Keywords:
Chemistry, Inorganic-Problems, exercises, etc.
;
Chemistry, Physical and theoretical-Problems, exercises, etc.
;
Electronic books.
Description / Table of Contents:
This textbook offers over 400 problems and solutions in structural inorganic chemistry for senior undergraduates and beginning graduates. It is an updated companion text to Advanced Structural Inorganic Chemistry by the same authors. The new edition adds over 100 new problems and three new chapters on metal compounds and bioinorganic chemistry.
Type of Medium:
Online Resource
Pages:
1 online resource (470 pages)
Edition:
2nd ed.
ISBN:
9780192557186
URL:
https://ebookcentral.proquest.com/lib/geomar/detail.action?docID=5891602
DDC:
541.2076
Language:
English
Note:
Cover -- Problems in Structural Inorganic Chemistry -- Copyright -- Preface to the First Edition -- Preface to the Second Edition -- Contents -- About the Authors -- 1. Electronic States and Configurations of Atoms and Molecules -- Problems -- Solutions -- 2. Introductory Quantum Chemistry -- Problems -- Solutions -- 3. Atomic Orbitals -- Problems -- Solutions -- 4. Hybrid Orbitals -- Problems -- Solutions -- 5. Molecular Symmetry -- Problems -- Solutions -- 6. Molecular Geometry and Bonding -- Problems -- Solutions -- 7. Crystal Field Theory -- Problems -- Solutions -- 8. Molecular Orbital Theory -- Problems -- Solutions -- 9. Vibrational Spectroscopy -- Problems -- Solutions -- 10. Crystal Structure -- Problems -- Solutions -- 11. Transition Metal Chemistry -- Problems -- Solutions -- 12. Metal Clusters: Bonding and Reactivity -- Problems -- Solutions -- 13. Bioinorganic Chemistry -- Problems -- Solutions -- Appendix 1. Periodic Table -- Appendix 2. Energy Conversion Factors, Physical Constants, and Atomic Units -- ENERGY CONVERSION FACTORS -- PHYSICAL CONSTANTS -- ATOMIC UNITS -- Appendix 3. Useful Integrals -- Appendix 4. Slater's Rules for Screening Constants -- Appendix 5. Wade's Rules -- A5.1 CARBORANES -- A5.2 MAIN-GROUP CLUSTERS -- A5.3 METALLOCARBORANES -- Appendix 6. Character Tables of Point Groups -- Appendix 7. Electrocyclic Reactions and Cycloadditions -- A7.1 PREDICTING THE COURSE OF A REACTION BY CONSIDERING THE SYMMETRY OF THE RELEVANT ORBITALS: ELECTROCYCLIC REACTIONS -- A7.2 PREDICTING THE COURSE OF A REACTION BY CONSIDERING THE SYMMETRY OF THE RELEVANT ORBITALS: CYCLOADDITIONS -- Appendix 8. Selected Topics in Bioinorganic Chemistry -- A8.1 BIOLOGICAL LIGANDS FOR METAL IONS -- A8.1.1 Coordination by Peptides and Proteins -- A8.1.2 Biosynthesized Macrocyclic Ligands -- A8.1.2.1 Macrocyclic tetrapyrrole systems.
,
A8.1.2.2 Ionophores and siderophores -- A8.1.3 Nucleic Acids as Ligands -- A8.2 IRON STORAGE AND TRANSPORT -- A8.2.1 Ferritin and Transferrin -- A8.2.2 Siderophores -- A8.3 BIOLOGICAL DIOXYGEN CARRIERS -- A8.3.1 Hemoglobin (Hb) and Myoglobin (Mb) -- Structures: -- The dioxygen-binding reaction: -- Synthetic model complexes for hemoglobin and myoglobin: -- A8.3.2 Hemerythrins (Hr) -- Structures: -- The dioxygen-binding reaction: -- Synthetic model complexes for hemerythrin: -- A8.3.3 Hemocyanins (Hc) -- Structures: -- The dioxygen-binding reaction: -- Synthetic model complexes for hemocyanin: -- A8.4 ELECTRON TRANSFER IN BIOLOGICAL SYSTEMS -- A8.4.1 Redox Active Protein Side Chains -- A8.4.2 Redox Active OrganicMolecules -- A8.4.3 Redox Cofactors -- A8.4.2.1 Flavins -- A8.4.2.2 Copper ions -- A8.4.2.3 Iron-sulfur Clusters -- A8.4.2.4 Cytochromes -- Further Reading -- Bibliography -- TEXTBOOKS -- Inorganic Chemistry -- Physical Chemistry -- Chemical Bonding -- Symmetry and Group Theory -- Molecular Quantum Mechanics -- X-Ray Crystallography -- Problem Books -- Monographs and Advanced Texts -- Index.
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