Summary
Two series of complexes having the formula [M{HB(3,5-Me2C3N2H)3}(NO)Cl(NHC6H4Z-p)]; in which M=Mo and Z=F, Cl, Br, OMe, SMe, CN, CO2Me or NO2 and M=W and Z=Br, OMe, CN, CO2Me or NO2, have been prepared. The reduction potentials of these new complexes were measured by cyclic voltammetry and, in combination with previously reported data for related species and for [Mo{HB(3,5-Me2C3N2H)3} (NO)I-(NHC6H4Z-p], were used to determine reaction constants for the reduction of [M{HB(3,5-Me2C3N2H)3}(NO)X(NHC6H4Z)]M=Mo and X=I or Cl; M=W, X=Cl.
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Part IV. N. Al Obaidi, M. Chaudhury, D. Clague, C. J. Jones, J. C. Pearson, J. A. McCleverty and S. S. Salam, submitted toJ. Chem. Soc., Dalton Trans., Paper 6/869.
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Al Obaidi, N., Charsley, S.M., Hussain, W. et al. Monometallic, homo- and hetero-bimetallic complexes based on redox active tris(3,5-dimethylpyrazolyl)boratomolybdenum and tungsten nitrosyls. Part V.Para-substituent effects on the reduction potentials of arylamide complexes. Transition Met Chem 12, 143–148 (1987). https://doi.org/10.1007/BF01022343
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DOI: https://doi.org/10.1007/BF01022343