Note: Front Cover -- Spot Tests in Organic Analysis -- Copyright Page -- Table of Contents -- Foreword -- Chapter 1. Developmenty Present State and Prospects of Organic Spot Test Analysis -- Chapter 2. Preliminary (Exploratory) Tests -- General remarks -- 1. Non-chemical proofs -- 2. Burning and pyrolysis tests -- 3. Examination of ignition residues -- 4. Carbon -- 5. Hydrogen -- 6. Halogens -- 7. Chlorine -- 8. Bromine -- 9. Iodine -- 10. Fluorine -- 11. Oxygen -- 12. Sulfur -- 13. Compounds with groups containing sulfur and oxygen -- 14. Selenium -- 15. Nitrogen -- 16. Compounds with groups containing nitrogen and oxygen -- 17. Sulfur and nitrogen (joint detection) -- 18. Phosphorus -- 19. Arsenic -- 20. Antimony -- 21. Silicon -- 22. Mercury -- 23. Metals -- 24. Tests for basic or acidic behavior -- 25. Detection of occult acidic groups -- 26. Detection of occult (non-basic) amino groups -- 27. Detection of water-soluble salts of organic bases and alkali salts of organic acids -- 28. Detection of water-soluble salts of sulfonic and sulfinic acids -- 29. Detection of water-insoluble bases and acids -- 30. Detection of compounds which react with acids -- 31. Orientation tests based on redox reactions -- 32. The Le Rosen test for aromatic compounds -- 33. Sulfonation test for aromatics -- 34. Pyrolysis tests for aromatic compound constaining oxygen -- 35. Ehrlich diazo test for compounds capable of coupling -- 36. Golmant chloranil test -- 37. Fuming-off test with concentrated nitric acid -- 38. Fusion test with benzoin -- 39. Sinter test with mercuric cyanide -- 40. Detection of compounds which split off water or ammonia when heated to 190° -- 41. Detection of compounds which yield ammonia when pyrolyzed -- 42. Detection of compounds which yield ammonia when heated with caustic alkali and Devarda alloy. , 43. Detection of compounds which split off water when heated to 180 -- 44. Compounds containing reactive CH2 and -NH2 groups -- 45. Solubility tests -- Chapter 3. Detection of Characteristic Functional Groups in Organic Compounds -- General remarks -- A. Groups containing carbon and hydrogen -- B. Organic halogen compounds -- C. Oxygen compounds (organic derivatives of water) -- D. Sulfur and selenium compounds -- E. Nitrogen compounds -- F. Organic compounds of P, As, Sb, Bi, and Hg -- Chapter 4. Detection of Structures and Certain Types of Organic Compounds -- General remarks -- 1. Vicinal polyalcohols ( C(OH)-(HO)C type) -- 2. 7-Dehydrosterols -- 3. Phenoxy compounds ( C6H5O-type ) -- 4. Polyhydroxybenzenes (C6H6-n(OH)n type) -- 5. m-Dihydroxybenzene derivatives -- 6. m-Dihydroxyaryl compounds (m-Ar(OH)2 type) -- 7. vic-Trihydroxyaryls -- 8. p-Hydroxy» and p-alkoxy-benzene derivatives -- 9. Methylene ethers of o-diphenols -- 10. 1,2-Dioxo compounds (-CO-CO- type) -- 11. Aliphatic 1,2-dioxo compounds (R-CO-CO-R type) -- 12. Aromatic 1,2-dioxo compounds and o-quinones (Ar-GO-CO-Ar type) -- 13. 