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  • 1
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Inc
    Journal of metamorphic geology 19 (2001), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Primary multiphase brine fluid inclusions in omphacite and garnet from low- to medium-temperature eclogites have been analysed for Cl, Br, I, F, Li and SO4. Halogen contents and ratios provide information about trapped lower crustal fluids, even though the major element (Na, K, Ca) contents of inclusion fluids have been modified by fluid–mineral interactions and (step-) daughter-crystal formation after trapping. Halogens in the inclusion fluids were analysed with crush–leach techniques. Cl/Br and Cl/I mass ratios of eclogite fluids are in the range 31–395 and 5000–33 000, respectively. Most fluids have a Cl/Br ratio lower than modern seawater and a Cl/I ratio one order of magnitude lower than modern seawater. Fluids with the lowest Cl/Br and highest Cl/I ratios come from an eclogite that formed by hydration of granulite facies rocks, and may indicate that Br and I are fractionated into hydrous minerals. Reconstructions indicate that the inclusion fluids originally contained 500–4000 ppm Br, 1–14 ppm I and 33–438 ppm Li. Electron microprobe analyses of eclogite facies amphibole, biotite, phengite and apatite indicate that F and Cl fractionate most strongly between phengite (F/Cl mass ratio of 1469 ± 1048) and fluid (F/Cl mass ratio of 0.008), and the least between amphibole and fluid. The chemical evolution of Cl and Br in pore fluids during hydration reactions is in many ways analogous to Cl and Br in seawater during evaporation: the Cl/Br ratio remains constant until the aH2O value is sufficiently lowered for Cl to be removed from solution by incorporation into hydrous minerals.
    Type of Medium: Electronic Resource
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  • 2
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    Unknown
    PANGAEA
    In:  Supplement to: Mazzini, Adriano; Svensen, H H; Planke, Sverre; Forsberg, Carl Fredrik; Tjelta, T I (2016): Pockmarks and methanogenic carbonates above the giant Troll gas field in the Norwegian North Sea. Marine Geology, 373, 26-38, https://doi.org/10.1016/j.margeo.2015.12.012
    Publication Date: 2023-01-13
    Description: Acoustic imaging has revealed more than 7000 pockmarks on the seafloor above the Troll East gas field in the Norwegian North Sea. We present the first comprehensive study conducted on one of the World's largest pockmark fields complementing the acoustic data with extensive sampling, geochemical and petrographical studies. Specifically, we aimed at detecting possible active seepage still present over this vast area. The pockmarks are present as isolated structures, on average ~ 35 m wide and up to 100 m in size. In addition, smaller satellite pockmarks surround some of the pockmarks. In contrast to the muddy surroundings, parts of the investigated pockmarks contain laterally extensive carbonate deposits or meter sized carbonate blocks. These blocks provide shelter to abundant colonies of benthic megafauna. The carbonate blocks are comprised of micritic Mg-calcite and calcite, micritic aragonite, and botryoidal aragonite. Framboidal pyrite is also commonly present. Carbon isotopic values of the carbonates are 13C-depleted (d13C as low as - 59.7per mil) and with d18O up to 4.5per mil, indicating a methanogenic origin, possibly linked to gas hydrate dissociation. Pore water extracted from shallow cores from the centre and the flanks of the pockmarks show similar Cl and SO4 profiles as the reference cores outside the pockmarks, ruling out active methane seepage. This conclusion is also supported by seafloor video observations that did not reveal any evidence of visual fluid seepage, and by the absence of microbial mats and by the fact that the carbonate blocks are exposed on the seafloor and party oxidized on the surface. We conclude that methane seepage formed this extensive gas field following to gas hydrate dissociation.
