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  • 1
    Online Resource
    Online Resource
    San Diego :Elsevier Science & Technology,
    Keywords: Catalysis. ; Chemistry, Physical and theoretical. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (433 pages)
    Edition: 1st ed.
    ISBN: 9780080565224
    Series Statement: Issn Series
    DDC: 541.3/95
    Language: English
    Note: Cover -- Copyright -- Contributors -- Preface -- Contents -- Contents of Previous Volumes -- Chapter 1. Stereochemistry and Mechanism of Hydrogenation of Naphthalenes on Transition Metal Catalysts and Conformational Analysis of the Products -- I. Introduction -- II. Conformational Analysis -- III. Experimental -- IV. Mechanism of Hydrogenation of Naphthalene -- V. Hydrogenation of Monomethylnaphthalenes -- VI. Hydrogenation of Dimethylnaphthalenes -- VII. Equilibria and Conformational Analysis of the Octahydronaphthalenes -- VIII. Conclusions -- References -- Chapter 2. The Effects of Ionizing Radiation on Solid Catalysts -- I. Introduction -- II. The Irradiation Technique in Catalysis -- III. Effects of Radiation on Catalytic and Chemisorptive Properties -- IV. Nonspecific Effects of Radiation -- V. Miscellaneous Topics -- VI. Conclusions -- Appendix I: Elementary Considerations on Dosimetry -- Appendix II: Effects of Radiation on Catalytio and Chemisorptive Properties of Solids -- References -- Chapter 3. Organic Catalysis over Crystalline Aluminosilicates -- I. Introduction and Scope -- II. Relation between Catalyst Structure and Catalytic Activity -- III. Organic Reactions Catalyzed by Crystalline Aluminosilicates -- References -- Chapter 4. On Transition Metal-Catalyzed Reactions of Norbornadiene and the Concept of π Complex Multicenter Processes -- I. Introduction -- II. Properties of Norbornadiene -- III. Some Reactions -- IV. Catalysis of Norbornadiene Cycloaddition Reactions -- V. Catalytic Carbonylation -- VI. Catalytic Dimerization -- VII. Binuclear Catalysis: The Stereospecific Synthesis of Binor-S -- VIII. Catalytic Reaction of Zn [Co(CO)4]2 with Acetylene -- IX. Catalytic Trimerization -- X. Summary and Conclusions -- References -- Author Index -- Subject Index.
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  • 2
    Online Resource
    Online Resource
    San Diego :Elsevier Science & Technology,
    Keywords: Catalysis. ; Chemistry, Physical and theoretical. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (445 pages)
    Edition: 1st ed.
    ISBN: 9780080565286
    Series Statement: Issn Series
    DDC: 541.3/95
    Language: English
    Note: Cover -- Copyright -- Contents -- Contributors -- Preface„ Catalysis and Relevance -- Sir Hugh S. Taylor (1890-1974) -- Chapter 1. Kinetics of Coupled Heterogeneous Catalytic Reactions -- I. Introduction -- II. Principles of Some Methods of Kinetic Analysis -- III. Specific Features of the Kinetics of Coupled Heterogeneous Catalytic Reactions -- IV. Experimental Kinetic Studies of Some Systems of Coupled Reactions -- List of Symbols -- References -- Chapter 2. Catalysis for Motor Vehicle Emissions -- I. Introduction -- II. Properties of Automotive Exhaust Gases -- III. Catalysts and Reactors -- IV. Kinetics and Mechanisms -- V. Physical Transport Processes -- VI. Durability of Catalytic Converters -- VII. Reactor Engineering -- VIII. Future Prospects -- List of Symbols -- References -- Chapter 3. The Metathesis of Unsaturated Hydrocarbons Catalyzed by Transition Metal Compounds -- I. Introduction -- II. Reactants and Catalyst Systems -- III. Mechanism -- IV. Thermodynamics and Kinetics -- References -- Chapter 4. One-Component Catalysts for Polymerization of Olefins -- I. Introduction -- II. Chromium Oxide Catalysts -- III. Catalysts Based on the Use of Organometallic Compounds of Transition Metals -- IV. Subhalides of Transition Metals -- V. Determination of the Number of Propagation Centers -- VI. Some General Features of Propagation Center in One-Component Polymerization Catalysts -- VII. Conclusion -- References -- Chapter 5. The Economics of Catalytic Processes -- I. Introduction -- II. Two Classes of