Note: INORGANIC SYNTHESES Volume XV -- CONTENTS -- Preface -- Notice to Contributors -- Chapter One METAL COMPLEXES OF OLEFINS -- 1. Bis(1,3,5,7-cyclooctatetraene)iron(0) -- 2. Bis(1,5-cyclooctadiene)nickel(0) -- 3. Ethylenebis(tri-o-tolyl phosphite)nickel(0) and Tris(tri-o-tolyl phosphite)- nickel(0) -- A. Ethylenebis(tri-o-tolyl phosphite)nickel(0) -- B. Tris(tri-o-tolyl phosphite)nickel(0) -- C. Tris(tri-o-tolyl phosphite)nickel(0) -- 4. Di-u-chlorotetrakis(ethylene)dirhodium(I), 2,4-Pentanedionatobis(ethylene)- rhodium(I), and Di-u-chlorotetracarbonyldirhodium(I) -- A. Di-u-chlorotetrakis(ethylene)dirhodium(I) -- B. 2,4-Pentanedionatobis(ethylene)rhodium(I) -- C. Di-u-chlorotetracarbonyldirhodium(I) -- 5. Cyclooctene and 1,5-Cyclooctadiene Complexes of Iridium(I) -- A. Di-u-chloro-bis(l,5-cyclooctadiene)diiridium(I) -- B. Di-u-chlorotetrakis(cyclooctene)diiridium(I) -- Chapter Two METAL COMPLEXES OF DINITROGEN AND OF HYDROGEN -- 6. trans-(Dinitrogen)bis[ethylenebis(diethylphosphine}]hydridoiron(II) Tetraphenylborate -- A. trans-Dichlorobis[ethylenebis(diethylphosphine)]iron(II) -- B. trans-Chlorobis[ethylenebis(diethylphosphine)]hydridoiron(II) -- C. trans-(Dinitrogen)bis[ethylenebis(diethylphosphine)]hydridoiron(II) Tetraphenylborate -- 7. trans-Bis(dinitrogen)bis[ethylenebis(diethylphosphine)]molybdenum(0) -- 8. (u-Dinitrogen-N,N')bis[bis(tricyclohexylphosphine)nickel(0)] -- A. (Ethylene)bis(tricyclohexylphosphine)nickel -- B. (u-Dinitrogen-N,N')bis[bis(tricyclohexylphosphine)nickel(0)] -- 9. Dinitrogen and Hydrogen Complexes of Ruthenium -- A. Dinitrogendihydridotris(triphenylphosphine)ruthenium(Il) -- B. Tetrahydridotris(triphenylphosphine)ruthenium(IV) -- 10. Pentahydridobis(trimethylphosphine)iridium(V) -- A. Trimethylphosphonium Tetrachlorobis(trimethylphosphine)iridate(1-) and Trichlorotris(trimethylphosphine)iridium(III). , B. Pentahydridobis(trimethylphosphine)iridium(V) -- 11. Hydride Complexes of Iron(I1) and Ruthenium(II) -- A. Bis[ethylenebis(disphenylphosphine)]-dihydridoiron(II) -- B. Tetrakis(triethyl phosphite)dihydridoruthenium(II) -- 12. Tetrahydridotetrakis(methyldiphenylphosphine)molybdenum(lV) -- A. Tetrachlorobis(methyIdiphenylphosphine)molybdenum(IV) -- B. Tetrahydridotetrakis(methyldiphenylphosphine)molybdenum(IV) -- Chapter Three TRIPHENYLPHOSPHINE COMPLEXES OF TRANSITION METALS -- 13. Complexes of Ruthenium, Osmium, Rhodium, and Iridium Containing Hydride, Carbonyl, or Nitrosyl Ligands -- A. Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II) -- B. Carbonyldihydridotris (triphenyIphosphine)ruthenium(II) (White Isomer) -- C. Tricarbonylbis(triphenylphosphine)ruthenium(0) -- D. Trichloronitrosylbis(triphenylphosphine)ruthenium(II) -- E. Dinitrosylbis(tripheny1phosphine)ruthenium -- F. Carbonylchlorohydridotris(triphenylphosphine)osmium(II) -- G. Carbonyldihydridotris(triphenylphosphine)osmium(II) -- H. Dicarbonyldihydridobis(triphenylphosphine)osmium(II) -- I. Tetrahydridotris(triphenylphosphine)osmium(lV) -- J. Trichloronitrosylbis(triphenylphosphine)osmium(II) -- K. Hydridotetrakis(triphenylphosphine)rhodium(I) -- L. Carbonylhydridotris(tripheny1phosphine)rhodium(I) -- M. Dichloronitrosylbis(triphenylphosphine)rhodium(I) -- N. Nitrosyltris(tripheny1phosphine)rhodium -- O. Dichloronitrosylbis(triphenylphosphine)iridium(I) -- 14. Fluoro Complexes of Rhodium(I) and Iridium(I) -- A. trans-Carbonylfluorobis(triphenylphosphine)rhodium(I) -- B. trans-Carbonylfluorobis(triphenylphosphine)iridium(I) -- 15. Covalent Perchlorato Complexes of Iridium and Rhodium -- A. trans-Carbonylperchloratobis(triphenylphosphine)iridium(I) -- B. trans-Carbonylperchloratobis(triphenylphosphine)rhodium(I). , 16. trans-Carbonyl(cyanotrihydridoborato)bis(triphenylphosphine)rhodium(I) -- Chapter Four OTHER TRANSITION-METAL COMPOUNDS -- 17. n-Allyl Complexes of Palladium and Platinum -- A. Di-u-chloro-bis[(1-ethyl-2-methyl-n-allyl)palladium] -- B.Di-u-chloro-bis{[1-hydroxyethyl)-3-methyl-n-allyl]palladium} -- C. Tetrakis[allylchloroplatinum(II)] -- 18. Dicarbonylchloro(p-toluidine)iridium(I) -- 19. u-Nitrido-bis(triphenylphosphorus) (1+) ("PPN") Salts with Metal Carbonyl Anions -- A. u-Nitrido-bis(triphenylphosphorus) (1+) Chloride -- B. u-Nitrido-bis(triphenylphosphorus) (1+) Nitrate -- C. u-Nitrido-bis(triphenylphosphorus) (I+) Tetracarbonylcobaltate (I--) -- D. u-Nitrido-bis(triphenylphosphorus) (1+) Salts of [M2(CO)10] 2-(M = Cr, Mo, W) -- 20. Dicarbonyl-h5-cyclopentadienylnitrosylmanganese (1+) Hexafluorophosphate (1-) -- 21. Hexaammineplatinum(IV) Chloride -- A. Dichlorotetrakis(methylamine)platinum(IV) Chloride -- B. Hexaammineplatinum(IV) Chloride -- 22. Bis(l,l,l,5,5,5-hexafluoro-2,4-pentanedionato)nickel(II)an d-cobaIt(II) -- 23. Ammonium Pentahalooxomolybdates(2-) -- A. Ammonium Pentachlorooxomolybdate(2-) -- B. Ammonium Pentabromooxomolybdate(2-) -- 24. 13-Vanadomanganate(IV) and Nickelate (IV) -- A. Potassium Vanadate(V) -- B. Potassium 13-Vanadomanganate(IB) 18-Hydrate -- C. Reduced Potassium 13-Vanadomanganate(IV) -- D. Ammonium 13-Vanadomanganate(IV) 18-Hydrate and 5-Hydrate -- E. Potassium 13-Vanadonickelate(IV) 16-Hydrate -- Chapter Five BORON COMPOUNDS -- 25. Octahydrotriborate(1-)([B3H8]-) Salts -- 26. Pentaborane(9) (B5H9) -- 27. Dimethylamine-Borane -- 28. Dimethylamine-Tribromoborane -- 29. Methyldiphenylphosphine-Borane and Dimethylphenylphosphine-Borane -- A. Methyldiphenylphosphine-Borane -- B. Dimethylphenylphosphine-Borane -- 30. Triphenylborane. , 31. Sodium Triethylhydroborate, Sodium Tetraethylborate and Sodium Triethyl-1-propynylborate -- A. Sodium Triethylhydroborate -- B. Sodium Tetraethylborate -- C. Sodium Triethyl-1-propynylborate -- 32. Tetraalkyldiboranes and 9-Borabicyclo[3,3,1] nonane Dimer -- A. "Tetraethyldiborane" and "Tetrapropyldiborane -- B. 9-Borabicyclo[3,3,1]nonane Dimer -- 33. Chlorodiethylborane