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  • 1
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    Laboratory experiments and continuous fluid monitoring at Campi Flegrei to understand pressure transients in hydrothermal systems (2015)
    In:  Geophysical Research Abstracts, Vol. 17, EGU2015-9613, 2015
    Details
    Publication Date: 2020-02-12
    Type: info:eu-repo/semantics/conferenceObject
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  • 2
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    An expanded non-Arrhenian model for silicate melt viscosity: A treatment for metaluminous, peraluminous and peralkaline liquids (2007)
    Elsevier
    Details
    Publication Date: 2020-10-29
    Description: We present new viscosity measurements for melts spanning a wide range of anhydrous compositions including: rhyolite, trachyte, moldavite, andesite, latite, pantellerite, basalt and basanite. Micropenetration and concentric cylinder viscometry measurements cover a viscosity range of 10−1 to 1012 Pas and a temperature range from 700 to 1650 °C. These new measurements, combined with other published data, provide a high-quality database comprising ∼800 experimental data on 44 well-characterized melt compositions. This database is used to recalibrate the model proposed by Giordano and Dingwell [Giordano, D., Dingwell, D. B., 2003a. Non-Arrhenian multicomponent melt viscosity: a model. Earth Planet. Sci. Lett. 208, 337–349] for predicting the viscosity of natural silicate melts. The present contribution clearly shows that: (1) the viscosity (η)–temperature relationship of natural silicate liquids is very well represented by the VFT equation [log η=A+B/ (T−C)] over the full range of viscosity considered here, (2) the use of a constant high-T limiting value of melt viscosity (e.g., A) is fully consistent with the experimental data, (3) there are 3 different compositional suites (peralkaline, metaluminous and peraluminous) that exhibit different patterns in viscosity, (4) the viscosity of metaluminous liquids is well described by a simple mathematical expression involving the compositional parameter (SM) but the compositional dependence of viscosity for peralkaline and peraluminous melts is not fully controlled by SM. For these extreme compositions we refitted the model using a temperature-dependent parameter based on the excess of alkalies relative to alumina (e.g., AE/SM). The recalibrated model reproduces the entire database to within 5% relative error (e.g., RMSE of 0.45 logunits).
    Description: Published
    Description: 42–56
    Description: reserved
    Keywords: Viscosity ; Model ; Silicate melts ; Metaluminous ; Peraluminous ; Peralkaline ; 04. Solid Earth::04.01. Earth Interior::04.01.05. Rheology ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Format: 717294 bytes
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  • 3
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    A general viscosity model of Campi Flegrei (Italy) melts (2011)
    Details
    Publication Date: 2021-01-14
    Description: Viscosities of shoshonitic and latitic melts, relevant to the Campi Flegrei caldera magmas, have been experimentally determined at atmospheric pressure and 0.5 GPa, temperatures between 840 K and 1870 K, and H2O contents from 0.02 to 3.30 wt%. The concentric cylinder technique was employed at atmospheric pressure to determine viscosity of nominally anhydrous melts in the viscosity range of 101.5 - 103 Pa·s. The micropenetration technique was used to determine the viscosity of hydrous and anhydrous melts at atmospheric pressure in the high viscosity range (1010 Pa·s). Falling sphere experiments were performed at 0.5 GPa in the low viscosity range (from 100.35 to 102.79 Pa·s) in order to obtain viscosity data of anhydrous and hydrous melts. The combination of data obtained from the three different techniques adopted permits a general description of viscosity as a function of temperature and water content using the following modified VFT equation: where η is the viscosity in Pa·s, T the temperature in K, w the H2O content in wt%, and a, b, c, d, e, g are the VFT parameters. This model reproduces the experimental data (95 measurements) with a 1σ standard deviation of 0.19 and 0.22 log units for shoshonite and latite, respectively. The proposed model has been applied also to a more evolved composition (trachyte) from the same area in order to create a general model applicable to the whole compositional range of Campi Flegrei products. Moreover, speed data have been used to constrain the ascent velocity of latitic, shoshonitic, and trachytic melts within dikes. Using petrological data and volcanological information (geometrical parameters of the eruptive fissure and depth of magma storage), we estimate a time scale for the ascent of melt from 9 km to 4 km depth (where deep and shallow reservoirs, respectively, are located) in the order of few minutes. Such a rapid ascent should be taken into account for the hazard assessment in the Campi Flegrei area.
