ISSN:
1440-1738
Quelle:
Blackwell Publishing Journal Backfiles 1879-2005
Thema:
Geologie und Paläontologie
Notizen:
Abstract Interstitial pore waters from Ocean Drilling Program Site 1150, where ∼1200 m of sub-sea-floor sediment from the upper Japan Trench forearc were recovered, were analyzed for element concentrations and Cl, Sr and B isotopes. Although chlorinity showed profound down-hole freshening to values as low as ∼310 mm (0.55 × seawater) in the deeper part of the claystone-dominated succession, both Sr and B concentrations showed an overall increase. Sr reached concentrations of up to 〉250 µm (∼3.00 × seawater), whereas B-enrichment was even stronger (3920 µm; i.e. 9.30 × seawater). The strong variations in concentration correspond to fractionation reactions in the deep, tectonically deformed part of the forearc. The heavily fractured portion of Site 1150 (from ∼700 m to the total depth of the hole) has two shear zones that very likely act as conduits that expel deep-seated fluids to the sea floor. These fluids not only showed the strongest freshening of Cl, but were also characterized by low δ37Cl measurements (down to −1.1‰), the heaviest δ11B measurements (∼40–46‰) and the least radiogenic 87Sr/ 86Sr measurements. The profound isotope anomalies together with the excursions in element concentrations suggest that diagenetic processes operate at that depth. These include clay mineral diagenesis, alteration of tephra from the Japan and Izu Arcs, and possibly transformation of biogenic silica from abundant diatoms. Given the strong enrichment of some mobile elements (e.g. Sr, B, Li), enhanced fluid flow through permeable penetrative faults through the forearc (like the shear zones at Site 1150) could be an efficient mechanism for back-flux of those elements from the deep forearc into the hydrosphere.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1111/j.1440-1738.2003.00424.x
