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  • 1
    Publication Date: 2017-04-04
    Description: Measurements of 220Rn and 222Rn activity and of CO2 flux in soil and fumaroles were carried out on Mount Etna volcano in 2005–2006, both in its summit area and along active faults on its flanks. We observe an empirical relationship between (220Rn/222Rn) and CO2 efflux. The higher the flux of CO2, the lower the ratio between 220Rn and 222Rn. Deep sources of gas are characterized by high 222Rn activity and high CO2 efflux, whereas shallow sources are indicated by high 220Rn activity and relatively low CO2 efflux. Excess 220Rn highlights sites of ongoing shallow rock fracturing that could be affected by collapse, as in the case of the rim of an active vent. Depletion both in 220Rn and in CO2 seems to be representative of residual degassing along recently active eruptive vents.
    Description: Published
    Description: Q10001
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: radon ; thoron ; carbon dioxide ; rock stress ; gas transport ; Mount Etna ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2020-02-24
    Description: Measurements of 220Rn and 222Rn activity and of CO2 flux in soil and fumaroles were carried out on Mount Etna volcano in 2005–2006, both in its summit area and along active faults on its flanks. We observe an empirical relationship between (220Rn/222Rn) and CO2 efflux. The higher the flux of CO2, the lower the ratio between 220Rn and 222Rn. Deep sources of gas are characterized by high 222Rn activity and high CO2 efflux, whereas shallow sources are indicated by high 220Rn activity and relatively low CO2 efflux. Excess 220Rn highlights sites of ongoing shallow rock fracturing that could be affected by collapse, as in the case of the rim of an active vent. Depletion both in 220Rn and in CO2 seems to be representative of residual degassing along recently active eruptive vents.
    Description: This work was funded by the Istituto Nazionale di Geofisica e Vulcanologia (S.G., M.N.) and by the Dipartimento per la Protezione Civile (Italy), projects V3_6/28-Etna (M.N.) and V5/08-Diffuse degassing in Italy (S.G.), and NSF EAR 063824101 (K.W.W.S.).
    Description: Published
    Description: Q10001
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: radon ; thoron ; carbon dioxide ; rock stress ; gas transport ; Mount Etna ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Publication Date: 2021-07-21
    Description: The Tierra Blanca (TB) eruptive suite comprises the last four major eruptions of Ilopango caldera in El Salvador (≤45 ka), including the youngest Tierra Blanca Joven eruption (TBJ; ∼106 km3): the most voluminous event during the Holocene in Central America. Despite the protracted and productive history of explosive silicic eruptions at Ilopango caldera, many aspects regarding the longevity and the prevailing physicochemical conditions of the underlying magmatic system remain unknown. Zircon 238U‐230Th geochronology of the TB suite (TBJ, TB2, TB3, and TB4) reveals a continuous and overlapping crystallization history among individual eruptions, suggesting persistent melt presence in thermally and compositionally distinct magma reservoirs over the last ca. 80 kyr. The longevity of zircon is in contrast to previously determined crystallization timescales of 〈10 kyr for major mineral phases in TBJ. This dichotomy is explained by a process of rhyolitic melt segregation from a crystal‐rich refractory residue that incorporates zircon, whereas a new generation of major mineral phases crystallized shortly before eruption. Ti‐in‐zircon temperatures and amphibole geothermobarometry suggest that rhyolitic melt was extracted from different storage zones of the magma reservoir as indicated by distinct but synchronous thermochemical zircon histories among the TB suite eruptions. Zircon from TBJ and TB2 suggests magma differentiation within deeper and hotter parts of the reservoir, whereas zircon from TB3 and TB4 instead hints at crystallization in comparatively shallower and cooler domains. The assembly of the voluminous TBJ magma reservoir was also likely enhanced by cannibalization of hydrothermally altered components as suggested by low‐δ18O values in zircon (+4.5 ± 0.3‰).
    Description: Plain Language Summary: The collapse of a volcano edifice into its shallow magma chamber can produce one of the most dangerous single events in nature, known as a caldera‐forming eruption. The TBJ eruption in El Salvador is of this kind and occurred around 1,500 years ago, having a profound impact on Maya societies. Because of this, it is crucial to understand the inner workings of caldera‐forming eruptions to assess volcanic risks and their mitigation. Beneath Ilopango caldera, the micrometer‐sized radioisotopically datable mineral zircon grew within different storage levels of a silica‐rich magma reservoir suggesting continuous melt presence for up to ca. 80,000 years prior to eruption. The time information given by zircon contrasts with that extracted from other, more abundant minerals from the same rocks (〈10,000 years). We explain this time difference between coexisting minerals by the ability of melt to carry along small zircon crystals, whereas coeval, larger, and more abundant minerals are left behind in the partially solidified portion of the magma reservoir. Once the segregated melt coalesced in a shallower and dominantly liquid magma chamber, major minerals resumed crystallization shortly before eruption. In addition, this new magma incorporated parts of older magmatic rocks from preceding volcanic cycles, thus generating even larger magma volumes.
