ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Zero-current counter-transport studies as well as electrodialytic transport experiments on solvent polymeric membranes doped with ionophores for anions have been carried out and were compared with potentiometric measurements on the same membranes. A theoretical description of the observed phenomena corroborates that lipophilic complexes of Co(III) (e. g. aquacyano[heptakis(2-phenylethyl)]Co(III) cobyrinate perchlorate) and Mn(III) (e. g. lipophilic Mn(III)porphyrin complexes) act as positively charged carriers for anions, whereas a lipophilic Ru(II)porphyrin complex has to be described as an electrically neutral carrier for anions.
Additional Material:
10 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19900730528
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