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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 60 (1996), S. 153-159 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The aging of high-density polyethylene (HDPE) when exposed to drastic climatic conditions (Canadian winter, characterized by low temperature and abrupt temperature variations between the night and the day) was studied. The importance of degradation was determined by evaluating the microstructural changes in HDPE (i.e., oxidations, ramifications, and polymeric chain breaking) by means of FTIR spectrophotometry. The crystallinity variation in HDPE by FTIR and DSC was also studied. Both techniques led to coherent results: there was a loss of crystallinity due to weathering degradation. This crystallinity reduction produced a drastic decrease in impact energy. However, the other properties evaluated were not significantly affected. © 1996 John Wiley & Sons, Inc.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary This paper studies polymer composites formed by a polystyrene matrix (PS) and a block copolymer of poly(styrene-butadiene) (SBS). Two series of polymer composites with different compositions have been prepared: the first by extrusion followed by injection and the second by dissolution and evaporation of the solvent from the injected samples. The comparison of the FTIR spectra of the polymer composites with those simulated by addition of the spectra of the component polymers allows the detection of differences attributed to the existence of interactions between both polymers that cause partial miscibility between them. The results obtained are corroborated by differential scanning calorimetry.
    Type of Medium: Electronic Resource
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