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  • 1
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Annals of the New York Academy of Sciences 576 (1989), S. 0 
    ISSN: 1749-6632
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Natural Sciences in General
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1432-2056
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Penicillium spp. isolated from the sediments of ponds in continental Antarctica have been studied and compared with species obtained from similar environments in the Apennines of the Liguria region, in northwestern Italy. The antibacterial activity exhibited by some strains was evaluated against standard strains using both liquid and solid media. The preliminary data suggest an antibacterial activity similar to β-lactam antibiotics.
    Type of Medium: Electronic Resource
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  • 3
    Publication Date: 2012-05-03
    Description: An improved method based on equilibrium partitioning between water samples and an inert host gas, introduced after sampling, is proposed for determining multiple species of dissolved gases in brackish water. The method itself, and the most convenient equations for describing gas solubilities in brackish waters, is described in detail. The method allows the rapid characterization of several sites and represents a useful tool for geochemical surveys. A comparison between replicate samples analyzed using different procedures demonstrates the efficiency of the method and indicates that the abundances of the main dissolved gases can be obtained, which can then be used to determine underlying geochemical processes. A Microsoft Excel worksheet is provided to easily calculate the concentration of dissolved gas species.
    Print ISSN: 1468-8115
    Electronic ISSN: 1468-8123
    Topics: Geosciences
    Published by Wiley-Blackwell
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  • 4
    Publication Date: 2020-11-12
    Description: The number of tornillo events has recently increased at the Vulcano Island, Italy. While only 15 tornillos were recorded during 2004–2006, 584 events occurred in 2007–2008. They were located just below La Fossa Crater at depths ranging between 0.1 and 1 km b.s.l. During two intervals in 2007–2008 increases in the number of tornillos took place at the same time as temperature and geochemical anomalies were observed. The spectral content of the tornillos, generally characterized by one–two dominant spectral peaks near 6 and 10 Hz, varied over time, with changes also noted in the quality factors. The simplest source mechanism proposed for tornillos is the free eigenvibration of a fluid volume within a crack or a conduit. Based on this model, we propose a causal relationship between the temperature and geochemical anomalies and the increases in numbers of tornillos. As the amount of hydrothermal fluids increases during the anomalies, the upward flux of fluids grows. The consequent changes in the pressure, temperature and dynamics of the system of cracks and conduits result in the generation of tornillos. Based on the fluid-filled crack/conduit model, the shallow depths of the sources and the values of the quality factors, the fluid within the resonant crack/conduit was inferred to be an ash–gas or water droplet–gas mixture. Moreover, the observed variations in the wavefield can be caused by small changes in the location of the source, in the source mechanism, or in the medium in between the source and the seismic station. Finally, another peculiar feature of tornillos is the amplitude modulation that can be explained as a result of a beating phenomenon.
    Description: Published
    Description: 377-393
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: JCR Journal
    Description: reserved
    Keywords: Tornillos ; Vulcano Island ; Hydrothermal system ; Volcano seismology ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 5
    Publication Date: 2017-04-04
    Description: The chemical and isotopic compositions of the precipitation at Stromboli Island, Italy, were investigated between October 2003 and October 2005. We employed a rain gauge network designed to cover the range in exposures and elevations of the volcanic edifice. The hydrogen and oxygen isotopic ratios vary greatly on a seasonal basis and correlate with air temperature. Deuterium excess values show a positive correlation with altitude. No direct contribution of volcanogenic H or O is evident in the isotopic composition of the rainwater. The chemical composition of the rainwater is principally controlled by the sea aerosol contribution at the coastal sites, whereas it is significantly influenced by volcanic activity near the summit vents. Interaction with volcanic acid gases is indicated by the pH, which is usually 1–2 units lower near the craters than at the coastal sites. The S/Cl, Cl/F, and S/F molar ratios in rainwater 1.5 km from the craters are consistent with those measured in the volcanic plume using other methods (diffusive tubes and Fourier transform infrared spectroscopy). Rising of undegassed magmas changes these molar ratios because of the differential degassing of sulphur, chlorine, and fluorine from the magma. We therefore propose that the chemical composition of precipitation, within 1.5 km of the craters, provides additional information that is useful for monitoring volcanic activity at Stromboli Island. Moreover, this paper presents estimates of the fluxes of F, Cl, S, Na, K, Ca, and Mg to the soil that could be useful for geochemical studies on groundwater.
