Keywords:
Molecules-Textbooks.
;
Electronic books.
Description / Table of Contents:
This unique General Chemistry textbook is tailored to more mathematically-oriented engineering or physics students and emphasizes the principles underlying chemistry rather than chemistry itself. Over 200 problems and answers are provided throughout the text for the student to solve and confirm their understanding of key topics.
Type of Medium:
Online Resource
Pages:
1 online resource (323 pages)
Edition:
1st ed.
ISBN:
9780429827174
URL:
https://ebookcentral.proquest.com/lib/geomar/detail.action?docID=5516297
DDC:
539.7
Language:
English
Note:
Cover -- Half Title -- Title Page -- Copyright Page -- Contents -- Introduction -- About the Authors -- Chapter 1 From the Chemical System to the Atomic Nucleus -- 1.1 Chemical System -- 1.2 Molecules -- 1.3 Atoms -- 1.4 Atomic and Mass Numbers, Isotopes -- Chapter 2 Stoichiometry -- 2.1 Fundamental Definitions -- 2.2 Elementary Stoichiometric Calculations -- 2.3 Concentration of Solutions -- Chapter 3 Nucleus and Radioactivity -- 3.1 Nucleus -- 3.2 Natural Radioactivity -- 3.3 Kinetics of Radioactive Decay -- 3.4 Electronuclear Energy -- Chapter 4 Interlude of Physics I: Quantum Mechanics -- 4.1 Physical Quantities -- 4.2 Classical Physics: Matter and Radiation -- 4.2.1 Crisis of Classical Physics -- 4.2.2 A Solid Foundation: The Conservation Theorems -- 4.3 Random Variables -- 4.4 Quantum Mechanics -- 4.4.1 Fundamental Postulate -- 4.4.2 Consequences of the Fundamental Postulate -- 4.4.2.1 Eigenvalue Equations -- 4.4.2.2 Position Observable -- 4.4.2.3 Linear Momentum Observable -- 4.4.2.4 Energy and the Schrödinger Equation -- 4.4.2.5 Uncertainty Principle -- 4.4.2.6 Stationary Schrödinger Equation -- 4.4.2.7 Particle in a Potential -- 4.4.2.8 Angular Momentum Observable -- 4.4.2.9 Orbital Angular Momentum -- 4.4.2.10 Spin -- 4.4.2.11 Pauli Exclusion Principle -- 4.4.3 Examples -- 4.4.3.1 Free Particle -- 4.4.3.2 Particle in a Box -- 4.4.3.3 Harmonic Oscillator -- 4.4.3.4 Rigid Rotator -- 4.4.3.5 Particle in a Central Potential -- 4.4.4 Approximation Methods -- 4.4.4.1 Perturbation Method -- 4.4.4.2 Variational Method -- Chapter 5 Atoms and the Periodic Table of the Elements -- 5.1 Hydrogen Atom -- 5.2 Many-Electron Atoms -- 5.3 Periodic Table of the Elements -- Chapter 6 Chemical Bond I: Lewis Scheme -- 6.1 Born-Oppenheimer Approximation -- 6.2 Lewis Structures -- 6.2.1 Diatomic Molecules -- 6.2.2 Electronegativity.
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6.2.3 Polyatomic Molecules -- 6.2.4 Examples -- Chapter 7 Chemical Bond II: Molecular Orbitals -- 7.1 H[sub(2)]+ Molecular Ion -- 7.2 Diatomic Molecules -- 7.2.1 H[sub(2)] Molecule -- 7.2.2 Homonuclear Diatomic Molecules -- 7.2.3 Heteronuclear Diatomic Molecules -- 7.3 Polyatomic Molecules -- 7.3.1 Walsh Diagrams -- 7.4 Photoelectron Spectroscopy -- 7.5 Hybridization -- 7.6 Valence Bond Method -- 7.7 Molecules with Conjugated Double Bonds -- Chapter 8 Chemical Bond III: Complements -- 8.1 Diatomic Molecules: Nuclei Dynamics -- 8.2 Diatomic Molecules: Roto-Vibrational Spectroscopy -- 8.2.1 Microwave Spectroscopy -- 8.2.2 IR Spectroscopy -- 8.2.3 Selection Rules -- 8.3 Polyatomic Molecules -- 8.4 Crystals -- 8.4.1 Chemical Bond in Solids -- 8.4.2 Crystal Structure -- Chapter 9 Interlude of Physics II: Thermodynamics -- 9.1 Thermodynamic State -- 9.2 Internal Energy -- 9.3 Processes in Isolated Systems -- 9.4 Entropy -- 9.4.1 Origin of Entropy -- 9.4.2 Meaning of Entropy -- 9.4.3 Spontaneous Evolution in Processes within Isolated Systems -- 9.4.4 Entropy and Internal Energy -- 9.5 Extensive and Intensive Quantities -- 9.5.1 Temperature, Pressure, and Chemical Potential -- 9.6 Thermodynamic Potentials -- 9.6.1 Legendre Transformations -- 9.6.2 Enthalpy, Helmholtz Free Energy, and Gibbs Free Energy -- 9.7 Third Principle of Thermodynamics -- 9.8 Work and Heat -- 9.9 Response Functions -- 9.9.1 Energy Equipartition Theorem -- 9.9.2 Le Chatelier's Principle -- Chapter 10 Phase Equilibria -- 10.1 One-Component Systems -- 10.1.1 Ideal Gas -- 10.1.2 Real Gases -- 10.1.2.1 Lever Rule -- 10.1.2.2 Andrews Bell -- 10.1.2.3 Compressibility Factor -- 10.1.2.4 Virial Equation -- 10.1.2.5 Van der Waals Equation -- 10.1.2.6 Law of Corresponding States -- 10.1.2.7 Maxwell Construction -- 10.1.3 Phase Diagrams on the T-p Plane -- 10.1.3.1 Clausius-Clapeyron Equation.
