Keywords:
Catalysis
;
Chemistry, Organic
;
Chemistry, inorganic
;
Chemistry
;
Aufsatzsammlung
;
Tandem-Reaktion
;
Übergangsmetallkomplexe
;
Katalysator
Description / Table of Contents:
Klappentext: Transition metal-catalyzed cascade reactions are an elegant approach to complex molecular scaffolds. Besides their esthetics and increase in structural complexity, they have also become mechanistic challenges for the combination of organometallic elementary steps. As a consequence, cascade reactions have revolutionized synthetic strategies and conceptual thinking. The authors highlight cyclization via carbopalladation and acylpalladation and Heck-pericyclic sequences. They discuss p-allyl palladium-based cascade reactions, Michael-type additions as an entry to transition-metal-promoted cyclizative transformations, and sequential or consecutive palladium-catalyzed processes, and show Pauson-Khand cascades, metal-catalyzed cyclizations of acyclic precursors, as well as cascade and sequential ruthenium-catalyzed transformations. Therefore, the reader finds overview of an exciting and highly dynamic field of a new and innovative methodological concept.
Type of Medium:
Online Resource
Pages:
Online-Ressource (VIII, 339 S.)
,
zahlr. graph. Darst.
Edition:
Online-Ausg. 2006 Springer eBook Collection. Chemistry and Materials Science
ISBN:
9783540329596
Series Statement:
Topics in organometallic chemistry 19
URL:
http://dx.doi.org/10.1007/11603696
DDC:
540
Language:
English
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