Keywords:
Photocatalysis.
;
Semiconductors.
;
Electronic books.
Type of Medium:
Online Resource
Pages:
1 online resource (304 pages)
Edition:
1st ed.
ISBN:
9780443136320
Series Statement:
Woodhead Publishing Series in Electronic and Optical Materials Series
URL:
https://ebookcentral.proquest.com/lib/geomar/detail.action?docID=31088518
DDC:
541.395
Language:
English
Note:
Front Cover -- Full-Spectrum Responsive Photocatalytic Materials -- Copyright Page -- Contents -- List of contributors -- About the authors -- Foreword -- Preface -- Introduction -- 1 Photochemistry: from basic principles to photocatalysis -- 1.1 Introduction -- 1.2 The history and recent development of photocatalysis -- 1.2.1 Photocatalysis -- 1.2.2 History of photocatalysis -- 1.2.3 Broad definition of photocatalysis -- 1.3 Principles of photocatalysis -- 1.3.1 Direct photocatalytic principle -- 1.3.2 Indirect photocatalytic principle -- 1.4 Semiconductor photocatalysts -- 1.4.1 Fundamentals of semiconductor-based photocatalysis -- 1.4.2 Mechanistic insights based on the type of semiconductor photocatalyst -- 1.5 Summary -- References -- 2 Introduction of full spectrum responsive photocatalytic materials -- 2.1 Introduction -- 2.2 The history and recent development of the full spectrum responsive photocatalysis -- 2.3 The working principles of the full spectrum responsive photocatalysis -- 2.3.1 Ultraviolet light-active photocatalysis -- 2.3.2 Visible light-active photocatalysis -- 2.3.3 Near-infrared-light-responsive photocatalysis -- 2.4 Widely used full spectrum responsive photocatalytic materials -- 2.4.1 Black TiO2-based photocatalysts -- 2.4.1.1 Black TiO2 -- 2.4.1.2 Modified black TiO2 photocatalysts -- 2.4.2 ZnIn2S4 (ZIS)-based photocatalysts -- 2.4.2.1 ZnIn2S4 -- 2.4.2.2 Modified ZnIn2S photocatalysts -- 2.4.3 Bismuth-based photocatalysts -- 2.4.3.1 Bismuth photocatalysts -- 2.4.3.2 Bismuth-based heterostructured photocatalysts -- 2.4.4 Metal-free supramolecular photocatalysts -- 2.4.4.1 Graphene-based photocatalysts -- 2.4.4.2 g-C3N4-based photocatalysts -- 2.4.4.3 PDI-based photocatalysts -- 2.4.5 MoSe2-based photocatalysts -- 2.4.5.1 MoSe2 photocatalysts -- 2.4.5.2 MoSe2-based heterostructured catalysts -- 2.4.6 Other photocatalysts.
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2.4.6.1 Upper conversion materials -- 2.4.6.2 Surface plasmon resonance substrate -- 2.5 Summary and outlook -- Acknowledgments -- References -- 3 Strategies to fabricate full spectrum responsive photocatalysts -- 3.1 Introduction -- 3.2 Introducing the surface plasmon resonance effect -- 3.2.1 What is the surface plasmon resonance effect? -- 3.2.2 The influence on plasma effect -- 3.3 Bandgap engineering -- 3.4 Generation of oxygen vacancies -- 3.5 Doping of single and composite systems -- 3.6 Incorporation of upconverting materials -- 3.7 Implementing machine learning methods to accelerate the discovery of full spectrum responsive photocatalysts -- 3.8 Other approaches -- 3.9 The take-home message about the main features of the above strategies -- References -- 4 Synthesis of full spectrum responsive photocatalysts -- 4.1 Introduction -- 4.2 Hydrothermal/solvothermal method -- 4.3 Calcination -- 4.3.1 Thermal polymerization method -- 4.3.2 Czochralski method -- 4.3.3 Molten salt method -- 4.4 Chemical precipitation method -- 4.5 Ultrasonication -- 4.6 Sol-gel method -- 4.7 Microwave-assisted methods -- 4.8 Other methods: physical vapor deposition, chemical vapor deposition, spin-coating, etc -- 4.8.1 Physical vapor deposition -- 4.8.1.1 Ion-beam-enhanced deposition technology -- 4.8.1.2 Electron spark deposition technology -- 4.8.1.3 Electron beam physical vapor deposition -- 4.8.1.4 Multilayer spray deposition -- 4.8.2 Chemical vapor deposition -- 4.8.2.1 Metal-organic compound chemical vapor deposition -- 4.8.2.2 Plasma-enhanced chemical vapor deposition -- 4.8.2.3 Laser chemical vapor deposition -- 4.8.2.4 Low-pressure chemical vapor deposition -- 4.8.2.5 Ultrasound-enhanced chemical vapor deposition -- 4.8.3 Spin-coating -- 4.9 Take home message considering synthesis methods -- References.