    Description: Published
    Description: Q07006
    Description: JCR Journal
    Description: reserved
    Keywords: rainwater ; isotopic composition ; plume ; volcanic gases ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 6
    Publication Date: 2017-04-04
    Description: Volcanic gases, being the most mobile phase of magmas, are worldwide monitored for geochemical surveillance. Together with chemical analyses, stable isotopic studies may be useful in understanding the origin of the fluids emerging in a volcanic system, providing new insights on their subsurface history and geochemical reactions. Isotopic composition of volcanic gases depends on various processes (physical and chemical fractionation, mixing of different end-members, etc.) many of which are strongly influenced by the approaching of paroxysmal activity. The most used isotopic ratios to detect the variable contribution of the magmatic component in volcanic gases are 13C of carbon dioxide and D and 18O of water vapor. Nevertheless, others isotope ratios have been related to volcanic activity (34S, 15N). Until now sampling frequency has been at most limited to monthly collection, but ideally continuous monitoring, impossible with routine methods, would be preferable. Isotopic ratios of many compounds have been also used to estimate the temperatures of magmatic/hydrothermal systems in their gaseous or vapor phase, assuming that exchange reactions reached isotopic equilibrium. Examples of such applications are 13C in carbon dioxide and methane and D in H2 and H2O. In recent times remote techniques have been applied for the study of chemical composition of volcanic gases because in situ sampling is often impractical or hazardous. New remote sensing technique, allowing isotopic analysis of volcanic gases, would be especially useful at volcanoes with open conduit activity, where almost all volcanic gases escape to the atmosphere through the summit craters and direct sampling is very difficult. Infrared Spectrometry could allow both continuous monitoring and remote sensing of isotopic composition of volcanic gases.
    Description: Published
    Description: Florence (Italy)
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: open
    Keywords: Isotopes ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Abstract
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  • 7
    Publication Date: 2017-04-04
    Description: Time-series acquired during last years by surface monitoring parameters are compared, and the results are discussed, following a theoretical approach. Surface parameters are fluid temperature, soil temperatures and seismic activity at La Fossa of Vulcano. Discussed periods are 1998 and from 2004 to 2007, when time relationship between changes of the heat flow from the ground and seismic activity, resulted worth noting. Earthquakes originating in the area of Vulcano are associated with both fracturing and degassing mechanisms. The formers are related to the activity of tectonic structures; while the latter are connected to fluid dynamics within the interior of the volcanic apparatus. In November 1998 seismic activity at La Fossa sharply increased: Five events were registered, with seismic signals of typical faulting earthquakes, triggered by mechanism of shear fracturing and focal depths ranging 1-4 km. Fumaroles temperatures, recorded by continuous monitoring system of INGV - Palermo, showed a growing trend since October to November 1998, highlighting a big increase of heat transfer during the period, and also the soil temperature, out of the fumaroles field showed a marked increase. Fumaroles temperatures heralded the increase of heat and energy flow during a pre-seismic period of about 1 month. The transient variation of surface release reflect an excited state of the system and may have many different causes, not directly related to the magma. Indeed, stress drops generated by small fracturing earthquakes, introduce a significant perturbation in the system resulting in a relevant production of mass and energy flow. Until these flows counteract every stress gradient, they support stationary state of the system. The observed time relationships only allow a qualitative discussion about cause and effects, but doesn’t allow any quantitative evaluation. Pressure transients generate anomalies (flows of matter, differential in heat flows, chemical reaction rates) whose time frame is specific, depending on many possible processes and path-ways. Fluid phases, along fumarolic conduits, reach the surface faster than the co-genetic earthquake, as the earthquake is embedded in a strain transient that broadly exceeds the time-space frame of the seismic transient (Lomnitz, 1994). On the other hand, in a volcano-tectonic context, different energy flows can either be a cause, either an effect of perturbation, depending on depth of their primary source. Thus, in some instances the strain transient related to local earthquakes produces anomalous chemical flows, while, in other instances the local seismic activity may be produced by chemical flows from the magmatic source. Following a period of lower energy release, other 3 anomalous periods were observed from November 2004, either in the seismic release and in the surface heat flow, even out from fumaroles. So far, the monitored sites resulted very sensitive to minor perturbations of the system. The comparative analysis of different time-series supplies information related to perturbations of the state variables, useful to verify conceptual framework and to better define “classical” and “new” monitoring techniques for volcanic, as well as seismic surveillance.