    Type: Dataset
    Format: application/zip, 4 datasets
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  • 3
    Publication Date: 2023-01-13
    Keywords: B53-2; B610-8; B612-1; B67-4; B67-6; Biological sample; BIOS; CARB; Carbonate; Event label; Latitude of event; Longitude of event; North Sea Norwegian Sea; Sample comment; Strontium-87/Strontium-86 ratio; δ13C; δ18O
    Type: Dataset
    Format: text/tab-separated-values, 57 data points
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  • 4
    Publication Date: 2023-02-07
    Keywords: Bromine; Calcium; Carbon, inorganic, total; Carbon, organic, total; Carbon, total; Chlorine; Core; CORE; Depth, bottom/max; DEPTH, sediment/rock; Depth, top/min; DWS201A; DWS202A; DWS203A; DWS210A; Event label; Latitude of event; Longitude of event; North Sea Norwegian Sea; Potassium; Sample ID; Sample position; Sodium; Sulfate; δ13C, total inorganic carbon; δ18O, water; δ Deuterium
    Type: Dataset
    Format: text/tab-separated-values, 587 data points
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  • 5
    Publication Date: 2023-02-07
    Keywords: Bromine; Chlorine; Core; CORE; Depth, bottom/max; DEPTH, sediment/rock; Depth, top/min; DWS201; DWS202; DWS203; DWS204; DWS205; DWS206; DWS207; DWS208; DWS209; Event label; Latitude of event; Longitude of event; North Sea Norwegian Sea; Sample ID; Sample position; Sulfate; δ13C, total inorganic carbon; δ18O, water; δ Deuterium
    Type: Dataset
    Format: text/tab-separated-values, 694 data points
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  • 6
    Publication Date: 2023-02-12
    Keywords: B610-8; B612-1; Biological sample; BIOS; Calcium; Calcium oxide; CARB; Carbonate; Description; Electron microprobe (EMP); Event label; Iron 2+; Iron oxide, FeO; Latitude of event; Longitude of event; Magnesium; Magnesium oxide; Manganese 2+; Manganese oxide; Minerals; North Sea Norwegian Sea; Sample comment; Strontium; Strontium oxide; Sum; Total
    Type: Dataset
    Format: text/tab-separated-values, 630 data points
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  • 7
    Publication Date: 2017-04-04
    Description: The Salton Sea Geothermal System (California) is an easily accessible setting for investigating the interactions of biotic and abiogenic geochemical processes in sediment-hosted hydrothermal systems. We present new temperature data and the molecular and isotopic composition of fluids seeping at the Davis-Schrimpf seep field during 2003–2008. Additionally, we show the first flux data for CO2 and CH4 released throughout the field from focused vents and diffuse soil degassing. The emitted gases are dominated by CO2 (~98%) and CH4 (~1.5%). By combining δ13CCO2 (as low as −5.4‰) and δ13CCH4 (−32‰to−17.6‰) with 3He/4He (R/RaN6) and δDCH4 values (−216‰to−150‰), we suggest, in contrast to previous studies, that CO2 may have a significant Sub-Continental Mantle source, with minimal crustal contamination, and CH4 seems to be a mixture of high temperature pyrolitic (thermogenic) and abiogenic gas. Water seeps show that δD and δ18O increase proportionally with salinity (Total Dissolved Solids in g/L) ranging from 1–3 g/L (gryphons) to 145 g/L (hypersaline pools). In agreement with elemental analyses, the isotopic composition of the waters indicate a meteoric origin, modified by surface evaporation, with little or no evidence of deep fossil or magmatic components. Very high Cl/Br (N3,000) measured at many seeping waters suggests that increased salinities result from dissolution of halite crusts near the seep sites. Gas flux measurements from 91 vents (pools and gryphons) give a conservative estimate of ~2,100 kg of CO2 and 11.5 kg of CH4 emitted per day. In addition soil degassing measured at 81 stations (20x20 m grid over 51,000 m2) revealed that 7,310 kg/d CO2 and 33 kg/d CH4 are pervasively released to the atmosphere. These results emphasise that diffuse gas emission from soil can be dominant (~75%) even in hydrothermal systems with large and vigorous gas venting. Sediment-hosted hydrothermal systems may represent an intermediate class of geologic methane sources for the atmosphere, with emission factors lower than those of sedimentary seepage in petroleum basins but higher than those of traditional geothermal-volcanic systems; on a global scale they may significantly contribute to the atmospheric methane budget.
