Publication Date:
2014-12-26
Description:
Publication date: 1 February 2015 Source: Earth and Planetary Science Letters, Volume 411 Author(s): Antonio Caracausi , Michele Paternoster , Pasquale Mario Nuccio Mantle volatiles are mainly lost from the Earth to the atmosphere through subaerial and submarine volcanism. Recent studies have shown that degassing of mantle volatiles also occurs from inactive volcanic areas and in tectonically active areas. A new challenge in Earth science is to quantify the mantle-derived flux of volatiles (e.g., CO 2 ) which is important for understanding such diverse issues as the evolution of the atmosphere, the relationships between magma degassing and volcanic activity, gas pressure and seismogenic processes, and the hazards posed by volcanic lakes. Here we present a detailed study of mantle-derived CO 2 budget from Mt. Vulture volcano in the Apennines, Italy, whose latest eruption occurred 141 ± 11 kyr ago. The relationship between δ 13 C CO2 and total dissolved carbon at Mt. Vulture volcano indicates that the emitted CO 2 is a mixture of a biogenic end-member with an average δ 13 C CO2 of about − 17 ‰ and a mantle-derived CO 2 end-member with δ 13 C CO2 values from − 3 ‰ to + 2 ‰ . These values of mantle-derived δ 13 C CO2 are in the range of those for gas emitted from active volcanoes in the Mediterranean. We calculated the contribution of individual components (CO 2 in groundwater, in lakes and from main pools) to the total CO 2 budget in the area. We used new measurements of water flow, combined with literature data, to calculate the CO 2 flux associated with groundwater, and measured the gas flux from the main pools on the volcanic edifice. Finally, we calculated the CO 2 flow in the lakes based on the gradient concentration and eddy diffusivity. The total mantle-derived CO 2 budget in the area is 4.85 × 10 8 mol yr − 1 , which is more than double previous estimates. This is higher than those observed in younger volcanic systems elsewhere, thereby supporting the existence of actively degassing mantle melts below Mt. Vulture volcano. A structural map highlights the tectonic control on CO 2 flow across the Mt. Vulture volcanic edifice. Indeed, the tectonic discontinuities that controlled the magma upwelling during the most recent volcanic activity are still the main active degassing structures. The new estimate of CO 2 budget in the Mt. Vulture area, together with literature data on CO 2 budget from historically active and inactive Italian volcanoes, suggests a power-law functional relationship between the age of the most recent volcanic eruption and both total discharged CO 2 ( R 2 = 0.73 ) and volcano size-normalized CO 2 flux ( R 2 = 0.66 ). This relation is also valid by using data from worldwide volcanoes highlighting that deep degassing can occur over very long time too. In turn, the highlighted relation provides also an important tool to better evaluate the state of activity of a volcano, whose last activity occurred far in time. Finally, our study highlights that in the southern Apennines, an active degassing of mantle-derived volatiles (i.e., He, CO 2 ) occurs indiscriminately from west to east. This is in contrast to the central–northern Apennine, which is characterized by a crustal radiogenic volatile contribution, which increases eastward, coupled to a decrease in deep CO 2 flux. This difference between the two regions is probably due to lithospheric tears which control the upwelling of mantle melts, their degassing and the transport of volatiles through the crust.
Print ISSN:
0012-821X
Electronic ISSN:
1385-013X
Topics:
Geosciences
,
Physics
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