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  • 1
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 21 (2006): PA3012, doi:10.1029/2006PA001273.
    Description: Geochemical compositions and Sr and Nd isotopes were measured in two cores collected ~2 and 5 km from the Rainbow hydrothermal vent site on the Mid-Atlantic Ridge. Overall, the cores record enrichments in Fe and other metals from hydrothermal fallout, but sequential dissolution of the sediments allows discrimination between a leach phase (easily leachable) and a residue phase (refractory). The oxy-anion and transition metal distribution combined with rare earth element (REE) patterns suggest that 1) the leach fraction is a mixture of biogenic carbonate and hydrothermal Fe-Mn oxy-hydroxide with no significant contribution from detrital material, and 2) 〉99.5% of the REE content of the leach fraction is of seawater origin. In addition, the leach fraction has an average 87Sr/86Sr ratio indistinguishable from modern seawater at 0.70916. Although we lack the εNd value of present day deep water at the Rainbow vent site, we believe that the REE budget of the leach fraction is predominantly of seawater origin. We suggest, therefore, that the leach fraction provides a record of local seawater εNd values. Nd isotope data from these cores span the period of 4-14 ka (14C ages) and yield εNd values for North East Atlantic Deep Water (NEADW) that are higher (-9.3 to -11.1) than those observed in the nearby Madeira Abyssal Plain from the same depth (-12.4 ± 0.9). This observation suggests that either the Iceland-Scotland Overflow Water (ISOW) and Lower Deep Water (LDW) contributions to the formation of NEADW are higher along the Mid-Atlantic Ridge than in the surrounding basins, or that the relative proportion of ISOW was higher during this period than is observed today. This study indicates that hydrothermal sediments have the potential to provide a higher resolution record of deep water εNd values, and hence deep-water circulation patterns in the oceans, than is possible from other types of sediments.
    Description: VC is funded by the 2000 National Oceanography Centre, Southampton fellowship. Hydrothermal research at NOCS is funded through NERC core strategic science.
    Keywords: Nd isotope ; Hydrothermal ; Seawater
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 2
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 7 (2006): Q11022, doi:10.1029/2006GC001324.
    Description: We report evidence for active hydrothermal venting along two back-arc spreading centers of the NE Lau Basin: the Fonualei Rift and Spreading Center (FRSC) and the Northeast Lau Spreading Center (NELSC). The ridge segments investigated here are of particular interest as the potential source of a mid-water hydrothermal plume (1500–2000 m depth) which extends more than 2000 km across the SW Pacific Ocean dispersing away from an apparent origin close to the most northeastern limits of the Lau Basin. Our results indicate the presence of at least four new hydrothermal plume sources, three along the FRSC and one on the NELSC, the latter situated within 150 km of the maximum for the previously identified SW Pacific regional-scale plume. However, TDFe and TDMn concentrations in the southernmost FRSC plume that we have identified only reach values of 19 and 13 nmol/L and dissolved 3He anomalies in the same plume are also small, both in relation to the SW Pacific plume and to local background, which shows evidence for extensive 3He enrichment throughout the entire Lau Basin water column. Our results reveal no evidence for a single major point hydrothermal source anywhere in the NE Lau Basin. Instead, we conclude that the regional-scale SW Pacific hydrothermal plume most probably results from the cumulative hydrothermal output of the entire topographically restricted Lau Basin, discharging via its NE-most corner.
    Description: This research was funded jointly by NSF's Ridge 2000 Program (OCE-0242002 and OCE-0242618), by the NOAA Vents Program, and by core strategic funding from the Natural Environment Research Council to the National Oceanography Centre, Southampton (UK).
    Keywords: Hydrothermal ; Exploration ; Lau Basin ; SW Pacific
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 3
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2007. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 8 (2007): Q08013, doi:10.1029/2007GC001652.
    Description: We report first evidence for hydrothermal activity from the southern Knipovich Ridge, an ultra-slow spreading ridge segment in the Norwegian-Greenland Sea. Evidence comes from optical backscatter anomalies collected during a systematic side-scan sonar survey of the ridge axis, augmented by the identification of biogeochemical tracers in the overlying water column that are diagnostic of hydrothermal plume discharge (Mn, CH4, ATP). Analysis of coregistered geologic and oceanographic data reveals that the signals we have identified are consistent with a single high-temperature hydrothermal source, located distant from any of the axial volcanic centers that define second-order segmentation along this oblique ridge system. Rather, our data indicate a hydrothermal source associated with highly tectonized seafloor that may be indicative of serpentinizing ultramafic outcrops. Consistent with this hypothesis, the hydrothermal plume signals we have detected exhibit a high methane to manganese ratio of 2–3:1. This is higher than that typical of volcanically hosted vent sites and provides further evidence that the source of the plume signals reported here is most probably a high-temperature hydrothermal field that experiences some ultramafic influence (compare to Rainbow and Logachev sites, Mid-Atlantic Ridge). While such sites have previously been invoked to be common on the SW Indian Ridge, this may be the first such site to be located along the Arctic ultra-slow spreading ridge system.
