ISSN:
1572-901X
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Summary Acis-α configuration for the [RuCl2(trien)]Cl·2H2O (trien=1, 8-diamino-3, 6-diazaoctane) complex has been confirmed by an x-ray crystal structure determination. Crystals are monoclinic, space group P21/c witha=7.336 (1),b=8.477 (2),c=23.181 (4) Å, β=103.3 (1)°, U=1403 (1) Å.3 Z=4 and M=389.7, Dc=1.84 g cm−3. The structure was refined by full matrix least squares methods to final residual values of R=0.025 and Rw=0.033 on the basis of 3882 unique reflections. The complex has been resolved into its optical isomers using the (+)1, 2-diaminoethanebis(oxalato)cobaltate(III) anion and the absolute configuration assigned.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01024036
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