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10.1.4 Phase Transitions -- 10.2 Phase Rule -- 10.3 Mixture of Ideal Gases -- 10.4 Two-Component Systems -- 10.4.1 Effects on the Solute: Henry's Law and Solubility -- 10.4.2 Effects on the Solvent: Colligative Properties -- 10.4.2.1 The Raoult Law -- 10.4.2.2 Ebullioscopy and Cryoscopy -- 10.4.2.3 Osmosis -- 10.4.3 Binary-System Phase Diagram -- 10.4.3.1 Liquid-Vapor Equilibria -- 10.4.3.2 Liquid-Solid Equilibria -- Chapter 11 Chemical Equilibrium -- 11.1 Chemical Equilibrium Among Ideal Gases -- 11.1.1 Other Forms of Equilibrium Constants -- 11.2 Influence of External Factors on a Reaction Equilibrium -- 11.3 Tables of Thermochemical Data -- 11.4 Problems -- 11.5 Chemical Equilibrium Among Condensed Phases and Ideal Gases -- 11.6 Chemical Equilibrium Among Real Gases -- 11.7 Chemical Equilibrium in Solution -- Chapter 12 Ionic Equilibria in Aqueous Solutions -- 12.1 Autoprotolysis of Water -- 12.2 Acids and Bases -- 12.3 pH in Various Circumstances -- 12.3.1 Strong Acids and Bases -- 12.3.2 Remarks -- 12.3.3 Weak Acids and Bases -- 12.3.4 Salts Hydrolysis -- 12.3.5 Dissociation Degree and Hydrolysis Degree -- 12.3.6 Diprotic Acids -- 12.3.7 Ampholytes -- 12.4 Buffers -- 12.5 Acid-Base Titrations -- 12.5.1 Indicators -- 12.6 Insoluble Salts -- Chapter 13 Chemical Kinetics -- 13.1 Descriptive Kinetics -- 13.1.1 Simple Kinetics, Order of Reaction -- 13.1.1.1 Zeroth-order Reactions -- 13.1.1.2 First-order Reactions -- 13.1.1.3 Second-order Reactions -- 13.1.2 Parallel Reactions -- 13.1.3 Consecutive Reactions, Determining Step -- 13.1.3.1 Stationary State, Induction Time -- 13.1.4 Opposite Reactions -- 13.2 Reaction Mechanisms, Molecularity -- 13.2.1 Chain Reactions -- 13.2.2 Unimolecular Reactions -- 13.3 Effects of Temperature, Arrhenius Equation -- 13.4 Molecular Interpretation of Reactive Processes -- 13.5 Enzyme Catalysis.
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Chapter 14 Electrochemistry -- 14.1 Redox Reactions -- 14.1.1 Oxidation Number -- 14.1.2 Balancing Redox Reactions -- 14.2 Galvanic Cell -- 14.2.1 Thermodynamics of the Galvanic Cell -- 14.3 Electrochemical Series -- 14.4 Applications -- 14.5 Problems -- 14.6 Electrolysis -- Appendix A: A Concise Guide to the Vocabulary of Chemistry -- A.1 Inorganic Compounds -- A.2 Organic Compounds: Hydrocarbons -- A.3 Isomerism -- A.4 Hydrocarbons: Continuation -- A.5 Halide Compounds (Functional Group -X, Halogen) -- A.6 Alcohols, Glycols, Phenols (Functional Group -OH, Hydroxyl) -- A.7 Ethers, Epoxides (Functional Group -OR, Alkoxy Group) -- A.8 Amines (Functional Group NH[sub(2)], -NHR, -NRR') -- A.9 Aldehydes, Ketones -- A.10 Carboxylic Acids (Carboxylic Functional Group, -COOH -- A.11 Acyl Halides, Anhydrides, Esters, Amides -- A.12 Carbohydrates -- Appendix B: Tables -- Index.
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