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  • 1
    Publication Date: 2021-01-25
    Description: The circulation of groundwater is influenced by several factors, including permeability changes due to the dynamics of the stress field acting along tectonic discontinuities. Open faults can act as preferential pathways for the escape of crustal and subcrustal gases, such as CO2, towards the surface, allowing their chemical interaction with meteoric fluids. Here, we present the first map of dissolved CO2 partial pressure in the groundwater of Sicily, Italy. Based on the chemical analysis of 557 samples of groundwater, which were collected in wells and springs, we calculated the related CO2 partial pressure (PCO2) using PHREEQC software. The spatial distribution of the calculated PCO2 values highlights a general homogeneity at the regional scale, interrupted by positive anomalies linked to the main seismogenic or volcanic areas. Faults work as preferential escape pathways for deep CO2. The subsequent CO2–water–rock interaction determines the chemical composition of circulating water. As a consequence, groundwater composition can be successfully used to identify anomalous degassing areas.
    Description: Published
    Description: 1959
    Description: 7T. Variazioni delle caratteristiche crostali e precursori sismici
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2020-09-01
    Description: Groundwater from karst circulation systems of Central Italy were sampled and analyzed, in 2018, for delineating a preliminary, general geochemical framework of their relationship with neotectonics, in an area characterized by a frequent and often destructive seismicity. We determined field physical-chemical parameters, concentrations of main dissolved ions and gases and isotopic composition of water ( 18O, D) and total dissolved inorganic carbon ( 13C TDIC). We discriminated between “normal” hydro-karst systems and multi-component aquifers, composed of meteoric groundwater that have also interacted with rocks of di erent lithological nature and/or deep fluids. These multicomponent aquifers are of potential interest in the monitoring of neotectonics activity, because changes in the stress field associated with the preparatory phase of an earthquake may a ect the permeability of rocks, in turn causing variation of their chemical-isotopic character. The geographical distribution of these aquifers seems to be controlled by tectonics. In fact, the Olevano–Antrodoco–Sibillini thrust separates the more anomalous sites, located westwards of it, from the groundwater bodies at its eastern side, showing a more typical karst character.
    Description: Published
    Description: id 1926
    Description: 7T. Variazioni delle caratteristiche crostali e precursori sismici
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Publication Date: 2021-05-12
    Description: Although groundwater is a strategic source in volcanic islands, most hydrogeochemical research on this topic has been focused on volcanic activity monitoring, overlooking general hydrogeological aspects. The same applies to one of the most studied volcanoes in the world, Stromboli Island (Italy). Here, we provide a hydrogeological scheme of its coastal aquifer, retrieving inferences about its potential use as a water supply source and for optimizing monitoring protocols for volcanic surveillance. Starting from the hydrogeochemical literature background, we analyzed new data, acquired both for volcano monitoring purposes and during specific surveys. Among these, there were saturated hydraulic conductivity measurements of selected rock samples and precise determinations of water table elevations based on GNSS surveys of wells. We identified a ubiquitous thin lens of brackish water floating on seawater and composed of a variable mixing of marine and meteoric components; inlets of hydrothermal fluids to the aquifer are basically gases, mainly CO2. Based on its hydrogeochemical character, the coastal aquifer of Stromboli could be used as a water supply source after desalinization by reverse osmosis, while the wells located far from the seashore are the most interesting for volcano monitoring, because they are less disturbed by the shallow geochemical noise.
    Description: Published
    Description: 417
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 4
    Publication Date: 2021-05-12
    Description: No abstract
    Description: Published
    Description: 115-118
    Description: 1TM. Formazione
    Description: N/A or not JCR
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 5
    Publication Date: 2021-06-22
    Description: Since 2016, Stromboli volcano has shown an increase of both frequency and energy of the volcanic activity; two strong paroxysms occurred on 3 July and 28 August 2019. The paroxysms were followed by a series of major explosions, which culminated on January 2021 with magma overflows and lava flows along the Sciara del Fuoco. This activity was monitored by the soil CO2 flux network of Istituto Nazionale di Geofisica e Vulcanologia (INGV), which highlighted significant changes before the paroxysmal activity. The CO2 flux started to increase in 2006, following a long-lasting positive trend, interrupted by short-lived high amplitude transients in 2016–2018 and 2018–2019. This increasing trend was recorded both in the summit and peripheral degassing areas of Stromboli, indicating that the magmatic gas release affected the whole volcanic edifice. These results suggest that Stromboli volcano is in a new critical phase, characterized by a great amount of volatiles exsolved by the shallow plumbing system, which could generate other energetic paroxysms in the future.
    Description: Published
    Description: 169
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Keywords: Stromboli volcano; paroxysmal activity; soil CO2 fluxes
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 6
    Publication Date: 2020-09-10
    Description: Paroxysmal explosions are some of the most spectacular evidence of volcanism on Earth andare triggered by the rapid ascent of volatile-rich magma. These explosions often occur in persistentlyerupting basaltic volcanoes located in subduction zones and represent a major hazard due to thesudden occurrence and wide impact on the neighboring populations. However, the recognition ofsignals that forecast these blasts remains challenging even in the best-monitored volcanoes. Here, wepresent the results of the regular monitoring of soil CO2flux from a fumarole field at the summit ofStromboli (Italy), highlighting that the 2016–2019 period was characterized by two important phasesof strong increases of volatile output rate degassing (24 g m2d−2and 32 g m2d−2, respectively)and moreover by significant changes in the degassing style few months before the last paroxysmalexplosions occurred in the summer 2019 (3 July and 28 August). Establish that the deep portionsof a volcano plumbing system are refilled by new volatiles-rich magma intruding from the mantleis therefore a key factor for forecasting eruptions and helping in recognizing possible precursors ofparoxysmal explosions and could be highlighted by the monitoring of soil CO2flux. The abruptincrease of degassing rate coupled with the strong increase of fluctuating signal (daily naturaldeviation) recorded during 2019 at Stromboli could be the key to predicting the occurrence ofparoxysmal events.