Useful Chemical Transformations -- III. The Network of Technological Factors and Constraints Affecting Catalyst Choice -- IV. The Economic Factors and Constraints Affecting Catalyst Choice -- V. Factors Involved in Economic Improvement to Typical Processes and Guidelines for Assessment -- References. , Chapter 6. Catalytic Reactivity of Hydrogen on Palladium and Nickel Hydride Phases -- I. Introduction -- II. Formation, Structure, and Properties of Palladium and Nickel Hydrides -- III. Catalytic Activity of Hydride Phases of Palladium and Its Alloys with Gold or Silver -- IV. The Effect of Transformation into Hydride on the Catalytic Activity of Nickel and Its Alloys with Copper -- V. Catalytic Activity of Other Metal Hydrides in Test Reaction of Hydrogen -- VI. General Remarks and Conclusions -- References -- Chapter 7. Laser Raman Spectroscopy and Its Application to the Study of Adsorbed Species -- I. Introduction -- II. The Origin of the Raman Effect -- III. Instrumentation -- IV. Recording Spectra of Adsorption Systems -- V. Raman Spectra of Adsorbed Molecules -- VI. Conclusion -- Appendix : Normal Coordinates, Vibrational Wavefunctions, and Spectral Activities -- References -- Chapter 8. Analysis of Thermal Desorption Data for Adsorption Studies -- I. Introduction -- II. Fundamental Definitions and Relationships -- III. Temperature Schedules in Thermal Desorption -- IV. Fundamental Relationships for the Determination of the Activation Energy of Desorption, of the Order of Desorption and of the Preexponential Factor -- V. Processing of the Experimental Data to Estimate the Kinetic Parameters of Desorption -- VI. Effects of the Surface Heterogeneity and of the Surface Coverage -- VII. Conclusion -- List of Symbols -- References -- Author Index -- Subject Index -- Contents of Previous Volumes.
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  • 3
    Online Resource
    Online Resource
    San Diego :Elsevier Science & Technology,
    Keywords: Catalysis. ; Chemistry, Physical and theoretical. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (367 pages)
    Edition: 1st ed.
    ISBN: 9780080565194
    Series Statement: Issn Series
    DDC: 541.3/95
    Language: English
    Note: Front Cover -- Advances in Catalysis and Related Subjects, Volume 15 -- Copyright Page -- Contents -- Contributors -- Preface -- Chapter 1. The Atomization of Diatomic Molecules by Metals -- I. Introduction -- II. Experimental Methods -- III. Experimental Results -- IV. Discussion -- V. Conclusions -- References -- Chapter 2. The Clean Single-Crystal-Surface Approach to Surface Reactions -- I. Introduction -- II. The Clean Surface -- III. The Low-Energy Electron Diffraction (LEED) and Work-Function Method -- IV. Vacuum Conditions -- V. Results -- References -- Chapter 3. Adsorption Measurements during Surface Catalysis -- I. Introduction -- II. General Scope of Adsorption Measurements during Surface Catalysis -- III. Experimental Methods -- IV. Decomposition of Germane on Germanium -- V. Decomposition of Formic Acid on Metal Catalysts -- VI. Decomposition of Ammonia on Metal Catalysts -- VII. Ammonia Synthesis on Iron Catalysts -- VIII. Concluding Remarks -- References -- Chapter 4.The Mechanism of the Hydrogenation of Unsaturated Hydrocarbons on Transition Metal Catalysts -- I. Introduction -- II. The Hydrogenation of Olefins -- III. The Hydrogenation of Alkynes and Dienes -- IV. The Hydrocarbon-Metal Bond in Catalytic and Organometallic Chemistry -- References -- Chapter 5. Electronic Spectroscopy of Adsorbed Gas Molecules -- I. Introduction -- II. General Considerations -- III. Spectra of Physically Adsorbed Molecules -- IV. Strong Spectral Perturbations -- V. Positive Ion Spectra of Adsorbed Molecules -- VI. Spectra of Anion Radicals on Surfaces -- VII. Radicals from Adsorbed Molecules -- References -- Chapter 6. The Catalysis of Isotopic Exchange in Molecular Oxygen -- I. Kinetics of Isotopic Exchange in Molecular Oxygen -- II. Some Experimental Data Relating Isotopic Exchange in Molecular Oxygen on Solid Catalysts -- III. Conclusion. , References -- Author Index -- Subject Index.