    Description: Key Points: U‐Th zircon ages for the last four explosive eruptions of Ilopango caldera reveal a long‐lived magma reservoir (〉80 kyr). Contrasting residence times for major minerals and zircon suggest extraction of zircon along with evolved melt from crystal residue. Melt extraction from vertically extensive, thermally zoned magma reservoir.
    Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659
    Keywords: 549 ; 551.701 ; Central America ; Geochemistry ; Oxygen isotopes ; SIMS ; U‐series ; Zircon
    Type: article
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  • 4
    Publication Date: 2019-02-01
    Description: Highlights • 238U-230Th-226Ra disequilibria in lavas from Northern Kolbeinsey Ridge (Eggvin Bank) support an eclogite-rich mantle source. • Jan Mayen Island lavas are likely the product of upwelling in a mantle plume containing moderate quantities of eclogite. • Low (226Ra/230Th) ratios in global OIB may be explained by the widespread influence of mafic rocks in deep mantle plumes. Abstract Sensitivity to rates of melting and to the presence of garnet in the melting residue makes U-series isotope disequilibrium a helpful tool for assessing the presence and role of mantle eclogite rocks in generating magmatic crust at both mid-ocean ridges and hotspots. Here we present 238U-234U-230Th-226Ra-210Pb isotope disequilibria data for a suite of fresh lavas from the tectonically and geochemically complex Jan Mayen region, including Jan Mayen Island; the Northern Kolbeinsey Ridge, which hosts the anomalous Eggvin Bank bathymetric high; and the Southern Mohns Ridge. Age-constrained, unaltered samples from the Northern Kolbeinsey Ridge and Eggvin Bank, including fresh popping rocks from Eggvin Bank, are characterized by relatively high (230Th/238U) = 1.23 to 1.36 and low (226Ra/230Th) = 1.24 to 1.28. These data are best explained by contributions to magma mixtures from an eclogite-dominated, upwelling mantle source with only modest aging or crystal fractionation effects during transport or storage in the crust. Young lavas from Jan Mayen Island have lower (230Th/238U) = 1.15 and (226Ra/230Th) = 1.05 to 1.16, and forward modeling suggests a detectible, but smaller mafic source contribution to a peridotitic magma mixture in faster upwelling mantle. Globally, most ocean island basalts also show low (226Ra/230Th) disequilibria, suggesting that in addition to high upwelling rates, mafic lithologies make significant melt contributions at most hotspots and that upwelling mantle plumes likely entrain highly fusible, recycled mafic rocks. Eggvin Bank apparently overlies a highly unusual mantle source that likely contains a remnant of delaminated, formerly underplated, ancient subcratonic mafic rocks, entrained by upwelling beneath the northernmost Kolbeinsey Ridge.
    Type: Article , PeerReviewed
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  • 5
    Publication Date: 2017-09-27
    Description: To examine the petrogenesis and sources of basalts from the Kolbeinsey Ridge, one of the shallowest locations along the global ridge system, we present new measurements of Nd, Sr, Hf, and Pb isotopes and U-series disequilibria on 32 axial basalts. Young Kolbeinsey basalts (full-spreading rate = 1.8 cm/yr; 67°05′–70°26′N) display (230Th/238U) 〈 1 and (230Th/238U) 〉 1 with (230Th/238U) from 0.95 to 1.30 and have low U (11.3–65.6 ppb) and Th (33.0 ppb–2.40 ppm) concentrations. Except for characteristic isotopic enrichment near the Jan Mayen region, the otherwise depleted Kolbeinsey basalts (e.g. 87Sr/86Sr = 0.70272–0.70301, εNd = 8.4–10.5, εHf = 15.4–19.6 (La/Yb)N = 0.28–0.84) encompass a narrow range of (230Th/232Th) (1.20–1.32) over a large range in (238U/232Th) (0.94–1.32), producing a horizontal array on a (230Th/232Th) vs. (238U/232Th) diagram and a large variation in (230Th/238U). However, the (230Th/238U) of the Kolbeinsey Ridge basalts (0.96–1.30) are inversely correlated with (234U/238U) (1.001–1.031). Samples with low (230Th/238U) and elevated (234U/238U) reflect alteration by seawater or seawater-derived materials. The unaltered Kolbeinsey lavas with equilibrium 234U/238U have high (230Th/238U) values (〉=1.2), which are consistent with melting in the presence of garnet. This is in keeping with the thick crust and anomalously shallow axial depth for the Kolbeinsey Ridge, which is thought to be the product of large degrees of melting in a long melt column. A time-dependent, dynamic melting scenario involving a long, slowly upwelling melting column that initiates well within the garnet peridotite stability zone can, in general, reproduce the (230Th/238U) and (231Pa/235U) ratios in uncontaminated Kolbeinsey lavas, but low (231Pa/235U) ratios in Eggvin Bank samples suggest eclogite involvement in the source for that ridge segment.
