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  • 1
    Publication Date: 2020-02-12
    Description: In this project we aim to develop a low-cost technology to remove ionic constituents from raw waters such as arsenic species. The proposed technology is based on the reactivity of schwertmannite, an oxyhydroxosulfate of the mean stochiometry Fe8O8(OH)6SO4 (molar mass 772.89 g/mol). This mineral typically forms in acidic and sulfate rich mine waters as a secondary mineral upon oxidation of Fe(II) in a biologically mediated process. Schwertmannite can be generated in a biotechnological process after aeration of mining process waters. It forms surface-rich aggregates of needle-like nanocrystals. It rapidly transforms into ferric hydroxides of high specific surface area once exposed to water containing at least some alkalinity. Our rationale follows the concept to make use of this transformation reaction by adding biosynthesized schwertmannite to contaminated raw waters where it generates a large sorption capacity to remove the pollutants (Peiffer et al., 2008).
    Language: English
    Type: info:eu-repo/semantics/conferenceObject
    Format: application/pdf
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  • 2
    Publication Date: 2021-07-30
    Description: The perovskite SrRuO3 is a prototypical itinerant ferromagnet which allows interface engineering of its electronic and magnetic properties. We report the synthesis and investigation of atomically flat artificial multilayers of SrRuO3 with the spin-orbit semimetal SrIrO3 in combination with band-structure calculations with a Hubbard U term and topological analysis. The latter reveal an electronic reconstruction and emergence of flat Ru-4dxz bands near the interface, ferromagnetic interlayer coupling, and a negative Berry-curvature contribution to the anomalous Hall effect. We analyze the Hall effect and magnetoresistance measurements as a function of the field angle from an out-of-plane towards an in-plane orientation (either parallel or perpendicular to the current direction) by a two-channel model. The magnetic easy direction is tilted by about 20∘ from the sample normal for low magnetic fields, rotating towards the out-of-plane direction by increasing fields. Fully strained epitaxial growth enables a strong anisotropy of magnetoresistance. An additional Hall effect contribution, not accounted for by the two-channel model, is compatible with stable skyrmions only up to a critical angle of roughly 45∘ from the sample normal. Within about 20∘ from the thin film plane an additional peaklike contribution to the Hall effect suggests the formation of a nontrivial spin structure.
    Type: info:eu-repo/semantics/article
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