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  • 4
    Online Resource
    Online Resource
    San Diego :Elsevier Science & Technology,
    Keywords: Catalysis. ; Chemistry, Physical and theoretical. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (435 pages)
    Edition: 1st ed.
    ISBN: 9780080565347
    Series Statement: Issn Series
    DDC: 541.3/95
    Language: English
    Note: Cover -- Copyright -- Contents -- Contributors -- Preface -- Juro Horiuti (1901-1979) -- Chapter 1. Mechanisms of Skeletal lsomerization of Hydrocarbons on Metals -- I. Introduction -- II. Approaches to Mechanisms of Skeletal Rearrangements -- III. Bond Shift -- IV. Cyclic Mechanism -- V. Hydrocracking -- VI . Aromatization -- VII. Skeletal Rearrangements of More Complex Molecules -- VIII. Correlation between Metal Particle Size and Reaction Mechanisms -- References -- Chapter 2. Tin-Antimony Oxide Catalysts -- I. Introduction -- II. Properties of the Catalyst -- III. Influence of Bulk and Surface Properties on Catalytic Performance -- IV. Conclusions -- References -- Chapter 3. Selective Oxidation and Ammoxidation of Propylene by Heterogeneous Catalysis -- I. Introduction -- II. Discussion -- III. Summary and Conclusions -- References -- Chapter 4. Mechanism of Hydrocarbon Synthesis over Fischer-Tropsch Catalysts -- I. Introduction -- II. Product Distribution under Steady-State Conditions -- III. Kinetics -- IV. Surface Spectroscopy -- V. Hydrocarbon Synthesis via Predeposited Carbidic Carbon -- VI. Fischer-Tropsch Synthesis via Carbidic Intermediates -- VII. Suggestions for Future Research -- References -- Chapter 5. Surface Reactions and Selectivity in Electrocatalysis -- I. Introduction -- II. The Art of Electrocatalysis -- III. Basic Electrocatalytic Concepts -- IV. Adsorption on Electrocatalysts -- V. Electrocatalytic Factors -- VI. Electrocatalytic Selectivity -- VII. Electrocatalytic Reactions and Mechanisms -- VIII. Techniques in Electrocatalytic Studies -- IX. Electrochemical Reaction Engineering -- X. Conclusions -- References -- Chapter 6. Solvent and Structure Effects in Hydrogenation of Unsaturated Substances on Solid Catalysts -- I. Introduction -- II. Kinetics of Catalytic Hydrogenations in the Liquid Phase. , III. Correlation Equations Describing the Effect of Structure of Reacting Compounds and Solvents on Reaction Kinetics -- IV. Hydrogenation of Olefinic Substrates -- V. Relationships between the Effect of Structure of Substrates and Solvents on Reactivity -- VI. Conclusion -- VII. List of Symbols -- References -- Author Index -- Subject Index -- Contents of Previous Volumes.
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  • 5
    Online Resource
    Online Resource
    San Diego :Elsevier Science & Technology,
    Keywords: Catalysis. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (363 pages)
    Edition: 1st ed.