    Description: Published
    Description: 50-59
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: JCR Journal
    Description: open
    Keywords: viscosity ; micropenetration ; concentric cylinder ; falling sphere ; shoshonites ; latites ; Campi Flegrei ; 04. Solid Earth::04.08. Volcanology::04.08.02. Experimental volcanism
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 4
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    Viscosity of high-K basalt from the 5th April 2003 Stromboli paroxysmal explosion (2009)
    elsevier
    Details
    Publication Date: 2021-01-14
    Description: The 5th April 2003 paroxysmal event was the strongest explosion that has occurred at Stromboli in the last 50 years. This event lasted only few minutes and was characterised by two violent explosions, followed by gas and pyroclast emission. In order to constrain models of the dynamics of the paroxystic event the viscosity of anhydrous and hydrous Stromboli high potassium (HK)-basaltic melts have been measured. Viscosity has been investigated in the low viscosity range with the falling sphere method at superliquidus temperatures (1423 to 1673 K) and 0.5 GPa and in the high viscosity range with micropenetration near the glass transition temperature (723 to 1035 K) at atmospheric pressure. Falling sphere experiments were performed in a piston cylinder apparatus with melts whose water content varies from nominally anhydrous (0.02 wt.% H2O) to 4.16 wt.% H2O. The combination of high- and low-viscosity data permits a general description of the viscosity as a function of temperature and water contentusing a modified Tamman–Vogel–Fulcher equation. Using these new viscosity data, an estimation of the flow regime and magma velocity is performed. Our data suggest that the ascent of magma from the 7–8 km deep reservoir to a shallower reservoir located at about 3 km of depth, may occur within minutes. Moreover, we infer a turbulent flow regime. Finally, our estimates of the ascent velocity agree qualitatively with results from petrological studies (e.g. [Bertagnini, A., Métrich, N., Landi, P., Rosi, M., 2003. Stromboli volcano (Aeolian Archipelago, Italy): an openwindowon the deep-feeding system of a steady state basaltic volcano. Journal of Geophysical Research 108, 2336–2350.]), which indicate a turbulent flow regime and rapid ascent velocities such to inhibit volatile-loss-induced crystallization.We conclude that hazard evaluation at Stromboli Island should incorporate the likelihood of very rapid ascent of less-evolved melts from depth.
    Description: Published
    Description: 278-285
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: JCR Journal
    Description: reserved
    Keywords: viscosity ; micropenetration ; Falling sphere ; Basalt ; Stromboli ; Silicate melt ; 04. Solid Earth::04.01. Earth Interior::04.01.05. Rheology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 5
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    Evidence of thermal-driven processes triggering the 2005–2014 unrest at Campi Flegrei caldera (2015)
    Elsevier | Elsevier Science Limited
    Details
    Publication Date: 2021-05-12
    Description: An accelerating process of ground deformation that began 10 years ago is currently affecting the Campi Flegrei caldera. The deformation pattern is here explained with the overlapping of two processes: short time pulses that are caused by injection of magmatic fluids into the hydrothermal system; and a long time process of heating of the rock. The short pulses are highlighted by comparison of the residuals of ground deformation (fitted with an accelerating polynomial function) with the fumarolic CO2/CH4 and He/CH4 ratios (which are good geochemical indicators of the arrival of magmatic gases). The two independent datasets show the same sequence of five peaks, with a delay of ∼200 days of the geochemical signal with respect to the geodetic signal. The heating of the hydrothermal system, which parallels the long-period accelerating curve, is inferred by temperature–pressure gas geoindicators. Referring to a recent interpretation that relates variations in the fumarolic inert gas species to open system magma degassing, we infer that the heating is caused by enrichment in water of the magmatic fluids and by an increment in their flux. Heating of the rock caused by magmatic fluids can be a central factor in triggering unrest at calderas.
    Description: Published
    Description: 58-67
    Description: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Description: JCR Journal
    Description: restricted
    Keywords: Campi Flegrei Caldera ; hydrothermal system ; ground deformation ; magmatic fluids ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 6
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    The deep magmatic system of the Campi Flegrei caldera (Italy) (2008)
    American Geophysical Union.