    Description: This research work has been carried out with the help of the National Institute of Geophysics and Volcanology and with the contribution of the Department for the Civil Defence
    Description: Published
    Description: Vien, Austria
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Description: open
    Keywords: hydrothermal flux ; soil temperature monitoring ; seismic activity ; Vulcano ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Abstract
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  • 8
    Publication Date: 2017-04-04
    Description: Volcanoes contribute to atmospheric pollution by increasing the amount of reactive and greenhouse gases and aerosols, making volcanic emissions one of the major natural sources of several trace elements to the atmosphere. In particular, Mt. Etna is considered to be, on the long-term average, the major atmospheric point source of many environmental harmful compounds. Their emission occurs in the form of gases, aerosols or particulate, both through continuous passive degassing from open-conduit activity and through sporadic paroxysmal eruptive activity. To estimate the environmental impact of magma-derived trace metals and their depositions processes, five bulk collectors have been deployed at various altitudes on the upper flanks around the summit craters of the volcano. Samples were collected every second week for a period of one year and analyzed for the main chemical-physical parameters (electric conductivity and pH) and for major and trace elements concentrations. The first data obtained clearly show that the volcanic contribution is always prevailing in the sampling site closest to the summit craters (∼1.5 km). In the distal sites (5.5-10 km from the summit) downwind of the summit craters, the volcanic contribution is also detectable but often overwhelmed by anthropogenic or other natural (seawater spray, geogenic dust) contributions. Volcanic contribution may derive from both dry and wet deposition of gases and aerosols from the volcanic plume, but sometimes also from leaching of freshly emitted volcanic ashes. In fact, in our background site (7.5 km in the upwind direction,) volcanic contribution has been detected only following an ash deposition event. Fluorine, S and Cl, are the major elements that prevailingly characterize the volcanic contribution in bulk deposition on Mt. Etna, but high concentrations of many trace elements are also detected in the studied samples. In particular, Si, Al, Fe, Ti, Cu, As, Rb, Pb, Tl, Cd, Cr, U and Ag display, in the site most exposed to the volcanic emissions, median concentration values about two orders of magnitude higher than those measured in our background site. Furthermore some of the analysed elements display very high enrichment values with respect to the average crust and, in the closest site to the summit craters, also deposition values higher than those measured in polluted urban or industrial sites.
    Description: Unpublished
    Description: Athens, Greece
    Description: 4.5. Degassamento naturale
    Description: open
    Keywords: Mt. Etna ; trace elements ; rainwater ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Oral presentation
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  • 9
    Publication Date: 2017-04-04
    Description: The ratios of stable isotopes of single rain events were investigated during the period October 2005 to September 2006 in the central Mediterranean. Clear seasonal trends were identified in both oxygen isotope ratios and the deuterium-excess parameter, and these were ascribed to the dominant circulation systems during both cold and hot intraannual periods. Rain events were classified on the basis of the origin of rain-bearing systems. Air masses coming from the south usually give rise to rainwater with a low deuterium excess. Air masses coming from the north and the northeast are often dry and cold, and are associated with high evaporation from the Mediterranean Sea that occurs under isotopic nonequilibrium conditions. Kinetic fractionation enhances lighter isotopomers in the vapor phase, increasing the deuterium excess. During cold periods large vapor fluxes from the Mediterranean Sea, as estimated by the ECMWF (European Centre for Medium-Range Weather Forecasts), usually precede rain events with a high deuterium excess. However, the isotope signatures of the Mediterranean moisture contribution may be masked by the original isotope content of the circulating air masses and/or by secondary evaporation effects.
    Description: Published
    Description: D16304
    Description: 3.7. Dinamica del clima e dell'oceano
    Description: JCR Journal
    Description: reserved
    Keywords: Isotopic composition ; 02. Cryosphere::02.03. Ice cores::02.03.06. Precipitation
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 10
    Publication Date: 2017-04-04
    Description: An accurate description of the geochemical system is presented here based on a review of scientific work performed during the past decade. The surface manifestations of the volcanic system of Stromboli have been investigated using several measuring techniques. Studying the chemical composition of the volcanic plume and of fumarolic emissions has provided information on magma degassing processes. The total fluxes of the emitted gases from both the plume and the soil were found to vary with changes in volcanic activity (from normal Strombolian activity to effusive and/or paroxysmal activity). Thermal water results from the interaction between volcanic gases, host rock, seawater and meteoric water and temporal changes observed in the chemical and the isotopic composition of the gases dissolved into thermal waters highlighted the rising of new magma batches. Combining modelling of gas-water-rock interactions with an understanding of the volcanic system allowed to identify preferential sampling sites and parameters for the geochemical monitoring of volcanic activity at Stromboli Island.
    Description: Unpublished
    Description: 16
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: open
    Keywords: Water geochemistry ; Volcanic surveillance ; Stromboli ; Gas geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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