    ISBN: 9780080565354
    Series Statement: Issn Series
    DDC: 541.3/95
    Language: English
    Note: Cover -- Copyright -- Contents -- Contributors -- Preface -- Chapter 1. Nonacid Catalysis with Zeolites -- I. Introduction -- II. Oxidation Reactions -- III. Hydrogenation and Dehydrogenation -- IV. Oligomerization Reactions -- V. Carbonylation -- VI. Hydroformylation -- VII. Methanation -- VIII. Conversion of Synthesis Gas to Hydrocarbons -- IX. Miscellaneous Reactions -- X. General Conclusions and Future Prospects -- References -- Chapter 2. Characterization and Reactivity of Mononuclear Oxygen Species on Oxide Surfaces -- I. Introduction -- II. Characterization of O ¯ by EPR and Optical Spectroscopy -- III. The Formation and Stability of O¯ Ions -- IV. Aggregate O¯ Species -- V. Reactivity of the O¯ Ion -- VI. The Surface Oxide Ion O2¯LC -- VII. Characterization and Reactivity of M=O -- Appendix. The EPR Parameters of O¯ Ions -- References -- Chapter 3. Sulfur Poisoning of Metals -- I. Introduction -- II. The Nature of Metal-Sulfur Bonds -- III. Sulfur Adsorption on Metals -- IV. Effects of Sulfur on Adsorption of Other Molecules -- V. Effects of Sulfur on Catalytic Activity and Selectivity Properties of Metals -- VI. Regeneration and Hydrogenolysis -- VII. Conclusions and Recommendations -- References -- Chapter 4. Methanol Synthesis -- I. Introduction -- II. Catalyst Selection -- III. The Activity of Pure Copper Metal -- IV. The Activity of Pure Zinc Oxide -- V. The Binary Copper-Zinc Oxide System -- VI. Other Binary Catalysts -- VII. Ternary and Quaternary Catalysts -- VIII. Mechanisms -- References -- Author Index -- Subject Index -- Contents of Previous Volumes.
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  • 6
    Online Resource
    Online Resource
    San Diego :Elsevier Science & Technology,
    Keywords: Catalysis. ; Chemistry, Physical and theoretical. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (343 pages)
    Edition: 1st ed.
    ISBN: 9780080565149
    Series Statement: Issn Series
    DDC: 541.3/95
    Language: English
    Note: Cover -- Copyright -- Contributors to Volume X -- Preface -- Walter G. Frankenburg 1893-1957 -- Vasili Ilyich Komarewsky -- Contents -- Chapter 1. The Infrared Spectra of Adsorbed Molecules -- I. Introduction -- II. Chemisorption on Supported-Metal Samples -- III. Chemisorption on Acidic Oxides -- IV. Spectra of Adsorbed Water and Surface Hydroxyl Groups on Nonacidic Oxides -- V. Infrared Spectra of Physically Adsorbed Molecules -- VI. The Pressed-Salt Method for Obtaining Spectra of Adsorbed Molecules -- VII. Spectra of Molecules Adsorbed on Unsupported Metals -- VIII. Conclusion -- References -- Chapter 2. The Influence of Crystal Face in Catalysis -- I. Introduction -- II. Factors to be Considered in Developing a Theory of the Influence of Face -- III. The Single-Crystal Method of Studying Surface Reactions -- IV. Results -- V. Discussion -- References -- Chapter 3. The Nature of Active Centers and the Kinetics of Catalytic Dehydrogenation -- I. Quasi-Homogeneous Surfaces -- II. Flow Method Kinetics -- III. Experimental Results on Dehydrogenation -- IV. Discussion of Results and the Multiplet Theory -- V. Summary -- References -- Chapter 4. The Structure of the Active Surface of Cholinesterases and the Mechanism of Their Catalytic Action in Ester Hydrolysis -- I. Introduction -- II. Enzyme Sources -- III. Methods -- IV. Catalytic Effects of Cholinesterases -- V. Mechanism of Hydrolysis by Cholinesterases -- VI. Structure of the Esteratic Site -- VII. The Anionic Sites in the Active Centers of Cholinesterases -- VIII. Concluding Remarks -- References -- Chapter 5. Commerical Alkylation of Paraffins and Aromatics -- I. Introduction -- II. Sources of Feed Stock -- III. Basic Factors in Alkylation -- IV. Alkylation Reactions -- V. Alkylation Processes -- VI. Materials of Construction -- VII. Future Outlook for Alkylation -- References. , Chapter 6. The Reactivity of Oxide Surfaces -- I. Introduction -- II. Experimental Method -- III. Exchange Kinetics -- IV. Interactions between Oxygen and Oxide Surfaces -- V. Exchange Reactions of CO and CO2 -- VI. Application to Catalytic Reactions -- References -- Chapter 7. The Structure and Activity of Metal-on-Silica Catalysts -- I . Introduction -- II. Texture and Structure of Ni„SiO2 Catalysts -- III. The Adsorption Bond and the Statistical Thermodynamics of the Adsorption Data -- IV. The Catalytic Activity of Ni„SiO2 Catalysts -- V. Some Properties of Other Metal-SiO2 Catalysts -- References -- Author Index -- Subject Index.
