Keywords:
Catalysis.
;
Activation (Chemistry).
;
Chemistry, Physical and theoretical.
;
Surface chemistry.
;
Electronic books.
Description / Table of Contents:
Catalysis will be of interest to anyone working in academia and industry that needs an up-to-date critical analysis and summary of catalysis research and applications.
Type of Medium:
Online Resource
Pages:
1 online resource (209 pages)
Edition:
1st ed.
ISBN:
9781847553300
Series Statement:
Issn Series
URL:
https://ebookcentral.proquest.com/lib/geomar/detail.action?docID=1185293
DDC:
541.395
Language:
English
Note:
Catalysis -- Contents -- Chapter 1 Vanadium-Phosphorus-Oxides: from Fundamentals of n-Butane Oxidation to Synthesis of New Phases -- 1 Introduction -- 2 Synthesis of VOHPO40.5H2O Precursor -- 3 Thermal Activation of VOHPO4O.5H2O Precursor -- 3.1 The Role of Conditioning Precursor -- 3.2 The Role of the P/V Ratio -- 4 Models of Active VPO Surface -- 5 Proposed Steps in n-Butane Oxidation to Maleic Anhydride -- 6 Proposed Active Sites and Mechanisms of n-Butane Oxidation -- 7 Effect of Promoters on n-Butane Oxidation Over VPO Catalysts -- 8 New Synthesis Routes to VPO Catalysts -- 8.1 Mesostructured VPO Phases -- 8.2 Macroporus VPO Phases -- 8.3 Intercalation and Pillaring of Layered VPO Phases -- 8.4 Alternative Synthesis Methods of Dense VPO Phases -- 9 Concluding Remarks -- References -- Chapter 2 Use of Solid Catalysts in Promoting Water Treatment and Remediation Technologies -- 1 Introduction -- 1.1 General Aspects of Use of Solid Catalysts in Water Purification Technologies -- 1.2 Perspectives in Using Solid Catalysts for the Treatment of Water -- 2 Water Issue and the Role of Solid Catalysis in Promoting New Technologies -- 2.1 Background -- 2.2 Water Treatment Technologies -- 2.3 Technological Needs for Sustainable Water -- 2.4 The Issue of Water Recycle in Industry -- 3 Conclusions -- References -- Chapter 3 Novel Supported Metal Oxide Adsorbents and Catalysts Prepared from Polynuclear Metal Complexes -- 1 Introduction -- 2 Background -- 3 The Chemistry of Oxide Surfaces -- 4 The Chemistry of Decorating Oxide Surfaces with Metal Complexes - Liquid Phase Technique -- 5 The Chemistry of Decorating Oxide Surfaces with Metal Complexes - Gas Phase Technique -- 6 Quantum Mechanical Modelling - Equilibrium Structures of Isolated Metal Complexes -- 6.1 VO(acac)2 -- 6.2 Cu(acac)2.
,
7 Quantum Mechanical Modelling - Properties of Isolated Metal Complexes -- 7.1 VO(acac)2 -- 8 Quantum Mechanical Modelling - Metal Complexes Decorating the Oxide Surface -- 8.1 Cu(acac)2/silica -- 9 Factors that Influence the Interaction Between the Metal Complex and the Oxide Surface -- 9.1 Stability of Metal Complex -- 9.2 Surface Acidity/Basicity -- 9.3 Choice of Solvent -- 9.4 Ionic Metal Complexes -- 9.5 Hydrogen Bonding -- 10 The Chemistry of Organic Supports -- 10.1 M2+(acac)2, (M = Cu, Co)/C -- 11 Characterization of Supported Metal Complexes -- 11.1 Chemical Analysis of Supported Neutral Metal Complexes -- 11.2 Chemical Analysis of Supported Ionic Metal Complexes -- 11.3 Thermal Analysis -- 11.4 Spectroscopy -- 11.5 XRD -- 11.6 EPR -- 11.7 SQUID -- 11.8 Selective Chemisorption -- 11.9 Chemical Reactions -- 12 Examples of Supported Metal Complexes Drawn from the Literature -- 13 Summary -- 14 Acknowledgements -- References -- Chapter 4 New Opportunity for HC-SCR Technology to Control NOx Emission from Advanced Internal Combustion Engines -- 1 Introduction -- 2 NOx Emission Regulation -- 3 Use of HCs for Catalytic Reduction of NOx -- 3.1 Challenges for HC-SCR Technology up to Early 1980s -- 3.2 Initial Study on the Development of Advanced HC-SCR Technology in Germany -- 3.3 Pioneering Work for the Development of Advanced HC-SCR Technology in Japan -- 4 Catalyst and Reductant -- 4.1 HC-SCR DeNOx Catalysts -- 4.2 Hydrocarbons and Related Compounds -- 5 Deactivation of DeNOx HC-SCR Catalysts by Water Vapor -- 5.1 Water Tolerance of HC-SCR Catalysts -- 5.2 Hydrothermal Stability of HC-SCR DeNOx Catalysts -- 5.3 Beneficial Modification of HC-SCR DeNOx Catalysts to Improve Hydrothermal Stability -- 5.4 Cause for the Deactivation of HC-SCR DeNOx Catalysts by H2O -- 6 Application of HC-SCR DeNOx Technology to Advanced ICEs.
,
7 Summary and Future Direction -- Acknowledgment -- Appendix -- References -- Chapter 5 Catalysis of Solid Oxide Fuel Cells -- 1 Introduction -- 2 Basic Principles of SOFC -- 3 Fuel Cell Performance -- 4 Cathode -- 5 Anode -- 6 Single Chamber Fuel Cell -- 7 Conclusion -- References.
Permalink