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  • 1
    Publication Date: 2023-02-08
    Description: Enhanced nutrient input and warming have led to the development of low oxygen (hypoxia) in coastal waters globally. For many coastal areas, insight into redox conditions prior to human impact is lacking. Here, we reconstructed bottom water redox conditions and sea surface temperatures (SSTs) for the coastal Stockholm Archipelago over the past 3000 yr. Elevated sedimentary concentrations of molybdenum indicate (seasonal) hypoxia between 1000b.c.e.and 1500c.e. Biomarker-based (TEX86) SST reconstructions indicate that the recovery from hypoxia after 1500c.e.coincided with a period of significant cooling (similar to 2 degrees C), while human activity in the study area, deduced from trends in sedimentary lead and existing paleobotanical and archeological records, had significantly increased. A strong increase in sedimentary lead and zinc, related to more intense human activity in the 18(th)and 19(th)century, and the onset of modern warming precede the return of hypoxia in the Stockholm Archipelago. We conclude that climatic cooling played an important role in the recovery from natural hypoxia after 1500c.e., but that eutrophication and warming, related to modern human activity, led to the return of hypoxia in the 20(th)century. Our findings imply that ongoing global warming may exacerbate hypoxia in the coastal zone of the Baltic Sea.
    Type: Article , PeerReviewed , info:eu-repo/semantics/article
    Format: text
    Format: text
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  • 2
    Publication Date: 2023-02-08
    Description: The Paleocene‐Eocene Thermal Maximum (PETM, ca. 56 Ma) is marked by a negative carbon isotope excursion (CIE) and increased global temperatures. The CIE is thought to result from the release of 13C‐depleted carbon, although the source(s) of carbon and triggers for its release, its rate of release, and the mechanisms by which the Earth system recovered are all debated. Many of the proposed mechanisms for the onset and recovery phases of the PETM make testable predictions about the marine silica cycle, making silicon isotope records a promising tool to address open questions about the PETM. We analyzed silicon isotope ratios (δ30Si) in radiolarian tests and sponge spicules from the Western North Atlantic (ODP Site 1051) across the PETM. Radiolarian δ30Si decreases by 0.6‰ from a background of 1‰ coeval with the CIE, while sponge δ30Si remains consistent at 0.2‰. Using a box model to test the Si cycle response to various scenarios, we find the data are best explained by a weak silicate weathering feedback, implying the recovery was mostly driven by nondiatom organic carbon burial, the other major long‐term carbon sink. We find no resolvable evidence for a volcanic trigger for carbon release, or for a change in regional oceanography. Better understanding of radiolarian Si isotope fractionation and more Si isotope records spanning the PETM are needed to confirm the global validity of these conclusions, but they highlight how the coupling between the silica and carbon cycles can be exploited to yield insight into the functioning of the Earth system.
    Type: Article , PeerReviewed
    Format: text
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  • 3
    Publication Date: 2023-07-10
    Description: This dataset contains stable Si isotope values from radiolarian tests and sponge spicules analyzed on MC-ICP-MS and SIMS. These are in association with a study aiming at investigating the changes to the Si cycle during the Paleocene-Eocene Thermal Maximum from siliceous microfossils from ODP hole 1051B.
    Keywords: 171-1051B; Age, relative; Blake Nose, North Atlantic Ocean; Depth, composite; DRILL; Drilling/drill rig; Joides Resolution; Laboratory; Leg171B; Multi-collector inductively coupled plasma mass spectrometer (MC-ICP-MS); Number; PETM; Radiolarians; Radiolarians, δ30Si; Radiolarians, δ30Si, standard deviation; Sample code/label; Secondary ion mass spectrometry (SIMS); silicon isotope; sponge; Sponge spiculae, δ30Si; Sponge spiculae, δ30Si, standard deviation
    Type: Dataset
    Format: text/tab-separated-values, 676 data points
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