1,2-Dioxo compounds and quinones -- 14. Quinones -- 15. o-Quinones -- 16. Naphthoquinones -- 17. p-Naphthoquinones -- 18. Anthraquinones -- 19. Carbohydrates -- 20. Reducing sugars -- 21. Hexoses -- 22. Ketohexoses -- 23. o-Hydroxyaryl carbonyl compounds -- 24. o-Hydroxyarylaldehydes -- 25. p-Hydroxyarylaldehydes -- 26. p-Hydroxy- and p-alkoxyaldehydes -- 27. Arylvinyl- and p-hydroxy-(alkoxy-)aryl-aldehydes -- 28. Polyhydroxyanthraquinones -- 29. Acyloins (Ar-CHOH-CO-Ar type) -- 30. 5-Hydroxyflavonols -- 31. 1,2-Dicarboxylic acids -- 32. α-Halogenofatty acids (-CHHalCOOH type) -- 33. Uronic acids -- 34. Salicylic acid derivatives -- 35. Phenoxyacetic acids -- 36. Phenol- and α-naphthol-sulfonic acids -- 37. Naphthalenesulfonic acids. , 38. Anthraquinonesulfonic acids -- 39. N-Alkylanilines -- 40. Ν,Ν-Dialkylanilines -- 41. Diphenylamine and derivatives -- 42. Halogenated anilines -- 43. β-Hydroxyethylamines -- 44. Amino acids -- 45. Aliphatic aminocarboxylic and -sulfonic acids -- 46. Aliphatic aminocarboxylic acids -- 47. α-Aminocarboxylic acids -- 48. Proteins -- 49. Aniline- and phenolsulfonic acids -- 50. Aniline derivatives containing strongly acidic groups in the para-position -- 51. Anilinearsonic and anilinestibonic acids -- 52. o- and peri-Hydroxyarylamines -- 53. Aromatic tertiary N-ring bases -- 54. Aromatic heterocyclic ring bases -- 55. Pyrrole derivatives -- 56. Indole derivatives -- 57. Carbazole derivatives -- 58. Pyridine derivatives -- 59. Pyridine-aldehydes -- 60. α-Carboxylic acids of aromatic heterocyclic bases -- 61. 8-Hydroxyquinoline and derivatives -- 62. Urea and derivatives -- 63. Thiourea and derivatives -- 64. Quinonechloroimines -- 65. Aliphatic 1,2-dioximes -- 66. o-Nitrosophenols -- 67. p-Nitrosophenols -- 68. o-Nitrosonaphthol derivatives -- 69. p-Nitrosoarylamines -- 70. m-Dinitro compounds -- 71. Benzaldehydesulfonic acids -- 72. Aminophenols -- 73. Phenylhydrazinesulfonic acids -- 74. Nitro- and aminobenzaldehydes -- Chapter 5. Identification of Individual Organic Compounds -- General remarks -- 1. Acetylene -- 2. Naphthalene -- 3. Anthracene and phenanthrene -- 4. Anthracene -- 5. Phenanthrene -- 6. Chloroform and bromoform -- 7. Bromoform -- 8. Carbon tetrachloride -- 9. Methanol -- 10. Ethanol -- 11. Cyclohexanol and cyclohexanone -- 12. Glycerol -- 13. Inositol -- 14. p-Cresol -- 15. α-Naphthol -- 16. β-Naphthol -- 17. Pyrocatechol -- 18. Resorcinol -- 19. Orcinol -- 20. Naphthoresorcinol -- 21. Hydroquinone -- 22. Pyrogallol -- 23. Hydroxyhydroquinone -- 24. Phloroglucinol -- 25. Pentachlorophenol -- 26. Salicyl alcohol (saligenin). , 27. Carbon monoxide -- 28. Formaldehyde -- 29. Acetaldehyde -- 30. Chloral and bromal -- 31. Citral -- 32. Glyoxal -- 33. o-Phthalaldehyde -- 34. Furfural -- 35. Acetone -- 36. Diacetyl -- 37. Acetylacetone -- 38. p-Benzoquinone -- 39. Chloranil -- 40. Phenanthraquinone -- 41. Rhodizonic acid -- 42. Formic acid -- 43. Acetic acid -- 44. Cinnamic acid -- 45. Oxalic acid -- 46. Esters of oxalic acid -- 47. Malonic acid -- 48. Succinic acid -- 49. Monochloroacetic acid -- 50. Dichloroacetic acid -- 51. Trichloroacetic acid -- 52. Glycolic acid -- 53. Lactic acid -- 54. Glyceric