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  • 7
    Online Resource
    Online Resource
    San Diego :Elsevier Science & Technology,
    Keywords: Catalysis. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (415 pages)
    Edition: 1st ed.
    ISBN: 9780080565316
    Series Statement: Issn Series
    DDC: 541.3/95
    Language: English
    Note: Front Cover -- Advances in Catalysis, Volume 27 -- Copyright Page -- Contents -- Contributors -- Preface -- Corrigendum -- Chapter 1. Electronics of Supported Catalysts -- I. Introduction -- II. Normal Supported Catalysts -- III. Inverse Supported Catalysts -- IV. Two Semiconductors -- V. Physical Observations -- VI. Conclusions -- References -- Chapter 2. The Effect of a Magnetic Field on the Catalyzed Nondissociative Parahydrogen Conversion Rate -- I. Introduction -- II. Conversion Rate Measurements -- III. Experimental Results -- IV. Correlation of Experimental Results -- V. Conversion and Field Effect Theory -- VI. Conclusions -- References -- Chapter 3. Hysteresis and Periodic Activity Behavior in Catalytic Chemical Reaction Systems -- I. Introduction -- II. Porous Catalyst Particle Problem -- III. Catalytic Wire Problem -- IV. Continuous Stirred-Tank Reactor -- V. Tubular Fixed-Bed Reactor -- VI. Monolithic Catalyst -- VII. Other Catalytic Systems -- VIII. Concluding Remarks -- Notation -- References -- Chapter 4. Surface Acidity of Solid Catalysts -- I. Introduction -- II. Critique of Methods for Determination of Surface Acidity -- III. Review of Acidity and Catalytic Activity of Specific Solids -- References -- Chapter 5. Selective Oxidation of Propylene -- I. Introduction -- II. Activation of Propylene -- III. Activation of Oxygen -- IV. Active Catalyst Systems -- V. Nature of the Active Sites -- VI. Conclusions -- References -- Chapter 6. σ-π Rearrangements and Their Role in Catalysis -- I. Introduction -- II. σ-π Rearrangement -- III. Classification of σ-π Rearrangements -- IV. Role of σ-π Rearrangement in Catalysis -- V. Conclusion -- References -- Chapter 7. Characterization of Molybdena Catalysts -- I. Introduction -- II. Background -- III. Catalyst Preparation -- IV. Characterization Techniques -- V. State of Molybdena Catalysts. , VI. Catalyst Activities -- VII. Proposed Models of the Sulfided Catalyst -- VIII. Role of Cobalt -- IX. Nickel-Molybdena Catalysts -- X. Active Sites-Concluding Remarks -- References -- Chapter 8. Poisoning of Automotive Catalysts -- I. Introduction -- II. Catalysts -- III. Poisons -- IV. Analysis and Examination of Poisons on Catalysts -- V. Early Observations of Catalyst Poisoning -- VI. Contaminant Retention -- VII. Poison Distribution -- VIII. Thermal Deactivation versus Poisoning -- IX. Mass Transfer Effects in Poisoned Catalysts -- X. Poisoning Effects of Individual Elements -- XI. Interaction between Poisons and Active Components -- XII. Poison-Resistant Automotive Catalysts -- XIII. Catalyst Rejuvenation -- XIV. Future Developments -- References -- Author Index -- Subject Index -- Contents of Previous Volumes.
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  • 8
    Online Resource
    Online Resource
    San Diego :Elsevier Science & Technology,
    Keywords: Catalysis. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (379 pages)
    Edition: 1st ed.
