ISSN:
1573-9171
Keywords:
closo-dodecahydrododecaborate
;
dichloromethoxymethane
;
1,7-dialkoxy derivatives
;
1-isopropoxy-7-morpholino-closo-decahydrododecaborate
;
NMR-spectra
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Dichloromethoxymethane reacts with the sodium salt ofcloso-dodecahydrododecaborate Na2B12H12 to give disubstituted cluster, which readily decomposes when treated with various reagents. This cluster reacts with water, forming the previously described 1,7-B12H10(OH)2 2−reaction with alcohols results in a novel 1,7-dialkoxy derivative, whereas interaction with morpholine in acetone solution affords the novel anion, 1-O-I-Pri-7-O(CH2CH2)N-B12H10 2−. All of these derivatives were isolated as cesium salts and characterized by one- and two-dimensional NMR techniques.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00702375