acid -- 55. Malic acid -- 56. Tartaric acid -- 57. Mucic acid -- 58. Citric acid -- 59. Ascorbic acid (vitamin C) -- 60. Salicylic acid -- 61. Phenoxyacetic acid -- 62. Coumarin -- 63. Glyoxalic (glyoxylic) acid -- 64. Pyruvic acid -- 65. Acetoacetic ester -- 66. Phosgene -- 67. Benzoyl peroxide -- 68. Carbon disulfide -- 69. Thio-Michler's ketone -- 70. Thiophene -- 71. Dixanthogen -- 72. Benzenesulfonic acid -- 73. α-Naphthalenesulfonic acid -- 74. Sulfosalicylic acid -- 75. 1,2-Naphthoquinone-4-sulfonic acid -- 76. Phenylsulfuric acid -- 77. Ethylenediamine and propylenediamine -- 78. Hexamethylenetetramine (urotropine, hexamine) -- 79. Aminoacetic acid (glycine) -- 80. α-Aminopropionic acid (α-alanine) -- 81. Hippuric acid -- 82. Tyrosine -- 83. Tryptophan -- 84. Ethylenediaminetetraacetic acid -- 85. Taurine (2-aminoethanesulfonic acid) -- 86. Benzylamine -- 87. α-Naphthylamine -- 88. o-Phenylenediamine -- 89. p-Phenylenediamine -- 90. p-Aminodimethylaniline -- 91. Tetrabase (4,4'-tetramethyldiaminodiphenylmethane) -- 92. Benzidine sulfate -- 93. o-Aminophenol -- 94. m-Aminophenol -- 95. p-Aminophenol -- 96. Ν,Ν-Diphenylanthranilic acid -- 97. Piperidine -- 98. Piperazine -- 99. Carbazole -- 100. Thiodiphenylamine (phenothiazine) -- 101. Pyridine -- 102. Pyridine-2-aldehyde. , 103. 3-Pyridinesulfonic acid -- 104. Quinoline -- 105. Isoquinoline -- 106. 8-Hydroxyquinoline -- 107. 8-Hydroxyquinolinesulfonic acids -- 108. Urea -- 109. Guanidine -- 110. Biguanide -- 111. Melamine -- 112. Formamide -- 113. N,N-Dimethylformamide -- 114. Formanilide -- 115. Benzamide -- 116. Oxamide -- 117. Oxanilide and oxanilic acid -- 118. Succinimide -- 119. N-Bromo(chloro-)succinimide -- 120. Isatin -- 121. Barbituric acid -- 122. Barbituric and thiobarbituric acid -- 123. Alloxan -- 124. Parabanic acid (oxalylurea) -- 125. Hydantoin and allantoin -- 126. Hydrocyanic acid (Prussic acid) -- 127. Dicyanogen -- 128. Cyanogen halides -- 129. Cyanoacetic acid -- 130. Cyanamide -- 131. Dicyanodiamide (cyanoguanidine) -- 132. Benzonitrile (phenyl cyanide) -- 133. Phenylhydrazine -- 134. Hydrazobenzene -- 135. Oxalic acid hydrazides -- 136. p-Nitrosophenol -- 137. α-Nitroso-β-naphthol -- 138. p-Nitrosodimethyl(ethyl)aniline -- 139. Nitromethane -- 140. Nltroethane -- 141. m-Nitrophenol -- 142. p-Nitrobenzaldehyde -- 143. rn-Nitroaniline -- 144. p-Nitroaniline -- 145. Thiocyano-2,4-dinitrobenzene -- 146. Phenylisothiocyanate (phenyl mustard oil) -- 147. N-Phenylsulfamic acid -- 148. Triphenyl phosphate -- Chapter 6. Application of Spot Tests in the Differentiation of Isomers and Homologous Compounds. Determination of Constitutions -- General remarks -- 1. Anthracene and phenanthrene -- 2. Phthalic-terephthalic acid. Maleic-fumaric acid -- 3. Naphthols, aminophenols and nitroanilines -- 4. Thiocyanates and isothiocyanates -- 5. Eugenol-isoeugenol. Safrole-isosafrole -- 6. Vanillins -- 7. Differentiation of dihydroxybenzenes -- 8. ω-Bromoacetophenone and p-bromoacetophenone -- 9. Naphthoquinones -- 10. Isomeric monohalogenofatty acids -- 11. Phenylsulfuric acid and phenolsulfonic acid -- 12. Naphthylamines -- 13. α- and β-Naphthylaminesulfonic acids. , 14. Benzylamine, monomethylaniline and (ο-, m-, p-)toluidine.

