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  • 1
    Publication Date: 2023-06-23
    Description: Magmas vesiculate during ascent, producing complex interconnected pore networks, which can act as outgassing pathways and then deflate or compact to volcanic plugs. Similarly, in-conduit fragmentation events during dome-forming eruptions create open systems transiently, before welding causes pore sealing. The percolation threshold is the first-order transition between closed- and open-system degassing dynamics. Here, we use time-resolved, synchrotron-source X-ray tomography to image synthetic magmas that go through cycles of opening and closing, to constrain the percolation threshold ΦC at a range of melt crystallinity, viscosity and overpressure pertinent to shallow magma ascent. During vesiculation, we observed different percolative regimes for the same initial bulk crystallinity depending on melt viscosity and gas overpressure. At high viscosity (〉 106 Pa s) and high overpressure (~ 1–4 MPa), we found that a brittle-viscous regime dominates in which brittle rupture allows system-spanning coalescence at a low percolation threshold (ΦC~0.17) via the formation of fracture-like bubble chains. Percolation was followed by outgassing and bubble collapse causing densification and isolation of the bubble network, resulting in a hysteresis in the evolution of connectivity with porosity. At low melt viscosity and overpressure, we observed a viscous regime with much higher percolation threshold (ΦC 〉 0.37) due to spherical bubble growth and lower degree of crystal connection. Finally, our results also show that sintering of crystal-free and crystal-bearing magma analogues is characterised by low percolation thresholds (ΦC = 0.04 – 0.10). We conclude that the presence of crystals lowers the percolation threshold during vesiculation and may promote outgassing in shallow, crystal-rich magma at initial stages of Vulcanian and Strombolian eruptions.
    Description: Paul Scherrer Institut http://dx.doi.org/10.13039/501100004219
    Description: European Research Council http://dx.doi.org/10.13039/501100000781
    Description: NERC
    Description: Deutsche Forschungsgemeinschaft
    Keywords: ddc:550.724 ; Effusive-explosive transition ; Percolation threshold ; Outgassing ; Crystal-rich magma ; Magma viscosity ; Gas overpressure ; Porosity ; Pore connectivity ; Hysteresis ; Strombolian/Vulcanian eruptions ; Dome-forming eruptions
    Language: English
    Type: doc-type:article
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  • 2
    Publication Date: 2023-11-23
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Breadcrust bombs formed during Vulcanian eruptions are assumed to originate from the shallow plug or dome. Their rim to core texture reflects the competition between cooling and degassing timescales, which results in a dense crust with isolated vesicles contrasting with a highly vesicular vesicle network in the interior. Due to relatively fast quenching, the crust can shed light on pre‐ and syn‐eruptive conditions prior to or during fragmentation, whereas the interior allows us to explore post‐fragmentation vesiculation. Investigation of pre‐ to post‐fragmentation processes in breadcrust bombs from the 1999 Vulcanian activity at Guagua Pichincha, Ecuador, via 2D and 3D textural analysis reveals a complex vesiculation history, with multiple, spatially localized nucleation and growth events. Large vesicles (Type 1), present in low number density in the crust, are interpreted as pre‐eruptive bubbles formed by outgassing and collapse of a permeable bubble network during ascent or stalling in the plug. Haloes of small, syn‐fragmentation vesicles (Type 2), distributed about large vesicles, are formed by pressurization and enrichment of volatiles in these haloes. The nature of the pressurization process in the plug is discussed in light of seismicity and ground deformation signals, and previous textural and chemical studies. A third population (Type 3) of post‐fragmentation small vesicles appears in the interior of the bomb, and growth and coalescence of Type 2 and 3 vesicles causes the transition from isolated to interconnected bubble network in the interior. We model the evolution of viscosity, bubble growth rate, diffusion timescales, bubble radius and porosity during fragmentation and cooling. These models reveal that thermal quenching dominates in the crust whereas the interior undergoes a viscosity quench caused by degassing, and that the transition from crust to interior corresponds to the onset of percolation and development of permeability in the bubble network.〈/p〉
    Description: Plain Language Summary: Breadcrust bombs are volcanic ejecta formed during explosive volcanic eruptions by rapid cooling of the exterior (the crust) and slow cooling of the interior that causes gas loss, bubble growth and cracking of the exterior. The rapidly cooled crust preserves characteristics of the magma prior to explosion. We study here the variations in porosity and vesicle properties from crust to interior in breadcrust bombs from the Guagua Pichincha volcano in Ecuador. Our results shed light on the pre‐eruptive conditions in the magma prior to explosive activity, and on the post‐fragmentation evolution of the bomb interior by bubble formation.〈/p〉
    Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉Vesicle textures in breadcrust bombs correlate with pre‐ to post‐fragmentation degassing processes during Vulcanian eruptions〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Large isolated vesicles preserved in the crust record a pre‐eruptive episode of outgassing and pressurization prior to fragmentation〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Small vesicles provide insights into post‐fragmentation onset of permeability from the crust to the interior〈/p〉〈/list-item〉 〈/list〉 〈/p〉
    Description: ERC
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Alexander von Humboldt‐Stiftung http://dx.doi.org/10.13039/100005156
    Description: National Science Foundation
    Description: German Research Foundation
    Description: https://doi.org/10.26022/IEDA/112846
    Keywords: ddc:552 ; breadcrust bombs ; Vulcanian eruptions ; vesicle number density ; vesiculation ; bubble nucleation ; fragmentation
    Language: English
    Type: doc-type:article
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  • 3
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Plant breeding 116 (1997), S. 0 
    ISSN: 1439-0523
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Cytoplasmic male sterile (CMS) chicory cybrids have previously been obtained by fusion between chicory and CMS sunflower protoplasts. Preliminary restriction fragment length polymorphism analysis has shown mitochondrial recombination events in CMS plants and their progeny. The aim of this study was to investigate the fate of the mitochondrial genome of the fourth progeny derived from one CMS cybrid. Southern hybridization using several specific mitochondrial sequences as probes have revealed polymorphic patterns between the plants analysed and, consequently, the genetic instability of this genome. Presence of the sequence responsible for cytoplasmic male sterility in sunflower (orf522) was detected by polymerase chain reaction and confirmed by molecular hybridization in the CMS chicory plants; however, its part in CMS expression in chicory did not appear obvious. Moreover, different flowering phenotypes, including completely fertile plants occurred and no correlation could be established between the different mitochondrial profiles and the flowering types. These results suggested some hypotheses and questions about the molecular determinant of CMS in chicory, its regulation and expression and questions about the mitochondrial-nuclear interactions.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Plant breeding 113 (1994), S. 0 
    ISSN: 1439-0523
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: This paper reports on a chlorsulfuron-resistant line of white chicory (Cichorium intybus cv. ‘Witloof’) regenerated from non-mutagenized cell cultures. The resistance was inherited as a monogenic semi-dominant trait. Homozygous resistant individuals withstood doses of herbicide 1500 to 2000-fold higher than the susceptible ones, whereas this ratio was around 300 for the heterozygotes. Cross-resistances to seven other sulfonylureas and to one imidazolinone were revealed, leading to the conclusion that this resistance could be due to mutation of the target enzyme.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of natural products 55 (1992), S. 33-38 
    ISSN: 1520-6025
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of food science 58 (1993), S. 0 
    ISSN: 1750-3841
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The method is based on equilibration of the sample with an atmosphere of pure water vapor at constant pressure. Water activity is calculated from the sample temperature at equilibrium. A curve describing ×= f(aw) at constant water vapor pressure (isobar) was established for microcrystalline cellulose and potato starch, within the range 100–150°C. The precision of the method was evaluated and an empirical model, based on the GAB equation, was developed to fit experimental data. Determination were specifically with isobars at 1 bar, but isobars at other pressures could be determined by modifying the system.
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] The detector consists of a multiplate spark chamber (thirteen plates of thickness 0.033 radiation lengths and area 850 cm2), shielded by an anticoincidence scintillation counter. The chamber is triggered by the coincidence telescope of a plastic scintillation counter (500 cm2) and a directional ...
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Phytochemistry 32 (1993), S. 929-931 
    ISSN: 0031-9422
    Keywords: (+)-catechin ; (-)-epicatechin ; (-)-epicatechin-3-O-gallate ; Fagopyrum esculentum ; Polygonaceae ; flavanols ; procyanidin B2 ; procyanidin B2-3
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Biology , Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Phytochemistry 31 (1992), S. 1239-1241 
    ISSN: 0031-9422
    Keywords: (+)-catechin ; (-)-epicatechin ; (-)-epicatechin-3-O-gallate production ; Fagopyrum esculentum ; Polygonaceae ; callus ; plant tissue culture ; polyphenols
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Biology , Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Biochemical and Biophysical Research Communications 134 (1986), S. 1204-1208 
    ISSN: 0006-291X
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Biology , Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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