and Chlorodiphenylborane -- A. Chlorodiethylborane -- B. Chlorodiphenylborane -- Chapter Six GERMANIUM HYDRIDE DERIVATIVES -- 34. Bromogermane and Dibromogermane -- 35. Chlorogermaneand lodogermane -- A. Chlorogermane -- B. lodogermane -- 36. Fluorogermane and Digermylcarbodiimide -- A. Fluorogermane -- B. Digermylcarbodiimide -- 37. lododigermane and Methyldigermane -- A. Iododigerrnane -- B. Methyldigermane -- 38. Pentacarbonylgermylmanganese -- 39. Germylphosphiae -- 40. Digermyl Sulfide(Digermthiane) -- Chapter Seven PHOSPHORUS COMPOUNDS -- 41. Ethylenebis(dimethy1phosphine) [1,2-bis(Dimethylphosphino)ethane], Tetramethyldiphosphane Disulfide, and Tetramethyldiphosphane -- A. Tetramethyldiphosphane Disulfide -- B. Tetramethyldiphosphane -- C. Ethylenebis(dimethylphosphine) -- 42. Dimethylphosphinothioic Chloride and Dimethylphosphinous Chloride -- A. Dimethylphosphinothioic Chloride -- B. Dimethylphosphinous Chloride -- 43. Phosphoric Trihalides -- A. Phosphoric Chloride Difluoride -- B. Phosphoric Dichloride Fluoride -- C. Phosphoric Bromide Diiluoride -- 44. u-Nitrido-bis[amidodiphenylphosphorus] (1+) Chloride -- Chapter Eight MAIN GROUP AND ACTINIDE COMPOUNDS -- 45. Trimethylgallium -- 46. Hexamethyldisilthiane and Hexamethylcyclotrisilthiane -- A. Hexamethyldisilthiane via 1-(Trimethy1silyl)imidazole -- B. Hexamethyldisilthiane via Chlorotrimethylsilane -- C. Hexamethylcyclotrisilthiane -- 47. Polyatomic Cations of Sulfur, Selenium, and Tellurium. , A. Octasulfur u-FIuorobis(pentafluoroantimonate(V)), S8(Sb2F11)2, and Octasulfur Hexafluoroarsenate(V), S8(ASF6)2 -- B. Octaselenium p-Fluorobis@entafluoroantimonate(V)),Se8(Sb2F11)2, and Octaselenium Hexafluoroarsenate(V), Se4(AsF6)2 -- C. Tetraselenium u-Fluorobis(pentafluoroantimonate( V)), Se4(Sb2F11)2, and Tetraselenium Hexafluoroarsenate(V), Se4(AsF6)2 -- D. Tetratellurium u-Fluorobis(pentafluoroantimonate(V)), Te4(Sb2F11)2, and Tetratellurium Hexafluoroarsenate( V), Te4(AsF6)2 -- 48. Tetraethylammonium Trichlorogermanate(1-) and Trichlorostannate(1-) -- A. Tetraethylammonium Trichlorogermanate(1-) -- B. Tetraethylammonium Trichlorostannate(1-) -- 49. Weak and Unstable Anionic Bromo and Iodo Complexes -- A. Starting Materials-Chloro Complexes -- 1. Triphenylphosphonium Hexachlorocerate(2-) -- 2. Triphenylphosphonium Hexachlorolanthanate(3-) Salts -- 3. Tetraethylammonium Tetrachloroferrate(1-) and Tetrachloroaurate(1-) -- B. Triphenylphosphonium Hexabromocerate(2-) -- C. Hexaiodolanthanide(3-) Salts -- D. Tetraethylammonium Tetraiodoferrate(1-) and Tetraiodoaurate(1-) -- E. Other Iodo Complexes -- 50. Hexahalouranate Salts -- A. Hexahalouranate(2-) Salts -- B. General Considerations in Handling [UX6]- Salts -- C. Hexachlorouranate(1-) Salts -- D. Hexabromouranate(1-) Salts -- E. Hexafluorouranate(1-) Salts -- 51. Pentachloro(trichloroacrylyl chloride)uranium(V) -- Index of Contributors -- Subject Index -- Formula Index.