Keywords:
Chirality.
;
Ligands.
;
Transition metal catalysts.
;
Electronic books.
Type of Medium:
Online Resource
Pages:
1 online resource (322 pages)
Edition:
1st ed.
ISBN:
9780323852265
URL:
https://ebookcentral.proquest.com/lib/geomar/detail.action?docID=7253908
DDC:
541.223
Language:
English
Note:
Front Cover -- Chiral Phosphorous Based Ligands in Earth-Abundant Transition Metal Catalysis -- Chiral Phosphorous Based Ligands in Earth-Abundant Transition Metal Catalysis -- Copyright -- Contents -- Contributors -- Acknowledgment -- Introduction -- 1 - Design and synthesis of typical chiral bisphosphorus ligands -- 1. Introduction -- 2. Bisphosphorus ligands with carbon chiral center -- 3. Axially chiral bisphosphorus ligands -- 4. Ferrocenyl bisphosphorus ligands -- 5. Spiro backbone-based bisphosphorus ligands -- 6. P-chiral bisphosphorus ligands -- 7. Conclusions -- References -- 2 - The progress of chiral phosphine ligands in asymmetric iron catalysis -- 1. Introduction -- 2. Kumada cross-coupling reactions -- 3. Suzuki-Miyaura coupling reaction -- 4. Diels-Alder reaction -- 5. 1,3-dipolar cycloadditions -- 6. Olefin carbometalation -- 7. Hydrosilylation of ketones -- 8. Asymmetric strecker reaction of azomethine imines -- 9. Asymmetric transfer hydrogenation of ketones and imines -- 10. Asymmetric hydrogenation of ketones and imines -- 11. Conclusion -- References -- 3 - Asymmetric transformations under cobalt catalysis -- 1. Introduction -- 2. Allylic substitutions -- 3. Cycloaddition and cyclization -- 4. Hydrogenation -- 5. Hydrosilylation -- 6. Hydroboration -- 7. Hydroarylation -- 8. Hydrovinylation -- 9. Hydroalkynylation -- 10. Hydroalkylation -- 11. Hydroacylation -- 12. Reductive coupling -- 13. Conclusions -- References -- 4 - Asymmetric transformations under nickel catalysis -- 1. Introduction -- 2. Allylic substitution reactions -- 3. Cross-coupling reactions -- 4. Addition reactions -- 5. Cyclization reactions -- 6. Cycloaddition reactions -- 7. Hydrogenation -- 8. Conclusions -- References -- 5 - Copper/chiral phosphine ligand-catalyzed enantioselective 1,3-dipole cycloaddition reactions -- 1. Introduction.
,
2. [3+2] cycloaddition -- 3. Ferrocene-derived chiral phosphine ligands -- 4. Biaryl ring chiral phosphine ligands -- 4.1 BINAP analogues -- 4.2 BINOL-derived chiral phosphine ligands -- 4.3 Biarylamine-derived chiral phosphine ligands -- 5. Ming-Phos and its derivative chiral phosphine ligand -- 6. [3+3] cycloaddition -- 7. [3+4] cycloaddition -- 8. [6+3] cycloaddition -- 9. Summary and outlook -- References -- 6 - Copper/phosphine-catalyzed asymmetric radical reactions -- 1. Introduction -- 2. Cu(I)-catalyzed asymmetric amination -- 3. Copper-catalyzed enantioselective cross-coupling -- 3.1 C-N cross-coupling -- 3.2 Alkynylation -- 3.3 Arylation -- 3.4 C-B cross-coupling -- 4. Conclusions and outlook -- References -- 7 - Asymmetric borylative functionalization of π systems by copper/chiral phosphine -- 1. Introduction -- 2. Asymmetric hydroboration reactions by copper/chiral phosphine -- 3. Tandem reactions initiated by copper-boryl intermediate -- 4. Conclusions -- References -- 8 - Asymmetric hydrosilylation reactions by copper/chiral phosphine -- 1. Introduction -- 2. Asymmetric hydrosilylation of CO bond -- 3. Asymmetric reduction of CC bond of α,β-unsaturated ketones and esters -- 4. Asymmetric hydrosilylation of alkenes -- 5. Conclusions -- References -- 9 - Asymmetric transformations under copper hydride (CuH) catalysis -- 1. Introduction -- 2. Asymmetric C-N bond-forming reactions -- 2.1 Asymmetric hydroamination of various alkenes -- 2.2 Modification of electrophilic amination reagents -- 2.3 Asymmetric intramolecular hydroamination -- 3. Asymmetric C-C bond-forming reactions -- 3.1 Asymmetric reductive coupling of alkenes with carbonyl derivatives -- 3.2 Asymmetric reductive coupling of alkenes with imines -- 3.3 Asymmetric reductive coupling of alkenes with other carbon electrophiles -- 4. Conclusions -- References -- Index -- A -- B.
,
C -- D -- F -- H -- I -- J -- K -- M -- N -- O -- P -- Q -- R -- S -- T -- V -- W -- Z -- Back Cover.