    Description: Connelly and German were funded by NERC grant NER/B/S/ 2000/00755, NERC Core Strategic Funding at NOC, and the ChEss project of the Census of Marine Life.
    Keywords: Hydrothermal ; Arctic ; Serpentinization ; Knipovich Ridge
    Repository Name: Woods Hole Open Access Server
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  • 4
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2009. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 10 (2009): Q05T05, doi:10.1029/2008GC002314.
    Description: This paper demonstrates that a Raman spectroscopy, point-counting technique can be used for phase analysis of minerals commonly found in deep-sea hydrothermal plumes, even for minerals with similar chemical compositions. It also presents our robust autonomous identification algorithm and spectral database, both of which were developed specifically for deep-sea hydrothermal studies. The Raman spectroscopy expert algorithm was developed and tested against multicomponent mixtures of minerals relevant to the deep-sea hydrothermal environment. It is intended for autonomous classification where many spectra must be examined with little or no human involvement to increase analytic precision, accuracy, and data volume or to enable in situ measurements and experimentation.
    Description: Support for J.A.B. was provided through a RIDGE 2000 Postdoctoral Fellowship (NSF OCE-0550331).
    Keywords: Hydrothermal ; Mineralogy ; Optical instruments ; Raman spectroscopy ; Analytic techniques ; Chemical sensor
    Repository Name: Woods Hole Open Access Server
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  • 5
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 33 (2006): L10608, doi:10.1029/2006GL026048.
    Description: About 90% of Earth's volcanism occurs along the global mid-ocean ridge system. Here, sporadic volcanic and tectonic activity is thought to cause cataclysmic release of hydrothermal fluids, forming event plumes. Each plume often contains as much hydrothermal effluent and heat as chronic hydrothermal venting from a typical vent site discharges during a year. To date, only a few event plumes have been detected, and only above intermediate-rate spreading ridges in the Pacific. Here, we report the first evidence for an unusually large event plume that originated from the slow-spreading (3 cm/yr full-rate) Carlsberg Ridge in the NW Indian Ocean. At 70 km long, up to 4540 km3 in volume and with up to 24 × 1016 J of excess heat, this event plume was substantially larger than previous ones and demonstrates that dispersion of hydrothermal heat and biological products from slow spreading ridges may be more significant and effective than hitherto imagined.
    Description: This work was supported by the Natural Environment Research Council, UK; the National Oceanography Centre, Southampton (NOCS); the NOAA Vents Program.
    Repository Name: Woods Hole Open Access Server
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  • 6
    Publication Date: 2022-10-26
    Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in German, C., Baumberger, T., Lilley, M., Lupton, J., Noble, A., Saito, M., Thurber, A., & Blackman, D. Hydrothermal exploration of the southern Chile Rise: sediment‐hosted venting at the Chile Triple Junction. Geochemistry Geophysics Geosystems, 23(3), (2022): e2021GC010317, https://doi.org/10.1029/2021gc010317.
    Description: We report results from a hydrothermal plume survey along the southernmost Chile Rise from the Guamblin Fracture Zone to the Chile Triple Junction (CTJ) encompassing two segments (93 km cumulative length) of intermediate spreading-rate mid-ocean ridge axis. Our approach used in situ water column sensing (CTD, optical clarity, redox disequilibrium) coupled with sampling for shipboard and shore based geochemical analyses (δ3He, CH4, total dissolvable iron (TDFe) and manganese, (TDMn)) to explore for evidence of seafloor hydrothermal venting. Across the entire survey, the only location at which evidence for submarine venting was detected was at the southernmost limit to the survey. There, the source of a dispersing hydrothermal plume was located at 46°16.5’S, 75°47.9’W, coincident with the CTJ itself. The plume exhibits anomalies in both δ3He and dissolved CH4 but no enrichments in TDFe or TDMn beyond what can be attributed to resuspension of sediments covering the seafloor where the ridge intersects the Chile margin. These results are indicative of sediment-hosted venting at the CTJ.
    Description: We acknowledge University of California Ship Funds for their support of that shiptime and the NOAA Ocean Exploration and Research Grant NA08OAR4600757 which supported the research presented here. Finally, we thank two anonymous reviewers whose important contributions helped to improve the final version of this paper. This is PMEL contribution number 5341.
    Keywords: Hydrothermal ; Geochemistry ; Chile Rise ; Chile Triple Junction ; Sediment hosted
    Repository Name: Woods Hole Open Access Server
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  • 7
    Publication Date: 2022-10-26
    Description: © The Author(s), 2021. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Hayes, C. T., Costa, K. M., Anderson, R. F., Calvo, E., Chase, Z., Demina, L. L., Dutay, J., German, C. R., Heimburger-Boavida, L., Jaccard, S. L., Jacobel, A., Kohfeld, K. E., Kravchishina, M. D., Lippold, J., Mekik, F., Missiaen, L., Pavia, F. J., Paytan, A., Pedrosa-Pamies, R., Petrova, M., V., Rahman, S., Robinson, L. F., Roy-Barman, M., Sanchez-Vidal, A., Shiller, A., Tagliabue, A., Tessin, A. C., van Hulten, M., & Zhang, J. Global ocean sediment composition and burial flux in the deep sea. Global Biogeochemical Cycles, 35(4), (2021): e2020GB006769, https://doi.org/10.1029/2020GB006769.
