Keywords:
Reaction mechanisms (Chemistry).
;
Organometallic compounds.
;
Inorganic compounds.
;
Electronic books.
Description / Table of Contents:
Reaction Mechanisms of Inorganic and Organometallic Systems helps students develop both an appreciation of and skepticism about mechanistic studies.
Type of Medium:
Online Resource
Pages:
1 online resource (532 pages)
Edition:
3rd ed.
ISBN:
9780199719730
Series Statement:
Topics in Inorganic Chemistry Series
URL:
https://ebookcentral.proquest.com/lib/geomar/detail.action?docID=415694
DDC:
541/.39
Language:
English
Note:
Intro -- Contents -- 1 Tools of the Trade -- 1.1 Basic Terminology -- 1.2 Analysis of Rate Data -- 1.3 Concentration Variables and Rate Constants -- 1.4 Complex Rate Laws -- 1.5 Complex Kinetic Systems -- 1.6 Temperature Dependence of Rate Constants -- 1.7 Pressure Dependence of Rate Constants -- 1.8 Ionic Strength Dependence of Rate Constants -- 1.9 Diffusion-Controlled Rate Constants -- 1.10 Molecular Modeling and Theory -- 2 Rate Law and Mechanism -- 2.1 Qualitative Guidelines -- 2.2 Steady-State Approximation -- 2.3 Rapid-Equilibrium Assumption -- 2.4 Curtin-Hammett Conditions -- 2.5 Rapid-Equilibrium or Steady-State? -- 2.6 Numerical Integration Methods -- 2.7 Principle of Detailed Balancing -- 2.8 Principle of Microscopic Reversibility -- 3 Ligand Substitution Reactions -- 3.1 Operational Approach to Classification of Substitution Mechanisms -- 3.2 Operational Tests for the Stoichiometric Mechanism -- 3.3 Examples of Tests for a Dissociative Mechanism -- 3.4 Operational Test for an Associative Mechanism -- 3.5 Operational Tests for the Intimate Mechanism -- 3.6 Some Special Effects -- 3.7 Variation of Substitution Rates with Metal Ion -- 3.8 Ligand Substitution on Labile Transition-Metal Ions -- 3.9 Kinetics of Chelate Formation -- 4 Stereochemical Change -- 4.1 Types of Ligand Rearrangements -- 4.2 Geometrical and Optical Isomerism in Octahedral Systems -- 4.3 Stereochemical Change in Five-Coordinate Systems -- 4.4 Isomerism in Square-Planar Systems -- 4.5 Fluxional Organometallic Compounds -- 5 Reaction Mechanisms of Organometallic Systems -- 5.1 Ligand Substitution Reactions -- 5.2 Insertion Reactions -- 5.3 Oxidative Addition Reactions -- 5.4 Reductive Elimination Reactions -- 5.5 Reactions of Alkenes -- 5.6 Catalytic Hydrogenation of Alkenes -- 5.7 Homogeneous Catalysis by Organometallic Compounds -- 6 Oxidation-Reduction Reactions.
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6.1 Classification of Reactions -- 6.2 Outer-Sphere Electron-Transfer Theory -- 6.3 Differentiation of Inner-Sphere and Outer-Sphere Mechanisms -- 6.4 Bridging Ligand Effects in Inner-Sphere Reactions -- 6.5 Intervalence Electron Transfer -- 6.6 Electron Transfer in Metalloproteins -- 7 Inorganic Photochemistry -- 7.1 Basic Terminology -- 7.2 Kinetic Factors Affecting Quantum Yields -- 7.3 Photochemistry of Cobalt(III) Complexes -- 7.4 Photochemistry of Rhodium(III) Complexes -- 7.5 Photochemistry of Chromium(III) Complexes -- 7.6 Photochemistry of Ruthenium(II) Complexes -- 7.7 Organometallic Photochemistry -- 7.8 Photochemical Generation of Reaction Intermediates -- 8 Bioinorganic Systems -- 8.1. Basic Terminology -- 8.2 Terms and Methods of Enzyme Kinetics -- 8.3 Vitamin B[sub(12)] -- 8.4 A Zinc(II) Enzyme: Carbonic Anhydrase -- 8.5 Enzymic Reactions of Dioxygen -- 8.6 Enzymic Reactions of Nitric Oxide -- 9 Kinetics in Heterogeneous Systems -- 9.1 Gas/Liquid Heterogeneous Systems -- 9.2 Gas/Liquid/Solid Heterogeneous Systems -- 9.3 Where is the Catalyst? -- 10 Experimental Methods -- 10.1 Flow Methods -- 10.2 Relaxation Methods -- 10.3 Electrochemical Methods -- 10.4 Nuclear Magnetic Resonance Methods -- 10.5 Electron Paramagnetic Resonance Methods -- 10.6 Pulse Radiolysis Methods -- 10.7 Flash Photolysis Methods -- Problems -- Chemical Abbreviations -- Index -- A -- B -- C -- D -- E -- F -- G -- H -- I -- K -- L -- M -- N -- O -- P -- Q -- R -- S -- T -- U -- V -- W -- Z.
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