In:
Chinese Journal of Chemistry, Wiley, Vol. 30, No. 7 ( 2012-07), p. 1474-1478
Abstract:
The reaction of anhydrous CoCl 2 with NaOAr (ArO=2,4,6‐tri‐ tert ‐butylphenoxo) in THF at room temperature in 1:3 molar ratio afforded anionic cobalt aryloxide [Na(THF) 6 ][Co(OAr) 3 ] ( 1 ). The definite structure of this complex was characterized by X‐ray single crystal diffraction. It was found that this anionic aryloxo cobalt(II) complex could effectively initiate the ring‐opening polymerization of L ‐lactide both in solution and in bulk, leading to high molecular weight poly( L ‐lactide).
Type of Medium:
Online Resource
ISSN:
1001-604X
,
1614-7065
DOI:
10.1002/cjoc.201100612
Language:
English
Publisher:
Wiley
Publication Date:
2012
detail.hit.zdb_id:
2144352-X
SSG:
6,25
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