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  • AIP Publishing  (5)
  • Asien - CrossAsia  (5)
Materialart
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  • AIP Publishing  (5)
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  • Asien - CrossAsia  (5)
  • 1
    Online-Ressource
    Online-Ressource
    AIP Publishing ; 2019
    In:  Chinese Journal of Chemical Physics Vol. 32, No. 5 ( 2019-10-01), p. 635-642
    In: Chinese Journal of Chemical Physics, AIP Publishing, Vol. 32, No. 5 ( 2019-10-01), p. 635-642
    Kurzfassung: In this work, a simple method was carried out to successfully fabricate superoleophilic and superhydrophobic N-dodecyltrimethoxysilane@tungsten trioxide coated copper mesh. The as-fabricated copper mesh displayed prominent superoleophilicity and superhydrophobicity with a huge water contact angle about 154.39° and oil contact angle near 0°. Moreover, the coated copper mesh showed high separation efficiency approximately 99.3%, and huge water flux about 9962.3 L·h−1·m−2, which could be used to separate various organic solvents/water mixtures. Furthermore, the coated copper mesh showed favorable stability that the separation efficiency remained above 90% after 10 separation cycles. Benefiting from the excellent photocatalytic degradation ability of tungsten trioxide, the coated copper mesh possessed the self-cleaning capacity. Therefore, the mesh contaminated with lubricating oil could regain superhydrophobic property, and this property of self-cleaning permitted that the fabricated copper mesh could be repeatedly used for oil and water separation.
    Materialart: Online-Ressource
    ISSN: 1674-0068 , 2327-2244
    Sprache: Englisch
    Verlag: AIP Publishing
    Publikationsdatum: 2019
    ZDB Id: 2381472-X
    SSG: 6,25
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 2
    Online-Ressource
    Online-Ressource
    AIP Publishing ; 2009
    In:  Chinese Journal of Chemical Physics Vol. 22, No. 5 ( 2009-10-01), p. 447-452
    In: Chinese Journal of Chemical Physics, AIP Publishing, Vol. 22, No. 5 ( 2009-10-01), p. 447-452
    Kurzfassung: The fast phase-transitional process of ploy(N-isopropylacrylamide) (PNIPAM) in deuterated solution was studied by laser induced temperature jump technique combined with time-resolved mid-infrared absorbance difference spectroscopy on nanosecond level. The multi-peaks of amide I' band of PNIPAM among the energy range of 15651700 cm-1 was experimentally resolved to three groups (i, ii, iii) for the first time, while the distinct three-stage procedure in the phase transitional process of long-chain PNIPAM was observed firstly too. Furthermore, proper assignments were also made for the three group peaks in amide I' band and the three steps in the kinetics process of long-chain PNIPAM.
    Materialart: Online-Ressource
    ISSN: 1674-0068 , 2327-2244
    Sprache: Englisch
    Verlag: AIP Publishing
    Publikationsdatum: 2009
    ZDB Id: 2381472-X
    SSG: 6,25
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 3
    Online-Ressource
    Online-Ressource
    AIP Publishing ; 2011
    In:  Chinese Journal of Chemical Physics Vol. 24, No. 2 ( 2011-04-01), p. 141-144
    In: Chinese Journal of Chemical Physics, AIP Publishing, Vol. 24, No. 2 ( 2011-04-01), p. 141-144
    Kurzfassung: Photodetachment of H− irradiated by linearly polarized few-cycle laser field is investigated by time-dependent Schrödinger equation numerically. The photo-electron left-right asymmetry parameter as a function of carrier-envelop (CE) phase of few-cycle pulses is attained. We confirm the asymmetry of photoelectron distribution in H− photodetachment and find that the maximal asymmetry parameter of H− is equal to that of H atom under the same conditions but the corresponding CE phases are quite different. Thus a CE phase shift appears. Compared to that of H atom and field free electron, the zero asymmetry CE phase shift is sensitively affected by Coulomb field. The Coulomb effect on the asymmetry of H− photodetachment mainly behaves in the CE phase shift of H− instead of the amplitude of asymmetry parameter curve.
    Materialart: Online-Ressource
    ISSN: 1674-0068 , 2327-2244
    Sprache: Englisch
    Verlag: AIP Publishing
    Publikationsdatum: 2011
    ZDB Id: 2381472-X
    SSG: 6,25
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 4
    Online-Ressource
    Online-Ressource
    AIP Publishing ; 2017
    In:  Chinese Journal of Chemical Physics Vol. 30, No. 5 ( 2017-10-27), p. 588-594
    In: Chinese Journal of Chemical Physics, AIP Publishing, Vol. 30, No. 5 ( 2017-10-27), p. 588-594
    Materialart: Online-Ressource
    ISSN: 1674-0068 , 2327-2244
    Sprache: Englisch
    Verlag: AIP Publishing
    Publikationsdatum: 2017
    ZDB Id: 2381472-X
    SSG: 6,25
    Standort Signatur Einschränkungen Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 5
    In: Chinese Journal of Chemical Physics, AIP Publishing, Vol. 20, No. 4 ( 2007-08-01), p. 461-467
    Kurzfassung: Carboxyl (COO) vibrational modes of two amino acids histidine and glycine in D2O solution were investigated by temperature-dependent FTIR spectroscopy and temperature-jump nanosecond time-resolved IR difference absorbance spectroscopy. The results show that hydrogen bonds are formed between amino acid molecules as well as between the amino acid molecule and the solvent molecules. The asymmetric vibrational frequency of COO around 1600-1610 cm1 is blue shifted when raising temperature, indicating that the strength of the hydrogen bonds becomes weaker at higher temperature. Two bleaching peaks at 1604 and 1612 cm1 were observed for histidine in response to a temperature jump from 10 C to 20 C. The lower vibrational frequency at 1604 cm1 is assigned to the chain COO group which forms the intermolecular hydrogen bond with {NH3}+ group, while the higher frequency at 1612 cm1 is assigned to the end COO group forming hydrogen bonds with the solvent molecules. This is because that the hydrogen bonds in the former are expected to be stronger than the latter. In addition the intensities of these two bleaching peaks are almost the same. In contrast, only the lower frequency at 1604 cm1 bleaching peak has been observed for glycine. The fact indicates that histidine molecules form a dimer-like intermolecular chain while glycine forms a relatively longer chain in the solution. The rising phase of the IR absorption kinetics in response to the temperature-jump detected at 1604 cm1 for histidine is about 3010 ns, within the resolution limit of our instrument, indicating that breaking or weakening the hydrogen bond is a very fast process.
    Materialart: Online-Ressource
    ISSN: 1674-0068 , 2327-2244
    Sprache: Englisch
    Verlag: AIP Publishing
    Publikationsdatum: 2007
    ZDB Id: 2381472-X
    SSG: 6,25
    Standort Signatur Einschränkungen Verfügbarkeit
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