Skip to main content
Log in

Relaxation of thiyl radicals as a measure of the probable timescale over which the missing fraction of muonium in water is lost

  • Molecular Structure and Dynamics, Muonium Chemistry
  • Published:
Hyperfine Interactions Aims and scope Submit manuscript

Abstract

Muonium atoms produced in water react with thioacetamide (CH3CSNH2) to form a sulphur-centred (thiyl) free radical whose level-crossing-resonance from the CH3-protons has been detected and analysed. Its amplitude increases with concentration below ∼10−2 M but decreases at higher concentrations with a concommitant increase in linewidth. This is interpreted as indicating overlap with paramagnetic species from the muon track. It starts when the track is a few nanoseconds old.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. K. Venkateswaran, M.V. Barnabas, R.F. Kiefl, J.M. Stadlbauer and D.C. Walker, J. Phys. Chem. 93 (1989) 388;

    Article  Google Scholar 

  2. D.C. Walker, M.V. Barnabas and K. Venkateswaran, Radiat. Phys. Chem., 36 (1990) 537.

    Google Scholar 

  3. K. Venkateswaran, M.V. Barnabas, Z. Wu and D.C. Walker, Can. J. Phys., in press.

  4. C.J. Rhodes, M.C.R. Symons and E. Roduner, J.C.S. Chem. Comm. 3 (1988).

  5. M.V. Barnabas, PhD Thesis, University of British Columbia, 1989;

  6. M.V. Barnabas and D.C. Walker, Chem. Phys. Lett., 168 (1990) 9.

    Article  ADS  Google Scholar 

  7. R.F. Kiefl, Hyp. Int. 32 (1986) 707;

    Google Scholar 

  8. R.F. Kiefl, S.R. Kreitzman, M. Celio, R. Keitel, J.H. Brewer, G.M. Luke, D. R. Noakes, P.W. Percival, T. Matsuzaki and K. Nishiyama, Phys. Rev A 34 (1986) 681.

    Article  ADS  Google Scholar 

  9. K. Venkateswaran, M.V. Barnabas and D.C. Walker, J. Phys. Chem. 94 (1990) 178.

    Article  Google Scholar 

  10. M. Heming, E. Roduner, I.D. Reid, P.W.F. Louwrier, J.W. Schneider, H. Keller, W. Odermatt, B.D. Patterson, B. Pumpin and I.M. Pumpin Chem. Phys. 129 (1989) 335.

    Article  Google Scholar 

  11. M.V. Barnabas, K. Venkateswaran and D.C. Walker, Can. J. Chem. 67 (1989) 120.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Barnabas, M.V., Venkateswaran, K. & Walker, D.C. Relaxation of thiyl radicals as a measure of the probable timescale over which the missing fraction of muonium in water is lost. Hyperfine Interact 65, 953–958 (1991). https://doi.org/10.1007/BF02397748

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02397748

Keywords

Navigation