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  • 1
    Publication Date: 2020-12-17
    Description: Volcanic gas emissions are intimately linked to the dynamics of magma ascent and outgassing and, on geological time scales, constitute an important source of volatiles to the Earth's atmosphere. Measurements of gas composition and flux are therefore critical to both volcano monitoring and to determining the contribution of volcanoes to global geochemical cycles. However, significant gaps remain in our global inventories of volcanic emissions, (particularly for CO2, which requires proximal sampling of a concentrated plume) for those volcanoes where the near‐vent region is hazardous or inaccessible. Unmanned Aerial Systems (UAS) provide a robust and effective solution to proximal sampling of dense volcanic plumes in extreme volcanic environments. Here we present gas compositional data acquired using a gas sensor payload aboard a UAS flown at Volcán Villarrica, Chile. We compare UAS‐derived gas time series to simultaneous crater rim multi‐GAS data and UV camera imagery to investigate early plume evolution. SO2 concentrations measured in the young proximal plume exhibit periodic variations that are well correlated with the concentrations of other species. By combining molar gas ratios (CO2/SO2 = 1.48–1.68, H2O/SO2 = 67–75, and H2O/CO2 = 45–51) with the SO2 flux (142 ± 17 t/day) from UV camera images, we derive CO2 and H2O fluxes of ~150 t/day and ~2,850 t/day, respectively. We observe good agreement between time‐averaged molar gas ratios obtained from simultaneous UAS‐ and ground‐based multi‐GAS acquisitions. However, the UAS measurements made in the young, less diluted plume reveal additional short‐term periodic structure that reflects active degassing through discrete, audible gas exhalations.
    Description: Published
    Description: 730-750
    Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Description: JCR Journal
    Keywords: UAS ; volcanic plume ; villarrica ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2020-12-17
    Description: Ultraviolet imaging has been applied in volcanology over the last ten years or so. This provides considerably higher temporal and spatial resolution volcanic gas emission rate data than available previously, enabling the volcanology community to investigate a range of far faster plume degassing processes than achievable hitherto. To date, this has covered rapid oscillations in passive degassing through conduits and lava lakes, as well as puffing and explosions, facilitating exciting connections to be made for the first time between previously rather separate sub-disciplines of volcanology. Firstly, there has been corroboration between geophysical and degassing datasets at ≈1 Hz, expediting more holistic investigations of volcanic source-process behaviour. Secondly, there has been the combination of surface observations of gas release with fluid dynamic models (numerical, mathematical, and laboratory) for gas flow in conduits, in attempts to link subterranean driving flow processes to surface activity types. There has also been considerable research and development concerning the technique itself, covering error analysis and most recently the adaptation of smartphone sensors for this application, to deliver gas fluxes at a significantly lower instrumental price point than possible previously. At this decadal juncture in the application of UV imaging in volcanology, this article provides an overview of what has been achieved to date as well as a forward look to possible future research directions.
    Description: Published
    Description: Article 68
    Description: 3V. Proprietà dei magmi e dei prodotti vulcanici
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Publication Date: 2022-05-06
    Description: Water vapour (H2O) is the dominant species in volcanic gas plumes. Therefore,measurements of H2O fluxes could provide valuable constraints on subsurface degassing and magmatic processes. However, due to the large and variable concentration of this species in the background atmosphere, little attention has been devoted to monitoring the emission rates of this species from volcanoes. Instead, the focus has been placed on remote measurements of SO2, which is present in far lower abundances in plumes, and therefore provides poorer single flux proxies for overall degassing conditions. Here, we present a new technique for the measurement of H2O emissions at degassing volcanoes at high temporal resolution ( 1 Hz), via remote sensing with low cost digital cameras. This approach is analogous to the use of dual band ultraviolet (UV) cameras for measurements of volcanic SO2 release, but is focused on near infrared absorption by H2O. We report on the field deployment of these devices on La Fossa crater, Vulcano Island, and the North East Crater of Mt. Etna, during which in-plume calibration was performed using a humidity sensor, resulting in estimated mean H2O fluxes of 15 kg s􀀀1 and 34 kg s􀀀1, respectively, in accordance with previously reported literature values. By combining the Etna data with parallel UV camera and Multi-GAS observations, we also derived, for the first time, a combined record of 1 Hz gas fluxes for the three most abundant volcanic gas species: H2O, CO2, and SO2. Spectral analysis of the Etna data revealed oscillations in the passive emissions of all three species, with periods spanning 40–175 s, and a strong degree of correlation between the periodicity manifested in the SO2 and H2O data, potentially related to the similar exsolution depths of these two gases. In contrast, there was a poorer linkage between oscillations in these species and those of CO2, possibly due to the deeper exsolution of carbon dioxide, giving rise to distinct periodic degassing behaviour.
    Description: Published
    Description: Article 146
    Description: 5V. Dinamica dei processi eruttivi e post-eruttivi
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 4
    Publication Date: 2022-05-06
    Description: We would like to thank our colleague, Christoph Kern, for his comment [1] on our recent paper [2], which provides a valuable adjunct to that published piece. In the comment, Kern details the difficulty of measuring water vapour in volcanic plumes at relatively low altitudes, especially considering the importance of in-plume scattering effects [2]. In particular, Kern [1] suggests that our image-based assessments of plume water amounts at Vulcano Island and Mt. Etna may in fact be more related to in-plume scattering, rather than in-plume water vapour column amounts. This said, we would respectfully argue, that as per the work of others, e.g., [3,4], that an empirical relationship between water and measured in-plume scattering can be established, from which trends in flux data can be determined, provided that sufficiently regular calibrations are performed. This was indeed the key message of the article, and in our case calibration was employed. As Kern remarks, the high ambient concentrations of CO2 and H2O in volcanic plumes do present key challenges to remote sensing of these species in volcano plumes. One key mitigating step is to measure plumes at higher altitude, where the overlying atmospheric column of these species will be reduced. Indeed, the possibility of measuring plume water vapour in this scenario has recently been rather elegantly demonstrated, in the case of Sabancaya volcano in Peru, one of the highest sources of volcanic degassing on the planet
    Description: Published
    Description: Article 1040
    Description: 5V. Dinamica dei processi eruttivi e post-eruttivi
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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