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  • 1
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    Online Resource
    A chemical ionization mass spectrometer for continuous underway shipboard analysis of dimethylsulfide in near-surface seawater (2009)
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    In: Ocean science, Katlenburg-Lindau : Copernicus Publ., 2005, 5(2009), 4, Seite 537-546, 1812-0792
    In: volume:5
    In: year:2009
    In: number:4
    In: pages:537-546
    Description / Table of Contents: A compact, low-cost atmospheric pressure, chemical ionization mass spectrometer ("mini-CIMS") has been developed for continuous underway shipboard measurements of dimethylsulfide (DMS) in seawater. The instrument was used to analyze DMS in air equilibrated with flowing seawater across a porous Teflon membrane equilibrator. The equilibrated gas stream was diluted with air containing an isotopically-labeled internal standard. DMS is ionized at atmospheric pressure via proton transfer from water vapor, then declustered, mass filtered via quadrupole mass spectrometry, and detected with an electron multiplier. The instrument described here is based on a low-cost residual gas analyzer (Stanford Research Systems), which has been modified for use as a chemical ionization mass spectrometer. The mini-CIMS has a gas phase detection limit of 220 ppt DMS for a 1 min averaging time, which is roughly equivalent to a seawater DMS concentration of 0.1 nM DMS at 20°C. The mini-CIMS has the sensitivity, selectivity, and time response required for underway measurements of surface ocean DMS over the full range of oceanographic conditions. The simple, robust design and relatively low cost of the instrument are intended to facilitate use in process studies and surveys, with potential for long-term deployment on research vessels, ships of opportunity, and large buoys.
    Type of Medium: Online Resource
    Pages: graph. Darst
    ISSN: 1812-0792
    URL: http://www.ocean-sci.net/5/537/2009/
    DOI: 10.5194/os-5-537-2009
    Language: English
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  • 2
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    Oxygenated volatile organic carbon in the western Pacific convective centre: ocean cycling, air–sea gas exchange and atmospheric transport. (2017)
    Copernicus
    In:  EPIC3Atmos. Chem. Phys. Discuss., Copernicus, acp-20, ISSN: 1680-7375
    Details
    Publication Date: 2017-11-06
    Description: A suite of oxygenated volatile organic compounds (OVOCs – acetaldehyde, acetone, propanal, butanal and butanone) were measured concurrently in the surface water and atmosphere of the South China Sea and Sulu Sea in November 2011. A strong correlation was observed between all OVOC concentrations in the surface seawater along the entire cruise track, except for acetaldehyde, suggesting similar sources and sinks in the surface ocean. Additionally, several phytoplankton groups, such as haptophytes or pelagophytes, were also correlated to all OVOCs indicating that phytoplankton may be an important source for marine OVOCs in the South China and Sulu Seas. Humic and protein like fluorescent dissolved organic matter (FDOM) components seemed to be additional precursors for butanone and acetaldehyde. The atmospheric OVOC mixing ratios were relative high compared with literature values, suggesting the coastal region of North Borneo as a local hot spot for atmospheric OVOCs. The flux of atmospheric OVOCs was largely into the ocean for all 5 gases, with a few important exceptions near the coast of Borneo. The calculated amount of OVOCs entrained into the ocean seemed to be an important source of OVOCs to the surface ocean. When the fluxes were out of the ocean, marine OVOCs were found to be enough to control the local measured OVOC distribution in the atmosphere. Based on our model calculations, at least 0.4 ppb of marine derived acetone and butanone can reach the upper troposphere, where they may have an important influence on hydrogen oxide radical formation over the western Pacific Ocean.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , notRev , info:eu-repo/semantics/article
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  • 3
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    Environmental control on the variability of DMS and DMSP in the Mauritanian upwelling region (2011)
    In:  EPIC3Biogeosciences Discussion, (8), pp. 8591-8618
    Details
    Publication Date: 2019-07-17
    Description: Dimethylsulfide (DMS) and dissolved and particulate dimethylsulfoniopropionate (DMSPd, DMSPp) were measured in sea surface layer along the Mauritanian coast, Northwest Africa, during the upwelling season in February 2008. DMS, DMSPd and DMSPp surface concentrations of up to 10 nmol L−1, 15 nmol L−1 and 990 nmol L−1, respectively, were measured. The maximum DMSPp concentration is the highest reported from upwelling regions so far and indicates that the Mauritanian upwelling is a hot spot of DMSP and, thus, DMS production. Dinoflagellates were responsible for the DMS production. Other phytoplankton groups seemed to have only a minor or no influence on the DMS and DMSP production. Decreasing nitrogen (i.e. increasing nitrogen limitation) most likely triggered a switch from high DMSP production to high DMS production. It seems that both nitrogen limitation and the intensive solar radiation in the tropics induced stress in DMSP producing algae and activated their antioxidant system. Our results underline the importance of coastal upwelling regions as ecosystems with a pronounced temporal and spatial variability which result in high DMSP and DMS production.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , peerRev
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  • 4
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    Sulphur compounds, methane and phytoplankton: interactios along a north-south transit in the western Pacific Ocean. (2013)