    ISBN: 9780080565262
    Series Statement: Issn Series
    DDC: 541.3/95
    Language: English
    Note: Front Cover -- Advances in Catalysis, Volume 22 -- Copyright Page -- Contents -- Contributors -- Preface -- Chapter 1.Hydrogenation and Isomerization over Zinc Oxide -- I. Introduction -- II. The Active Sites -- III. Mechanism of Ethylene Hydrogenation -- IV. Reactions with Propylene -- V. Reactions of Butene -- VI. Reactions of Acetylenes -- VII. Concluding Remarks -- References. -- Chapter 2.Chemisorption Complexes and Their Role in Catalytic Reactions on Transition Metals -- I. Introduction -- II. General Formation of the Problem -- III. Chemisorption Complexes -- IV. Characterization of the Metal Surfaces -- V. Concluding Remarks -- References -- Chapter 3. Influence of Metal Particle Size in Nickel-on-Aerosil Catalysts on Surface Site Distribution, Catalytic Activity, and Selectivity -- I. Introduction -- II. Statistics of Surface Atoms and Surface Sites -- III. Infrared Studies on the Adsorption of N2, CO, and CO2 -- IV. Deuteration and Exchange of Benzene -- V. Conclusions -- VI. Preparation and Characterization of Catalysts -- References -- Chapter 4. Adsorption and Catalysis on Evaporated Alloy Films -- I. Introduction -- II. Preparation of Alloy Films -- III.Characterization of Alloy Films -- IV. Adsorption and Catalysis on Alloy Films -- V. Conclusions -- References -- Chapter 5. Heat-Flow Microcalorimetry and Its Application to Heterogeneous Catalysis -- I. Introduction -- II. Principle of Heat-Flow Calorimetry -- III. Some Heat-Flow Microcalorimeters That Can Be Used in Heterogeneous Catalysis Research -- IV. Theory of Heat-Flow Calorimetry -- V. Analysis of the Calorimetric Data -- VI. Measurement of the Differential Heats of Gas-Solid Interactions -- VII. Applications of Heat-Flow Microcalorimetry in Heterogeneous Catalysis -- VIII. Conclusions -- References -- Chapter 6. Electron Spin Resonance in Catalysis -- I. Introduction. , II. The Theoretical Basis -- III. Experimental Considerations -- IV. Applications -- References -- Appendix A : Quantum Mechanics for Spin Systems . . -- Appendix B: Determination of Energy Levels from the Spin Hamiltonnian -- Appendix C: The g Tensor -- Appendix D : The Hyperfine Tensor -- Author Index -- Subject Index -- Contents of Previous Volumes.
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  • 9
    Online Resource
    Online Resource
    San Diego :Elsevier Science & Technology,
    Keywords: Catalysis. ; Chemistry, Physical and theoretical. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (363 pages)
    Edition: 1st ed.
    ISBN: 9780080565279
    Series Statement: Issn Series
    DDC: 541.3/95
    Language: English
    Note: Intro -- Front Cover -- Advances in Catalysis, Volume 23 -- Copyright Page -- Contents -- Contributors -- Preface -- Chapter 1. Metal Catalyzed Skeletal Reactions of Hydrocarbons -- I. Introduction -- II. Catalyst Structure -- Ill. Experimental Techniques -- IV. lsomerization and Dehydrocyclization Reactions on Metals -- V. Hydrogenolysis on Metals. -- VI. Reactions over Chromium Oxide Catalysts -- References -- Chapter 2. Specificity in Catalytic Hydrogenolysis by Metals -- I. Introduction -- II. General Discussion on Hydrogenolysis Reactions -- III. Comparison of Metals as Hydrogenolysis Catalysts. -- IV. Contrast between Ethane Hydrogenolysis and Other Reactions -- V. Conclusion -- References -- Chapter 3. The Chemisorption of Benzene -- I. Introduction, -- II. Chemisorption -- Ill. Exchange Reactions -- IV. Some Aspects of Benzene Hydrogenation. -- V. Conclusions -- References -- Chapter 4. The Electronic Theory of Photocatalytic Reactions on Semiconductors -- Introduction -- I. The Mechanism of the Influence