In:
Israel Journal of Chemistry, Wiley, Vol. 59, No. 3-4 ( 2019-03), p. 140-150
Abstract:
Coordination self‐assemblies have attracted more and more attentions from chemists because of their beautiful structures and wide applications, and a number of excellent reviews that focus on either synthesis or application have been published. This paper will hightlight how to controllablly construct supramolecular assemblies based on flexibility of ligands driven by different external stimuli. Herein, not only various discrete metal‐organic aggregates including M 2 L 2 type metallocycles, M 2 L 4 /M 2 L 6 /M 3 L 2 /M 6 L 4 /M 6 L 8 type metallocages have been prepared, but also many well‐organized ensembles based on such new‐formed discrete aggretates have been further assembled driven by suitable external stimuli. Also, controllable self‐assembly processes accompanied with structure changes have been developed. It is expected that this paper will provide a potential strategy for developing novel coordination assemblies that can be comparable to biomacromolecules from organism.
Type of Medium:
Online Resource
ISSN:
0021-2148
,
1869-5868
DOI:
10.1002/ijch.v59.3-4
DOI:
10.1002/ijch.201800055
Language:
English
Publisher:
Wiley
Publication Date:
2019
detail.hit.zdb_id:
2066481-3
Permalink