    Description: Published
    Description: 67-83
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: Salton Sea Geothermal System ; hydrothermal seeps ; gas and water geochemistry ; flux measurements ; mantle ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 8
    Publication Date: 2017-04-04
    Description: The 29th of May 2006 gas and mud eruptions suddenly appeared along the Watukosek fault in the north east of Java, Indonesia. Within a few weeks several villages were submerged by boiling mud. The most prominent eruption site was named Lusi. To date (November 2011) Lusi is still active and a ~7 km2 area is covered by the burst mud breccia. The mechanisms responsible for this devastating eruption remain elusive. While there is consensus about the origin of the erupted mud, the source of water is uncertain, the origin of the gas is unknown and the trigger of the eruption is still debated. In order to shed light on these unknowns, we acquired a wide set of data of molecular and isotopic composition of gas sampled in several Lusi vents, in the surrounding mud volcanoes, in the closest natural gas field (Wunut), and in the hydrothermal vents at the neighbouring volcanic complex in the period 2006–2011. The boiling fluids erupted in the crater zone are apparently CO2-dominated, while colder CH4-dominated and C2–C3 bearing fluids are identified at several sites around the crater zone. Gas genetic diagrams, maturity plots and gas generation modelling suggest that the hydrocarbons are thermogenic (δ¹³C1 up to −35‰; δ¹³C2 up to −20‰), deriving from marine kerogen with maturity of at least 1.5%Ro, for instance in the ~4400 m deep Ngimbang source rocks. CO2 released from the crater and surrounding seeps is also thermogenic (δ¹³C from −15 to −24‰) related to kerogen decarboxylation or thermal CH4 oxidation in deep rocks, although three vents just outside the crater showed an apparent inorganic signature (−7.5 ‰〈 δ¹³C=−0.5‰) associated to mantle helium (R/Ra up to 6.5). High CO2–CH4 equilibrium temperatures (200–400 °C) are typical of thermally altered hydrocarbons or organic matter. The data suggest mainly thermally altered organic sources for the erupted gases, deeper sourced than the mud and water (Upper Kalibeng shales). These results are consistent with a scenario of deep seated (〉4000 m) magmatic intrusions and hydrothermal fluids responsible for the enhanced heat that altered source rocks and/or gas reservoirs. The neighbouring magmatic Arjuno complex and its fluid–pressure system combined with high seismic activity could have played a key role in the Lusi genesis and evolution. Within this new model framework, Lusi is better understood as a sediment-hosted hydrothermal system rather than a mud volcano.
    Description: Published
    Description: 305–318
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: Lusi eruption ; sediment-hosted hydrothermal system ; mud volcanoes ; gas origin ; CO2 and CH4 ; mantle ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 9
  • 10
    Publication Date: 2017-07-21
    Description: Targeted sampling on the Dolgovskoy Mound (northern Shatsky Ridge) revealed the presence of spectacular laterally extensive and differently shaped authigenic carbonates. The sampling stations were selected based on sidescan sonar and profiler images that show patchy backscatter and irregular and discontinuous reflections in the near subsurface. The interpretation of acoustic data from the top part of the mound supports the seafloor observations and the sampling that revealed the presence of a complex subsurface plumbing system characterized by carbonates and gas. The crusts sampled consist of carbonate cemented layered hemipelagic sedimentary Unit 1 associated with several centimetres thick microbial mats. Three different carbonate morphologies were observed: (a) tabular slabs, (b) subsurface cavernous carbonates consisting of void chambers up to 20 cm3 in size and (c) chimney and tubular conduits vertically oriented or forming a subhorizontal network in the subsurface. The methanogenic origin of the carbonates is established based on visual observations of fluids seepage structures, 13C depletion of the carbonates (δ13C varying between −36.7‰ and −27.4‰), and by thin carbonate layers present within the thick microbial mats. Laboratory experiments with a Hele–Shaw cell were conducted in order to simulate the gas seepage through contrasting grain size media present on the seafloor. Combined petrography, visual observations and sandbox simulations allowed a characterization of the dynamics and the structures of the plumbing system in the near subsurface. Based on sample observations and the experiments, three observed morphologies of authigenic carbonates are interpreted, respectively, as (a) Darcian porous flow through the finely laminated clayey/coccolith-rich layers, (b) gas accumulation chambers at sites where significant fluid escape was impeded by thicker clayey layers forming the laminated Unit1 and (c) focussed vertical fluid venting and subhorizontal migration of overpressured fluids released from (b). The Hele–Shaw cell experiments represent a promising tool for investigating shallow fluid flow pathways in marine systems.
    Type: Article , PeerReviewed
    Format: text
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