    Details
    Publication Date: 2017-04-04
    Description: Melt inclusions in phenocrysts of the Minopoli2 shoshonite and Fondo Riccio latite eruptive products (Campi Flegrei caldera; 10.2 to 9.5 ka BP) constrain the nature of deep Phlegraean magmatic fluids, their role in volcanism and give new insights into the magmatic plumbing system. The analyzed melt inclusions show that CO2 is an abundant gaseous species, confirming the results of geochemical studies on the magmatic gas fraction involved in present-day fumarolic emissions. Volatile concentrations within the melt inclusions require gas-melt equilibria between 8 and 9 km depth, and closed-system degassing in presence of ascending CO2-rich fluids of deep provenance. Magmas later re-equilibrate at depths up to 3–2 km, i.e. above the top of the carbonate basement. These observations correlate well with independent geophysical and geochemical evidence and are useful constraints for volcanic hazards assessment at Campi Flegrei.
    Description: Published
    Description: L21304
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: magmatic system ; Campi Flegrei caldera ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 7
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    Water solubility and speciation in shoshonitic and latitic melt composition from Campi Flegrei Caldera (Italy) (2007)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: We report new data on water solubility in two melt compositions representative of volcanic units of the Campi Flegrei Caldera (Italy). The first composition is a primitive shoshonite and the second one is a more evolved latitic composition that have been chosen because of their less evolved nature compared to the other erupted products of Campi Flegrei. Water solubility was investigated at pressures from 25 to 200 MPa and 1200 °C following synthesis in an Internal Heated Pressure Vessel (IHPV). The glasses obtained from water-saturated experiments were analysed using both Fourier Transform Infra Red spectroscopy (FTIR) and Karl Fischer Titration (KFT). KFT was used as an independent method to obtain water concentration for the calibration of molar absorptivities of infrared bands at ∼3550 cm−1 (total water), ∼4500 cm−1 (hydroxyl groups) and ∼5200 cm−1 (molecular water). Water solubility in the shoshonitic melts is similar to that of a basalt while a slightly higher water solubility is observed for the latitic composition. As regards the speciation, we have investigated the water speciation for the shoshonitic composition only and we have made a comparison between the data resulting using different molar absorptivities obtained for basaltic compositions similar to our shoshonite.
    Description: Published
    Description: 113–124
    Description: reserved
    Keywords: Water solubility ; Shoshonitic melts ; Latitic melts ; FTIR ; Molar absorptivity ; Water speciation ; 04. Solid Earth::04.01. Earth Interior::04.01.04. Mineral physics and properties of rocks ; 04. Solid Earth::04.01. Earth Interior::04.01.05. Rheology ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Format: 387108 bytes
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  • 8
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    A CO2-rich magma source beneath the Phlegraean Volcanic District (Southern Italy): (2012)
    Details
    Publication Date: 2017-04-04
    Description: We present a study of olivine-hosted glass/melt inclusions (MIs) in the most primitive rocks erupted at Procida Island, within the Phlegraean Volcanic District (PVD), Southern Italy. MIs were analyzed by combined Scanning Electron Microscopy coupled with Energy Dispersive X-ray-detectors, Wavelength Dispersive X-rayequipped Electron Microprobe and Fourier Transform Infrared (FT-IR) Spectroscopy; notably, the novel Focal- Plane-Array mode provided high-resolution FT-IR images evidencing the distribution of the C–H–O species across samples. Olivines range in composition from Fo85 to Fo90, do not show chemical zoning and are totally anhydrous. The majority of the MIs are glassy, while only few are completely crystallized. Some MIs, however, show the occurrence of crystal nuclei, i.e., nano- to micro-sized pyroxenes and oxides, and appear as lowcrystallized MIs. The glass of crystal-free and low-crystallized MIs shows K-affinity and a compositional range along the basalt, trachy-basalt, shoshonite, tephrite basanite and phono-tephrite array. H2O and CO2 contents up to 2.69 wt.% and 2653 ppm, respectively, define a major degassing trend with small isobaric deviations. The collected data allow recalculating entrapment pressures from ~350 MPa to b50 MPa and suggest that the magma ascent was dominated by degassing. Crystallization was aminor process, likely also consequent to local CO2-fluxing. Mingling occurred between variable degassed and crystallized magma portions during decompression. The geochemical and isotopic data of Procida glasses and rocks, and the compositional relationship between our MIs and those from slightly more evolved and radiogenic Phlegraean products, indicate that Procida basalts are an adequate parental end-member for the PVD. Our data suggest that a CO2- rich magma source was stored at depths of at least 13–14 km (i.e., 350 MPa) beneath the PVD. Fast ascent of magma batches directly started from this depth shortly before PVD trachy-basaltic to shoshonitic eruptions. Such results have implication on volcanic hazard assessment in the PVD area.