    COPERNICUS GESELLSCHAFT MBH
    In:  EPIC3Biogeosciences, COPERNICUS GESELLSCHAFT MBH, 10, pp. 3297-3311, ISSN: 1726-4170
    Details
    Publication Date: 2019-07-17
    Description: Here we present results of the first comprehensive study of sulphur compounds and methane in the oligotrophic tropical western Pacific Ocean. The concentrations of dimethylsuphide (DMS), dimethylsulphoniopropionate (DMSP), dimethylsulphoxide (DMSO), and methane (CH4), as well as various phytoplankton marker pigments in the surface ocean were measured along a north–south transit from Japan to Australia in October 2009. DMS (0.9 nmol L−1), dissolved DMSP (DMSPd, 1.6 nmol L−1) and particulate DMSP (DMSPp, 2 nmol L−1) concentrations were generally low, while dissolved DMSO (DMSOd, 4.4 nmol L−1) and particulate DMSO (DMSOp, 11.5 nmol L−1) concentrations were comparably enhanced. Positive correlations were found between DMSO and DMSP as well as DMSP and DMSO with chlorophyll a, which suggests a similar source for both compounds. Similar phytoplankton groups were identified as being important for the DMSO and DMSP pool, thus, the same algae taxa might produce both DMSP and DMSO. In contrast, phytoplankton seemed to play only a minor role for the DMS distribution in the western Pacific Ocean. The observed DMSPp : DMSOp ratios were very low and seem to be characteristic of oligotrophic tropical waters representing the extreme endpoint of the global DMSPp : DMSOp ratio vs SST relationship. It is most likely that nutrient limitation and oxidative stress in the tropical western Pacific Ocean triggered enhanced DMSO production leading to an accumulation of DMSO in the sea surface. Positive correlations between DMSPd and CH4, as well as between DMSO (particulate and total) and CH4, were found along the transit. We conclude that DMSP and DMSO and/or their degradation products might serve as potential substrates for CH4 production in the oxic surface layer of the western Pacific Ocean.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 5
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    Sulphur compounds, methane, and phytoplankton: interactions along a north-south transit in the western Pacific Ocean (2012)
    Copernicus
    In:  EPIC3Biogeosciences Discussion, Copernicus, 9, pp. 15011-15049, ISSN: 1810-6285
    Details
    Publication Date: 2019-07-17
    Description: Here we present results of the first comprehensive study of sulphur compounds and methane in the oligotrophic tropical West Pacific Ocean. The concentrations of dimethylsuphide (DMS), dimethylsulphoniopropionate (DMSP), dimethylsulphoxide (DMSO), and methane (CH4), as well as various phytoplankton marker pigments in the surface ocean were measured along a north-south transit from Japan to Australia in October 2009. DMS (0.9 nmol l−1), dissolved DMSP (DMSPd, 1.6 nmol l−1) and particulate DMSP (DMSPp, 2 nmol l−1) concentrations were generally low, while dissolved DMSO (DMSOd, 4.4 nmol l−1) and particulate DMSO (DMSOp, 11.5 nmol l−1) concentrations were comparably enhanced. Positive correlations were found between DMSO and DMSP as well as DMSP and DMSO with chlorophyll a, which suggests a similar source for both compounds. Similar phytoplankton groups were identified as being important for the DMSO and DMSP pool, thus, the same algae taxa might produce both DMSP and DMSO. In contrast, phytoplankton seemed to play only a minor role for the DMS distribution in the western Pacific Ocean. The observed DMSPp : DMSOp ratios were very low and seem to be characteristic of oligotrophic tropical waters representing the extreme endpoint of the global DMSPp : DMSOp ratio vs. SST relationship. It is most likely that nutrient limitation and oxidative stress in the tropical West Pacific Ocean triggered enhanced DMSO production leading to an accumulation of DMSO in the sea surface. Positive correlations between DMSPd and CH4, as well as between DMSO (particulate and total) and CH4, were found along the transit. We conclude that both DMSP and DMSO serve as substrates for methanogenic bacteria in the western Pacific Ocean.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , notRev
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  • 6
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    Environmental control on the variability of DMS and DMSP in the Mauritanian upwelling region (2012)
    COPERNICUS GESELLSCHAFT MBH
    In:  EPIC3Biogeosciences, COPERNICUS GESELLSCHAFT MBH, 9(3), pp. 1041-1051, ISSN: 1726-4170
    Details
    Publication Date: 2019-07-17
    Description: Dimethylsulphide (DMS) and dissolved and particulate dimethylsulfoniopropionate (DMSPd, DMSPp) were measured in near-surface waters along the Mauritanian coast, Northwest Africa, during the upwelling season in February 2008. DMS, DMSPd and DMSPp surface concentrations of up to 10 nmol L−1, 15 nmol L−1 and 990 nmol L−1, respectively, were measured. However, the DMS concentrations measured are in the low range compared to other upwelling regions. The maximum DMSPp concentration is the highest reported from upwelling regions so far, which might indicate that the Mauritanian upwelling is a hot spot for DMSP. Within the phytoplankton groups, dinoflagellates were identified as important contributors to DMS concentrations, while other algae seemed to have only a minor or no influence on DMS and DMSP concentrations. A pronounced switch from high DMSP to high DMS concentrations was observed when the nitrogen to phosphorus ratio (N:P) was below 7. The high DMS/DMSP ratios at N:P ratios 〈7 indicate that nitrogen limitation presumably triggered a switch from DMSP to DMS independent of the species composition. Our results underline the importance of coastal upwelling regions as a local source for surface seawater sulphur.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Format: application/pdf
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