It is shown here by a heuristic theoretical argument that in 3 He- 4 He solutions ([unk]μ 4 /[unk] x 3 ) T and ([unk]μ 3 /[unk] x 3 ) T probably do not vanish and C x 3 does not have its maximum possible value, although it may become infinite when x 3 → 0. (μ 4 and μ 3 are chemical potentials of 4 He and 3 He and x 3 is the molefraction of 3 He). Only at the tricritical point does ([unk]μ 4 /[unk] x 3 ) T finally vanish and C x 3 have a value, which cannot be exceeded without the system's becoming unstable. In the case of the transition in solid NH 4 Cl the experimental facts seem to indicate that at the higher temperatures, where the transition is of higher order, ([unk] P /[unk] V ) T does not become zero along the transition line. A statistical thermodynamic description of tricritical points is given, and shown to accord qualitatively with the experimental results for the 3 He- 4 He solutions. There is evidence that any singular behavior at the tricritical point in 3 He- 4 He is already present along the λ line. Finally, an analysis is made of the possible behavior of binary liquid solutions, and it is shown that a tendency of C V to exceed its maximum value can result in a flat top on the coexistence curve.
    Type of Medium: Online Resource
    ISSN: 0027-8424 , 1091-6490
    RVK:
    RVK:
    Language: English
    Publisher: Proceedings of the National Academy of Sciences
    Publication Date: 1973
    detail.hit.zdb_id: 209104-5
    detail.hit.zdb_id: 1461794-8
    SSG: 11
    SSG: 12
    Location Call Number Limitation Availability
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  • 4
    Online Resource
    Online Resource
    American Association for the Advancement of Science (AAAS) ; 1966
    In:  Science Vol. 152, No. 3722 ( 1966-04-29), p. 677-678
    In: Science, American Association for the Advancement of Science (AAAS), Vol. 152, No. 3722 ( 1966-04-29), p. 677-678
    Type of Medium: Online Resource
    ISSN: 0036-8075 , 1095-9203
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    Language: English
    Publisher: American Association for the Advancement of Science (AAAS)
    Publication Date: 1966
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  • 5
    In: Science, American Association for the Advancement of Science (AAAS), Vol. 377, No. 6614 ( 2022-09-30)
    Abstract: The Perseverance rover landed in Jezero crater on Mars on 18 February 2021 with three scientific objectives: to explore the geologic setting of the crater, to identify ancient habitable environments and assess the possibility of past martian life, and to collect samples for potential transport to Earth for analysis in laboratories. In the 290 martian days (sols) after landing, Perseverance explored rocks of the Jezero crater floor. RATIONALE Jezero, a 45-km-diameter crater, was selected for investigation by Perseverance because orbital observations had shown that it previously contained an open-system lake, prior to ~3.5 billion years ago. Major climate change then left Mars in its current cold and dry state. On Earth, broadly similar environments of similar age to Jezero contain evidence of microbial life. Jezero crater contains a well-preserved delta, identified as a target for astrobiological investigation by the rover. Perseverance landed ~2 km away from the delta, on rocks of the crater floor. Previously proposed origins for these rocks have ranged from lake (or river) sediments to lava flows. Olivine-rich rocks identified on the crater floor, as well as in the area surrounding Jezero, have previously been attributed to a widely distributed impact melt or volcanic deposit, variably altered to carbonate. We used Perseverance to investigate the origin of the crater floor rocks and to acquire samples of them. RESULTS The Jezero crater floor consists of two geologic units: the informally named Máaz formation covers much of the crater floor and surrounds the other unit, which is informally named the Séítah formation. Máaz rocks display a range of morphologies: structureless boulders, flagstone-like outcrops, and ridges that are several meters high. The ridges expose prominent layers, ranging in thickness from a few centimeters to a few tens of centimeters. Rocks of Séítah are often tabular and strongly layered, with layer thicknesses ranging from centimeters to meters. Máaz and Séítah rocks display no outcrop or grain-scale evidence for transport by wind or water. Perseverance observations show that the Máaz rocks consist of 0.5- to 1-mm interlocking crystals of pyroxene and plagioclase. Combined with bulk chemical composition measurements, this suggests Máaz is an igneous unit that cooled slowly. In contrast, most Séítah rocks are very rich in magnesium and are dominated by densely packed 2- to 3-mm-diameter crystals of olivine, surrounded by pyroxene. These properties indicate settling and accumulation of olivine