    Description: Published
    Description: 66-80
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: 3.6. Fisica del vulcanismo
    Description: 5.3. TTC - Banche dati vulcanologiche
    Description: JCR Journal
    Description: reserved
    Keywords: Melt inclusions ; Phlegraean Volcanic District ; CO2-rich magma source ; Degassing ; Fluxing ; 02. Cryosphere::02.01. Permafrost::02.01.08. Instruments and techniques ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.01. Earth Interior::04.01.04. Mineral physics and properties of rocks ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.04. Geology::04.04.07. Rock geochemistry ; 04. Solid Earth::04.04. Geology::04.04.11. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 9
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    Defining a 3D physical model for the hydrothermal circulation at Campi Flegrei caldera (Italy) (2013)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: Our study is aimed to develop a 3D physical model of the Campi Flegrei geothermal system, in order to achieve a more accurate and comprehensive representation of the hydrothermal processes occurring in the caldera. The new model, developed by using the TOUGH2 code simulator, accounts for the caldera rocks' physical properties, bathymetry and water table topography. In particular, the computational domain is constrained by density values obtained by tomographic inversion of gravity data collected during several surveys at CF both onshore and offshore the caldera. Empirical relations between density and porosity and between porosity and permeability, derived by published data on samples cored in deep wells or collected in outcrops, allowed us to characterize the main rocks physical parameters controlling the dynamic of the CF geothermal system. We have performed and compared several simulations investigating the effects of the injection at depth, underneath Solfatara crater, of a hot gaseous mixture rich in CO2. We show that, with respect to the available literature on 2D axisymmetric models, the effects of the water table topography together with the bathymetry and the heterogeneous distribution of the rocks' physical properties, lead to important differences in the hydrothermal circulation of fluids at CF. These constraints allow the activation of convective cells with different behaviors, which produce variable patterns of temperature inside the hydrothermal system. As a consequence, the predominant effect is again represented by a central plume below the Solfatara crater, but with a non-axisymmetric structure and a wider extension. Additionally, high temperature zones are present near the coastline and in the middle part of the submerged area of the caldera with a SE–NW alignment. Moreover, our results indicate that, the submerged part of the CF caldera would deserve a more accurate study and survey, being affected by phenomenon of heating and degassing. This information could be very useful in terms of hazard assessment and volcanic risk mitigation in such an active and densely inhabited volcanic and geothermal area.
    Description: Published
    Description: 172-182
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Campi Flegrei ; Geothermal system ; 3D model ; Water table topography ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 10
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    Texture and composition of pumices and scoriae from the Campi Flegrei caldera (Italy): implications on the dynamics of explosive eruptions (2008)
    AGU
    Details
    Publication Date: 2020-05-29
    Description: The Campi Flegrei (CF) caldera is one of the most dangerous quiescent volcanic systems in the world. Its activity mostly resulted in low magnitude explosive eruptions, such as that of the Monte Nuovo tuff cone that represents the last eruptive event within the caldera (AD 1538). However, there have been more energetic Plinian events, i.e., the Agnano Monte Spina eruption (4.1 ky), and very highly-explosive, caldera-forming eruptions, i.e., the Campanian Ignimbrite eruption (39 ky). Here, we integrate new and literature data on the groundmass texture and composition of pyroclastic products from the three above eruptions with the aim of unraveling how volatiles content, degassing mechanisms and crystallization processes influence magma explosivity and eruption dynamics at CF. Previous studies indicate that the investigated rocks share similar major element bulk and phenocryst chemistry; also similar is the water content of their trapped melt inclusions. These observations suggest that the magmas feeding these eruptions had comparable physico-chemical properties during storage in the shallow crust. However, our investigations indicate that the studied rocks differ in texture and composition of the groundmass and viscosity of the related magmas. We ascribe such differences to the variable style of volatile exsolution and outgassing from the melt, primarily in response to changes of the rate of magma ascent to the surface. We conclude that the magma ascent rate was the key-parameter in driving explosive eruptions at CF and we suggest that this parameter may be influenced by magma/water interaction and/or magma chamber geometry and replenishment.
    Description: Published
    Description: Q03013
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: JCR Journal
    Description: reserved
    Keywords: Campi Flegrei ; products ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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