Note: Description based upon print version of record , Front Cover; Spot Tests in Inorganic Analysis; Copyright Page; Foreword; Table of Contents; CHAPTER 1. DEVELOPMENT, PRESENT STATE AND PROSPECTS OF INORGANIC SPOT TEST ANALYSIS; References; CHAPTER 2. METHODOLOGY OF SPOT TEST ANALYSIS; 1. Introduction; 2. Laboratory; 3. Sampling; 4. Fundamental treatment; 5. Separation techniques; 6. Handling of vapors and separation of gases; 7. Conduct of spot test analysis; 8. Special methods and procedures; References; CHAPTER 3. PRELIMINARY ORIENTATIONAL TESTS , 1. Behavior of solids when heated on magnesia (spoon) or in contact with porcelain (dish or micro crucible)2. Behavior of solids when heated in an ignition tube; 3. Tests for H+ and OH- ions without use of acid-base indicators; 4. Tests for soluble and insoluble basic materials; 5. Tests for oxidants in acidic medium; 6. Test for oxidizing anions in alkaline medium; 7. Test for reductants in acidic medium; 8. Tests for reductants in alkaline medium; 9. Tests for halogen ions and silver halides; 10. Test for sulfur-bearing materials; 11. Test for anions containing sulfur , 12. Test for metal ions that form insoluble sulfides13. Test for acidic sulfides; 14. Test for compounds that contain divalent sulfur; 15. Test for ions and compounds that remove sulfide ions; 16. Test for elemental selenium, tellurium, arsenic, antimony and tin; 17. Test for arsenicIII, antimonymIII and tinII in alkaline solution; 18. Test based on reduction to the elemental state by iron(II) sulfate; 19. Test for higher metal oxides; 20. Tests for metals that are attacked by dilute acids; 21. Tests for metals that are attacked by caustic alkali , 22. Selective precipitation of palladium, silver and lead as selenosulfate23. Test for oxides of molybdenum, tungsten and vanadium; 24. Test for elementary sulfur, selenium and tellurium; 25. Test for platinum metals; CHAPTER 4. TESTS FOR THE ELEMENTS, THEIR IONS AND COMPOUNDS; Aluminum; Antimony; Arsenic; Barium; Beryllium; Bismuth; Boron; Bromine; Cadmium; Calcium; Carbon; Cerium; Cesium; Chlorine; Chromium; Cobalt; Copper; Fluorine; Gallium; Germanium; Gold; Hafnium; Hydrogen; Indium; Iodine; Iridium; Iron; Lanthanum; Lead; Lithium; Magnesium; Manganese; Mercury; Molybdenum; Nickel , NiobiumNitrogen; Osmium; Oxygen; Palladium; Phosphorus; Platinum; Plutonium; Potassium; Rare earths; Rhenium; Rhodium; Rubidium; Ruthenium; Scandium; Selenium; Silicon; Silver; Sodium; Strontium; Sulfur; Tantalum; Technetium; Tellurium; Thallium; Thorium; Tin; Titanium; Tungsten; Uranium; Vanadium; Yttrium; Zinc; Zirconium; CHAPTER 5. APPLICATION OF SPOT REACTIONS IN TESTS OF PURITY, EXAMINATION OF TECHNICAL MATERIALS, STUDIES OF MINERALS; 1. Detection of alkali metals in silicates; 2. Detection of alkali earth and alkali in ash of paper, charcoal, and coal , 3. Detection of traces of aluminum in water