of Illumination on the Adsorption and Catalytic Properties of a Surface -- II. The Photoadsorptive Effect -- III. The Reaction of Hydrogen-Deuterium Exchange -- IV. The Reaction of Oxidation of Carbon Monoxide -- V. The Reaction of Synthesis of Hydrogen Peroxide -- VI. Conclusions -- References -- Chapter 5. Cycloamyloses as Catalysts -- I. Introduction -- II. Physical Properties of the Cycloamyloses -- III. Reactions in Which the Cycloamyloses Participate Covalently -- IV. Noncovalent Catalysis by the Cycloamyloses -- V. Catalytic Properties of Modified Cycloamyloses -- VI. Concluding Remarks -- References -- Chapter 6. Pi and Sigma Transition Metal Carbon Compounds as Catalysts for the Polymerization of Vinyl Monomers and Olefins -- I. Introduction -- II. Soluble Transition Metal Alkyl Compounds as Polymerization Catalysts. , III. Ligand Replacement in Transition Metal Alkyl Compounds and Polymerization Activity -- IV. Heterogeneous Polymerization Catalysts Derived from Transition Metal Alkyl Compounds. -- V. Stereoregular Polymerization with Transition Metal Alkyls -- VI. Mechanism of Polymerization -- VII. Conclusion -- References -- Author Index -- Subject Index -- Contents of Previous Volumes.
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  • 10
    Online Resource
    Online Resource
    San Diego :Elsevier Science & Technology,
    Keywords: Catalysis. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (409 pages)
    Edition: 1st ed.
    ISBN: 9780080565378
    Series Statement: Issn Series
    DDC: 541.3/95
    Language: English
    Note: Front Cover -- Advances in Catalysis, Volume 33 -- Copyright Page -- Contents -- Contributors -- Paul Hugh Emmett, 1900-1985 -- Chapter 1. Homogeneous Nickel-Catalyzed Olefin Hydrocyanation -- I. Introduction and Scope -- II. Equilibria Involving Ni(0) Complexes -- III. Dienes and HCN -- IV. Olefin Isomerization -- V. Monoolefins and HCN -- References -- Chapter 2. Supported Chromium Catalysts for Ethylene Polymerization -- Introduction -- I. Hexavalent Cr/Silica -- II. Reduced Cr/Silica -- III. Polymerization over Cr/Silica -- IV. The Porosity of the Support -- V. Modifications of Cr/Silica -- VI. Chromium Oxide on Other Support -- VII. Organochromium Catalysis -- References -- Chapter 3. Catalysis Controlled by the Constitution of Active Sites -- I. Introduction -- II. Isomerization Reaction -- III. Hydrogen Exchange Reaction -- IV. Hydrogenation Reaction -- V. Conclusion -- References -- Chapter 4. Selective Oxidative Dehydrogenation of Butenes on Ferrite Catalysts -- I. Introduction -- II. Selective Oxidation and Combustion Sites -- III. Densities of Oxidation Sites -- IV. Role of Adsorbed Oxygen -- V. Role of Lattice Oxygen -- VI. Kinetics and Mechanism -- VII. Factors Affecting Selectivity: Roles of Crystal Structure, Nature of Transition Metal Ions, and Effect of Promoters -- VIII. Effect of Crystallite Size -- IX. Other Structure-Sensitive Oxidation Reactions -- X. Catalytic Activity of Iron Hydroxide -- XI. Conclusions -- References -- Chapter 5. The Study of Aluminosilicate and Related Catalysts by High- Resolution Solid-state NMR Spectroscopy -- I. Introduction -- II. Relevant Spectroscopic Considerations -- III. Solide-State NMR Studies of Zeolites -- IV. Silica-Alumina Gels -- V. Derivatized Surfaces and "Immobilized" Homogeneous Catalysts -- VI. Probing Supported Metal Catalysts by NMR without Utilizing High-Resolution Techniques. , VII. Bond Lengths, Structure, and Mechanism in Heterogeneous Catalysis and in Chemisorbed States -- VIII. Sheet Silicates and Their Pillared Variants -- IX. Recent Trends in the Study of Catalytic Solids by NMR -- References -- Author Index -- Subject Index.
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