near the base of a thick magma body, such as an intrusion, lava lake, or thick lava flow. Ground-penetrating radar indicates that Séítah rocks dip beneath the Máaz formation. We hypothesize that Máaz could be the magmatic complement to the Séítah olivine-rich rocks or, alternatively, Máaz could be a series of basaltic lavas that flowed over and around the older Séítah formation. The olivines in the Séítah formation are rimmed with magnesium-iron carbonate, likely produced by interaction with CO 2 -rich water. Máaz formation rocks contain an aqueously deposited iron oxide or iron silicate alteration product. Both units commonly contain patches of bright-white salts, including sodium perchlorate and various sulfate minerals. Although both rock units have been altered by water, preservation of the original igneous minerals and the absence of aluminous clay minerals indicate that the alteration occurred under low water/rock ratio and that there was little loss of soluble species to the surroundings. It remains unclear when these aqueous processes occurred and whether they relate to the lake that once filled Jezero. The exposure of the olivine-rich Séítah rocks at the surface, the absence of lake or river sediment in the exploration area, and several nearby erosional remnant hills of delta sediment indicate that substantial crater floor erosion occurred after formation of these igneous units. Samples of both of these geologic units were collected as drill cores. The drill cores were stored in ultraclean sample tubes, for potential transport to Earth by future missions in the early 2030s. CONCLUSION The floor of Jezero crater explored by Perseverance consists of two distinct igneous units that have both experienced reactions with liquid water. Multiple rock cores were collected from these units for potential transport to Earth and analysis in terrestrial laboratories. Sample collection by Perseverance on Mars. This image mosaic was acquired by the WATSON camera on the rover’s robot arm. Rock cores were drilled from the two holes (arrow) in an igneous rock of the Máaz formation. The 6-cm-long, 1.3-cm-diameter cores were sealed into individual sample tubes and are now stored inside the rover.
    Type of Medium: Online Resource
    ISSN: 0036-8075 , 1095-9203
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    Language: English
    Publisher: American Association for the Advancement of Science (AAAS)
    Publication Date: 2022
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  • 6
    In: Science, American Association for the Advancement of Science (AAAS), Vol. 374, No. 6568 ( 2021-11-05), p. 711-717
    Abstract: Observations from orbital spacecraft have shown that Jezero crater on Mars contains a prominent fan-shaped body of sedimentary rock deposited at its western margin. The Perseverance rover landed in Jezero crater in February 2021. We analyze images taken by the rover in the 3 months after landing. The fan has outcrop faces, which were invisible from orbit, that record the hydrological evolution of Jezero crater. We interpret the presence of inclined strata in these outcrops as evidence of deltas that advanced into a lake. In contrast, the uppermost fan strata are composed of boulder conglomerates, which imply deposition by episodic high-energy floods. This sedimentary succession indicates a transition from sustained hydrologic activity in a persistent lake environment to highly energetic short-duration fluvial flows.
    Type of Medium: Online Resource
    ISSN: 0036-8075 , 1095-9203
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    Language: English
    Publisher: American Association for the Advancement of Science (AAAS)
    Publication Date: 2021
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  • 7
    In: Science, American Association for the Advancement of Science (AAAS), Vol. 360, No. 6395 ( 2018-06-22)
    Abstract: Disorders of the brain can exhibit considerable epidemiological comorbidity and often share symptoms, provoking debate about their etiologic overlap. We quantified the genetic sharing of 25 brain disorders from genome-wide association studies of 265,218 patients and 784,643 control participants and assessed their relationship to 17 phenotypes from 1,191,588 individuals. Psychiatric disorders share common variant risk, whereas neurological disorders appear more distinct from one another and from the psychiatric disorders. We also identified significant sharing between disorders and a number of brain phenotypes, including cognitive measures. Further, we conducted simulations to explore how statistical power, diagnostic misclassification, and phenotypic heterogeneity affect genetic correlations. These results highlight the importance of common genetic variation as a risk factor for brain disorders and the value of heritability-based methods in understanding their etiology.