    Description: Quantitative knowledge about the burial of sedimentary components at the seafloor has wide-ranging implications in ocean science, from global climate to continental weathering. The use of 230Th-normalized fluxes reduces uncertainties that many prior studies faced by accounting for the effects of sediment redistribution by bottom currents and minimizing the impact of age model uncertainty. Here we employ a recently compiled global data set of 230Th-normalized fluxes with an updated database of seafloor surface sediment composition to derive atlases of the deep-sea burial flux of calcium carbonate, biogenic opal, total organic carbon (TOC), nonbiogenic material, iron, mercury, and excess barium (Baxs). The spatial patterns of major component burial are mainly consistent with prior work, but the new quantitative estimates allow evaluations of deep-sea budgets. Our integrated deep-sea burial fluxes are 136 Tg C/yr CaCO3, 153 Tg Si/yr opal, 20Tg C/yr TOC, 220 Mg Hg/yr, and 2.6 Tg Baxs/yr. This opal flux is roughly a factor of 2 increase over previous estimates, with important implications for the global Si cycle. Sedimentary Fe fluxes reflect a mixture of sources including lithogenic material, hydrothermal inputs and authigenic phases. The fluxes of some commonly used paleo-productivity proxies (TOC, biogenic opal, and Baxs) are not well-correlated geographically with satellite-based productivity estimates. Our new compilation of sedimentary fluxes provides detailed regional and global information, which will help refine the understanding of sediment preservation.
    Description: This study was supported by the Past Global Changes (PAGES) project, which in turn received support from the Swiss Academy of Sciences and the US-NSF. The work grew out of a 2018 workshop in Aix-Marseille, France, funded by PAGES, GEOTRACES, SCOR, US-NSF, Aix Marseille Université, and John Cantle Scientific, and the authors would like to acknowledge all attendees of this meeting. The authors acknowledge the participants of the 68th cruise of RV Akademik Mstislav Keldysh for helping acquire samples. Christopher T. Hayes acknowledges support from US-NSF awards 1658445 and 1737023. Some data compilation on Arctic shelf seas was supported by the Russian Science Foundation, grant number 20-17-00157. This work was also supported through project CRESCENDO (grant no. 641816, European Commission). Zanna Chase acknowledges support from the Australian Research Council’s Discovery Projects funding scheme (project DP180102357). Christopher R. German acknowledges US-NSF awards 1235248 and 1234827. Some colorbars used in the figures were designed by Kristen Thyng et al. (2016) and Patrick Rafter.
    Keywords: Barium ; Carbon cycle ; Marine atlas ; Mercury ; Opal ; Sediment burial
    Repository Name: Woods Hole Open Access Server
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  • 8
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2010. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 37 (2010): L18303, doi:10.1029/2010GL043542.
    Description: Inversion of near-bottom magnetic data reveals a well-defined low crustal magnetization zone (LMZ) near a local topographic high (37°47′S, 49°39′E) on the ultraslow-spreading Southwest Indian Ridge (SWIR). The magnetic data were collected by the autonomous underwater vehicle ABE on board R/V DaYangYiHao in February-March 2007. The first active hydrothermal vent field observed on the SWIR is located in Area A within and adjacent to the LMZ at the local topographic high, implying that this LMZ may be the result of hydrothermal alteration of magnetic minerals. The maximum reduction in crustal magnetization is 3 A/M. The spatial extent of the LMZ is estimated to be at least 6.7 × 104 m2, which is larger than that of the LMZs at the TAG vent field on the Mid-Atlantic Ridge (MAR), as well as the Relict Field, Bastille, Dante-Grotto, and New Field vent-sites on the Juan de Fuca Ridge (JdF). The calculated magnetic moment, i.e., the product of the spatial extent and amplitude of crustal magnetization reduction is at least −3 × 107 Am2 for the LMZ on the SWIR, while that for the TAG field on the MAR is −8 × 107 Am2 and that for the four individual vent fields on the JdF range from −5 × 107 to −3 × 107 Am2. Together these results indicate that crustal demagnetization is a common feature of basalt-hosted hydrothermal vent fields at mid-ocean ridges of all spreading rates. Furthermore, the crustal demagnetization of the Area A on the ultraslow-spreading SWIR is comparable in strength to that of the TAG area on the slow-spreading MAR.
    Description: This work was supported by NSF‐China and COMRA Projects 40676023 and DYXM‐115‐02‐03‐02 (JZ and YJC), the Charles D. Hollister Endowed Fund for Support of Innovative Research at WHOI (JL), and the ChEss Program of the Census of Marine Life (CRG).
    Keywords: Reduced magnetization zone ; Southwest Indian Ridge ; Hydrothermal vent
    Repository Name: Woods Hole Open Access Server
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