    Type: Article , PeerReviewed
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  • 6
    Publication Date: 2013-06-27
    Type: Conference or Workshop Item , NonPeerReviewed
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  • 7
    Publication Date: 2013-06-27
    Type: Conference or Workshop Item , NonPeerReviewed
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  • 8
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    European Association of Geochemistry
    In:  Geochemical Perspectives Letters, 2 (1). pp. 55-67.
    Publication Date: 2019-09-23
    Description: At slow to ultraslow spreading rates along mid-ocean ridges, thicker lithosphere typically impedes magma generation and tectonic extension can play a more significant role in crustal production (Dick et al., 2003). The source of anomalously high magma supply thus remains unclear along ridges with ultraslow-spreading rates adjacent to Jan Mayen Island in the North Atlantic (Neumann and Schilling, 1984; Mertz et al., 1991; Haase et al., 1996; Schilling et al., 1999; Trønnes et al., 1999; Haase et al., 2003; Mertz et al., 2004; Blichert-Toft et al., 2005; Debaille et al., 2009). Here we show that Jan Mayen volcanism is likely the surface expression of a small mantle plume, which exerts significant influence on nearby mid-ocean ridge tectonics and volcanism. Progressive dilution of Jan Mayen geochemical signatures with distance from the hotspot is observed in lava samples from the immediately adjacent Mohns Ridge, and morphological indicators of enhanced magma supply are observed on both the Mohns Ridge and the nearby Kolbeinsey Ridge, which additionally locally overlies a highly heterogeneous, eclogite-bearing mantle source. These morphological and geochemical influences underscore the importance of heterogeneous mantle sources in modifying melt supply and thus the local expression of tectonic boundaries.
    Type: Article , PeerReviewed
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  • 9
    Publication Date: 2016-11-08
    Description: Sr provides unique constraints on subduction magma source models because it is a fluid-mobile element that is abundant and relatively unradiogenic in arc volcanic rocks. It is common for arc basalts to be 3-4-times more Sr-rich than similarly evolved MORB (Sr/Nd = 30-50 vs 10-15 in MORB) yet Sr isotopes in arc basalts are usually offset from MORB only slightly ( Sr/ Sr ~0.7034 vs 0.7028 for MORB). This is a puzzle because abundant sources of subducted Sr in sediment (GLOSS II Sr/ Sr = 0.712) and altered oceanic crust ( Sr/ Sr = 0.704-0.705) are more radiogenic than average arc basalts globally ( Sr/ Sr ~ 0.7034)...
    Type: Conference or Workshop Item , NonPeerReviewed
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  • 10
    Publication Date: 2024-02-07
    Description: The Tierra Blanca (TB) eruptive suite comprises the last four major eruptions of Ilopango caldera in El Salvador (≤45 ka), including the youngest Tierra Blanca Joven eruption (TBJ; ∼106 km3): the most voluminous event during the Holocene in Central America. Despite the protracted and productive history of explosive silicic eruptions at Ilopango caldera, many aspects regarding the longevity and the prevailing physicochemical conditions of the underlying magmatic system remain unknown. Zircon 238U-230Th geochronology of the TB suite (TBJ, TB2, TB3, and TB4) reveals a continuous and overlapping crystallization history among individual eruptions, suggesting persistent melt presence in thermally and compositionally distinct magma reservoirs over the last ca. 80 kyr. The longevity of zircon is in contrast to previously determined crystallization timescales of 〈10 kyr for major mineral phases in TBJ. This dichotomy is explained by a process of rhyolitic melt segregation from a crystal-rich refractory residue that incorporates zircon, whereas a new generation of major mineral phases crystallized shortly before eruption. Ti-in-zircon temperatures and amphibole geothermobarometry suggest that rhyolitic melt was extracted from different storage zones of the magma reservoir as indicated by distinct but synchronous thermochemical zircon histories among the TB suite eruptions. Zircon from TBJ and TB2 suggests magma differentiation within deeper and hotter parts of the reservoir, whereas zircon from TB3 and TB4 instead hints at crystallization in comparatively shallower and cooler domains. The assembly of the voluminous TBJ magma reservoir was also likely enhanced by cannibalization of hydrothermally altered components as suggested by low-δ18O values in zircon (+4.5 ± 0.3‰).
    Type: Article , PeerReviewed
    Format: text
    Format: archive
    Format: archive
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