    Type of Medium: Online Resource
    ISSN: 0036-8075 , 1095-9203
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    Language: English
    Publisher: American Association for the Advancement of Science (AAAS)
    Publication Date: 2018
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  • 8
    Online Resource
    Online Resource
    American Association for the Advancement of Science (AAAS) ; 2013
    In:  Science Vol. 340, No. 6136 ( 2013-05-31), p. 1068-1072
    In: Science, American Association for the Advancement of Science (AAAS), Vol. 340, No. 6136 ( 2013-05-31), p. 1068-1072
    Abstract: Observations by the Mars Science Laboratory Mast Camera (Mastcam) in Gale crater reveal isolated outcrops of cemented pebbles (2 to 40 millimeters in diameter) and sand grains with textures typical of fluvial sedimentary conglomerates. Rounded pebbles in the conglomerates indicate substantial fluvial abrasion. ChemCam emission spectra at one outcrop show a predominantly feldspathic composition, consistent with minimal aqueous alteration of sediments. Sediment was mobilized in ancient water flows that likely exceeded the threshold conditions (depth 0.03 to 0.9 meter, average velocity 0.20 to 0.75 meter per second) required to transport the pebbles. Climate conditions at the time sediment was transported must have differed substantially from the cold, hyper-arid modern environment to permit aqueous flows across several kilometers.
    Type of Medium: Online Resource
    ISSN: 0036-8075 , 1095-9203
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    Language: English
    Publisher: American Association for the Advancement of Science (AAAS)
    Publication Date: 2013
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  • 9
    In: Science, American Association for the Advancement of Science (AAAS), Vol. 364, No. 6442 ( 2019-05-24)
    Abstract: Approximately 2.4% of the human mitochondrial DNA (mtDNA) genome exhibits common homoplasmic genetic variation. We analyzed 12,975 whole-genome sequences to show that 45.1% of individuals from 1526 mother–offspring pairs harbor a mixed population of mtDNA (heteroplasmy), but the propensity for maternal transmission differs across the mitochondrial genome. Over one generation, we observed selection both for and against variants in specific genomic regions; known variants were more likely to be transmitted than previously unknown variants. However, new heteroplasmies were more likely to match the nuclear genetic ancestry as opposed to the ancestry of the mitochondrial genome on which the mutations occurred, validating our findings in 40,325 individuals. Thus, human mtDNA at the population level is shaped by selective forces within the female germ line under nuclear genetic control, which ensures consistency between the two independent genetic lineages.
    Type of Medium: Online Resource
    ISSN: 0036-8075 , 1095-9203
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    Language: English
    Publisher: American Association for the Advancement of Science (AAAS)
    Publication Date: 2019
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  • 10
    In: Science, American Association for the Advancement of Science (AAAS), Vol. 343, No. 6169 ( 2014-01-24)
    Abstract: Sedimentary rocks examined by the Curiosity rover at Yellowknife Bay, Mars, were derived from sources that evolved from an approximately average martian crustal composition to one influenced by alkaline basalts. No evidence of chemical weathering is preserved, indicating arid, possibly cold, paleoclimates and rapid erosion and deposition. The absence of predicted geochemical variations indicates that magnetite and phyllosilicates formed by diagenesis under low-temperature, circumneutral pH, rock-dominated aqueous conditions. Analyses of diagenetic features (including concretions, raised ridges, and fractures) at high spatial resolution indicate that they are composed of iron- and halogen-rich components, magnesium-iron-chlorine–rich components, and hydrated calcium sulfates, respectively. Composition of a cross-cutting dike-like feature is consistent with sedimentary intrusion. The geochemistry of these sedimentary rocks provides further evidence for diverse depositional and diagenetic sedimentary environments during the early history of Mars.
    Type of Medium: Online Resource
    ISSN: 0036-8075 , 1095-9203
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    Language: English
    Publisher: American Association for the Advancement of Science (AAAS)
    Publication Date: 2014
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    detail.hit.zdb_id: 2066996-3
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    SSG: 11
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