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5 Characterization techniques for full-spectrum responsive photocatalysts -- 5.1 Introduction -- 5.2 Microscopic analysis -- 5.2.1 Scanning electron microscope -- 5.2.2 Transmission electron microscope -- 5.2.3 Atomic force microscope -- 5.3 Spectroscopic analysis -- 5.3.1 Electron paramagnetic resonance or electron spin resonance -- 5.3.2 X-ray photoelectron spectroscopy -- 5.3.3 UV/Vis-IR absorption spectra -- 5.3.4 Photoluminescence spectra -- 5.3.5 Time-resolved photoluminescence spectra -- 5.3.6 Raman spectroscopy -- 5.3.7 Fourier-transform infrared spectroscopy -- 5.4 X-ray analysis -- 5.4.1 X-ray powder diffraction -- 5.4.2 X-ray absorption near-edge structure spectrum and the extended X-ray absorption fine structure spectrum -- 5.5 Work function measurement -- 5.6 Thermal analysis -- 5.7 Density-functional theory calculations -- 5.7.1 Computational details -- 5.7.2 Band alignments: HOMO and LUMO level -- 5.7.3 Density of states -- 5.7.4 Binding energy, surface energy, and adsorption energies -- 5.7.5 Free energy -- 5.8 Other technique methods -- 5.9 Take home message about the characterization methods -- References -- 6 Applications in environmental remediation -- 6.1 Introduction -- 6.2 Water treatment -- 6.2.1 Removal of organic pollutants -- 6.2.1.1 Organic dyes -- 6.2.1.2 Phenolic compounds -- 6.2.1.3 Pharmaceuticals and personal care products -- 6.2.2 Photoreduction of heavy metal ions -- 6.2.3 Bacterial inactivation -- 6.3 Air purification -- 6.3.1 NOx removal -- 6.3.2 Decomposing volatile organic compounds -- 6.4 Summary and outlook -- Acknowledgments -- References -- 7 Applications in energy conversion -- 7.1 Introduction -- 7.2 CO2 conversion -- 7.2.1 CO2 photoreduction to CO -- 7.2.2 CO2 photoreduction to HCOOH -- 7.2.3 CO2 photoreduction to CH4 -- 7.2.4 CO2 photoreduction to CH3OH -- 7.2.5 CO2 photoreduction to CO and CH4.
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7.3 H2 evolution -- 7.3.1 H2 evolution from water -- 7.3.2 H2 evolution from ammonia borane -- 7.3.3 H2 production via photoreforming of bioethanol -- 7.4 N2 photo-fixation to NH3 -- 7.5 O2 evolution -- 7.6 Photocatalytic organic transformations: intermediates of high-value chemicals -- 7.7 Summary and outlook -- References -- 8 Novel applications in drug-free sustainable photocatalytic cancer therapy -- 8.1 Introduction -- 8.2 The rise of drug-free photocatalytic cancer therapy -- 8.3 Mechanisms of drug-free photocatalytic cancer therapy -- 8.3.1 Photodynamic therapy: the generation of reactive oxygen species -- 8.3.2 Photocatalytically oxidized H2O2 into O2 and OH -- 8.3.3 Combined hole/hydrogen therapy strategy -- 8.4 Evaluation criteria -- 8.4.1 Antitumor activity -- 8.4.2 Change of tumor microenvironment -- 8.4.3 Biocompatibility/biosafety -- 8.4.4 Others -- 8.5 Summary, challenges, and prospects -- References -- 9 Conclusion and outlook -- 9.1 Limitations of the full spectrum (UV-vis-near-infrared) responsive photocatalytic materials -- 9.1.1 Low efficiency -- 9.1.1.1 Development of semiconductors with narrow bandgap -- 9.1.1.2 Controlling defects in semiconductors -- 9.1.1.3 Plasmon in photocatalysis -- 9.1.2 Limitations in practical applications -- 9.1.2.1 Photocatalytic environmental decontamination -- 9.1.2.2 Photo-electrochemical water splitting -- 9.1.2.3 Photocatalytic CO2 conversion -- 9.1.2.4 Photocatalytic oxidation reactions -- 9.2 Strategies to address the issues -- 9.2.1 Doping of single and heterocomposite systems -- 9.2.2 Plasmon-based semiconductor heterocomposites -- 9.2.3 Semiconductor-based heterocomposite systems with up-conversion materials -- 9.2.4 Metal-containing intricate heterocomposite systems -- 9.2.5 Thermo-photo catalytic composite systems -- 9.3 Future opportunities and outlook -- References -- Appendix.
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Glossary -- Index -- Back Cover.
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