    Description: Published
    Description: id 4757
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Keywords: Stromboli volcano; geochemical monitoring; CO2degassing; paroxysmal activity
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 7
    Publication Date: 2020-11-17
    Description: The Santa Ninfa karst system is an area strongly controlled by tectonics, whose intense fracturing gave rise to the formation of a large number of cavities that foster the drainage of water. The hydrogeochemical characters of groundwater circulating in this aquifer, together with its isotopic signature, were investigated in detail. The chemistry of groundwater reflects the nature of the rocks hosting the aquifers, constituted by primary and diagenetic selenitic gypsum, salts, and gypsum-arenite, whose dissolution is responsible of the geochemical fingerprint of the quasi-totality of the samples. A single site (CAM) is characterised by a different chemical composition, indicating a mixing between Ca-sulphate, Ca-bicarbonate and a NaCl-rich water. From the chemical point of view, no evidence of interaction between shallow groundwater and deep fluids has been detected. Conversely, isotopic fluctuations highlight mixing processes between surficial (evaporated) runoff and groundwater. Different mixing proportion among these endmembers can be reflected in variations of the chemical character of the sampled springs. Changes in mixing proportions can be the effect of differential permeability variations, in turn produced by local stress field changes during seismogenic processes. In this scenario the geochemical monitoring of the Santa Ninfa karst aquifer could be of relevant interest in the study of seismogenic processes in this area, with particular reference to the relationship between seismic and geochemical transients.
    Description: Published
    Description: SE102
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: Hydrogeochemistry ; Gypsum karst system ; Neotectonics, ; Groundwater. ; 03.02. Hydrology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 8
    Publication Date: 2021-01-25
    Description: The underground systems for catchment and storage of meteoric water are a type of hydraulic works with a multi-millenary history, presently used, and with very interesting future perspectives in the framework the conversion to the “green economy”. An interesting topic, related to the possible anthropic reuse of ancient meteoric water collection and storage systems, is the evaluation of the chemical interactions between water and the rocks inside which these systems are carved, and the possible superseding of maximum admitted concentrations of chemical species potentially toxic or noxious for human health. In this work, after a review of the lithological nature of these systems, we discuss the chemical character of the water they collect, using direct measures and theoretical data from the literature, giving indications for its possible anthropic uses.
    Description: Published
    Description: 29-34
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: N/A or not JCR
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 9
    Publication Date: 2021-01-29
    Description: Oxygen isotopic composition is useful for individuating recharge areas of groundwater bodies by the comparison with those of local rainfalls. While on a global scale general relationships, such as the isotopic vertical gradient or continentality effects, efficiently describe spatial variations of the isotopic signature, hydrogeological applications need spatial models that are more focused on the effects of local topographic structures and/or subsoil geology. This work presents a case study in northeastern Sicily (Italy) characterized by complex geological and orographic structures, in which isotopic composition of rainfalls is governed by orographic effects and the varying initial composition of humid air masses. We used a black box approach, comparing the average isotopic composition of rain collected from a network of eight samplers with their spatial descriptors (elevation, latitude and longitude). We obtained the best correlation with the simultaneous use of all these variables, applying their multiple linear correlation equation to transform the 1 × 1 km digital elevation model (DEM) of the study area into a digital isotopic model (DIM). The reliability of the DIM was confirmed by its good agreement with the oxygen isotopic composition contour map of the local groundwater.
    Description: Published
    Description: 22
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Limitation Availability
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  • 10
    Publication Date: 2017-04-19
    Description: Many lakes have been the object of hydraulic works in historical times, and the drainage tunnel carved by Romans for regulating the level of Lake Albano (Central Italy) can be considered as one of the most important historical hydraulic tunnels in the world. We sampled and analysed lake water, as well as groundwater samples from the Lake Albano emissary and another hydraulic work in the area (Ninfeo), which were analysed for their geochemical and isotopic composition in order to extract useful information for a possible reuse of the tunnel for anthropogenic purposes. The collected water samples exhibit common chemical features, typical of water–rock interaction processes in volcanic areas. Analyses of minor and trace elements confirmed the abovementioned results, indicating the presence of an atmospheric pollution source for heavy metals, although their concentrations are mostly below the Maximum Admitted Concentrations for drinking water issued by the World Health Organization. The chemical composition of dissolved gases indicated that both lake and groundwater are mainly enriched in CO2. Isotopic analyses suggested a clear volcanic origin for CO2 dissolved in lake water, while carbon dioxide in groundwater from the Roman emissary is produced by soil respiration. As further confirmed by Oxygen and Deuterium isotopic composition, the Roman emissary drains local suspended aquifers neither in contact with the lake water body nor influenced by volcanic activity, suggesting the opportunity to use the tunnel as a ‘‘zero-condition’’ monitoring site for individuating a possible future renewal of volcanic activity.
    Description: Published
    Description: 289
    Description: 6A. Geochimica per l'ambiente
    Description: JCR Journal
    Keywords: Hydrochemistry ; Isotopes ; Lacustrine environment ; Drainage tunnel ; Volcano monitoring ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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