Abstract
The structural features of aqueous sucrose solutions are investigated via viscosimetry and IR spectroscopy in the 293.15–323.5 K range of temperatures at concentrations of 0–60%. Concentration dependences of the activation parameters of viscous flow, structural temperature, and energy and length of intermolecular hydrogen bonds are calculated based on the experimental data. It is shown that the solution became more structured with an increase in the sucrose concentration.
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References
A. T. Allen and R. M. Wood, Sugar Technol. Rev. 2, 165 (1974).
V. A. Mikhailik, E. O. Davydova, and V. V. Mank, in Thermodynamics of Organic Compounds, Collection of Articles (Gor’kii, 1989), No. 1, p. 86 [in Russian].
E. I. Akhumov, Zh. Prikl. Khim. 48, 458 (1975).
L. D. Bobrovnik, A. M. Grekhov, and I. S. Gulyi, J. Struct. Chem. 39, 704 (1998).
S. Glasstone, K. J. Laidler, and H. Eyring, The Theory of Rate Processes: The Kinetics of Chemical Reactions, Viscosity, Diffusion and Electrochemical Phenomena (Van Nostrand, New York, 1941).
E. A. Masimov, B. G. Pashayev, and H. Sh. Hasanov, News Baku Univ., Ser. Phys.-Math. Sci., No. 3, 109 (2010).
E. A. Masimov, G. Sh. Gasanov, and B. G. Pashaev, Russ. J. Phys. Chem. A 87, 948 (2013).
E. A. Masimov, B. G. Pashaev, G. Sh. Hasanov, and S. I. Musaeva, Russ. J. Phys. Chem. A 87, 2105 (2013).
E. A. Masimov, B. G. Pashaev, G. Sh. Hasanov, and N. H. Hasanov, Russ. J. Phys. Chem. A 89, 1244 (2015).
H. Vogel, Z. Phys. 22, 648 (1921).
Water in Polymers, Ed. by S. Rowland, ACS Symposium Ser., No. 127 (Amer. Chem. Soc., Washington, D.C. 1980; Mir, Moscow, 1984).
A. V. Karyakin and G. A. Kriventsova, The State of Water in Organic and Inorganic Compounds (Nauka, Moscow, 1973) [in Russian].
G. V. Yukhnevich, Infrared Spectroscopy of Water (Nauka, Moscow, 1973) [in Russian].
Hydrogen Bond, Collection of Articles (Nauka, Moscow, 1981), p. 112 [in Russian].
J. D. Worley and I. M. Klotz, J. Chem. Phys. 45, 2868 (1966).
K. Ueberreiter, Makromol. Chem., Rapid Commun. 1, 139 (1980).
K. Ueberreiter, Makromol. Chem., Rapid Commun. 1, 143 (1980).
K. Ueberreiter, Colloid Polym. Sci. 260, 37 (1982).
K. Ueberreiter and D. Ziegler, Colloid Polym. Sci. 265, 908 (1987).
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Original Russian Text © E.A. Masimov, B.G. Pashaev, G.Sh. Hasanov, 2017, published in Zhurnal Fizicheskoi Khimii, 2017, Vol. 91, No. 4, pp. 644–647.
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Masimov, E.A., Pashaev, B.G. & Hasanov, G.S. Structure of aqueous solutions of sucrose, derived from viscosimetry data and IR spectroscopy. Russ. J. Phys. Chem. 91, 667–671 (2017). https://doi.org/10.1134/S003602441704015X
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DOI: https://doi.org/10.1134/S003602441704015X