Description: We present a global atlas of downcore foraminiferal oxygen and carbon isotope ratios available at https://doi.org/10.1594/PANGAEA.936747 (Mulitza et al., 2021a). The database contains 2106 published and previously unpublished stable isotope downcore records with 361 949 stable isotope values of various planktic and benthic species of Foraminifera from 1265 sediment cores. Age constraints are provided by 6153 uncalibrated radiocarbon ages from 598 (47 %) of the cores. Each stable isotope and radiocarbon series is provided in a separate netCDF file containing fundamental metadata as attributes. The data set can be managed and explored with the free software tool PaleoDataView. The atlas will provide important data for paleoceanographic analyses and compilations, site surveys, or for teaching marine stratigraphy. The database can be updated with new records as they are generated, providing a live ongoing resource into the future.

Description: The transfer of vast amounts of carbon from a deep oceanic reservoir to the atmosphere is considered to be a dominant driver of the deglacial rise in atmospheric CO2. Paleoceanographic reconstructions reveal evidence for the existence of CO2-rich waters in the mid to deep Southern Ocean. These water masses ventilate to the atmosphere south of the Polar Front, releasing CO2 prior to the formation and subduction of intermediate-waters. Changes in the amount of CO2 in the sea water directly affect the oceanic carbon chemistry system. Here we present B/Ca ratios, a proxy for delta carbonate ion concentrations Δ[CO32−], and stable isotopes (δ13C) from benthic foraminifera from a sediment core bathed in Antarctic Intermediate Water (AAIW), offshore New Zealand in the Southwest Pacific. We find two transient intervals of rising [CO32−] and δ13C that that are consistent with the release of CO2 via the Southern Ocean. These intervals coincide with the two pulses in rising atmospheric CO2 at ~ 17.5–14.3 ka and 12.9–11.1 ka. Our results lend support for the release of sequestered CO2 from the deep ocean to surface and atmospheric reservoirs during the last deglaciation, although further work is required to pin down the detailed carbon transfer pathways.

Description: Glacio-eustatic cycles lead to changes in sedimentation on all types of continental margins. There is, however, a paucity of sedimentation rate data over eustatic sea-level cycles in active subduction zones. During International Ocean Discovery Program Expedition 375, coring of the upper ∼110 m of the northern Hikurangi Trough Site U1520 recovered a turbidite-dominated succession deposited during the last ∼45 kyrs (Marine Isotope Stages (MIS) 1–3). We present an age model integrating radiocarbon dates, tephrochronology, and δ18O stratigraphy, to evaluate the bed recurrence interval (RI) and sediment accumulation rate (SAR). Our analyses indicate mean bed RI varies from ∼322 yrs in MIS1, ∼49 yrs in MIS2, and ∼231 yrs in MIS3. Large (6-fold) and abrupt variations in SAR are recorded across MIS transitions, with rates of up to ∼10 m/kyr occurring during the Last Glacial Maximum (LGM), and 〈1 m/kyr during MIS1 and 3. The pronounced variability in SAR, with extremely high rates during the LGM, even for a subduction zone, are the result of changes in regional sediment supply associated with climate-driven changes in terrestrial catchment erosion, and critical thresholds of eustatic sea-level change altering the degree of sediment bypassing the continental shelf and slope via submarine canyon systems.

Description: Author Posting. © American Geophysical Union, 2017. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 32 (2017): 512–530, doi:10.1002/2016PA003072.

Description: The carbon isotope composition (δ13C) of seawater provides valuable insight on ocean circulation, air-sea exchange, the biological pump, and the global carbon cycle and is reflected by the δ13C of foraminifera tests. Here more than 1700 δ13C observations of the benthic foraminifera genus Cibicides from late Holocene sediments (δ13CCibnat) are compiled and compared with newly updated estimates of the natural (preindustrial) water column δ13C of dissolved inorganic carbon (δ13CDICnat) as part of the international Ocean Circulation and Carbon Cycling (OC3) project. Using selection criteria based on the spatial distance between samples, we find high correlation between δ13CCibnat and δ13CDICnat, confirming earlier work. Regression analyses indicate significant carbonate ion (−2.6 ± 0.4) × 10−3‰/(μmol kg−1) [CO32−] and pressure (−4.9 ± 1.7) × 10−5‰ m−1 (depth) effects, which we use to propose a new global calibration for predicting δ13CDICnat from δ13CCibnat. This calibration is shown to remove some systematic regional biases and decrease errors compared with the one-to-one relationship (δ13CDICnat = δ13CCibnat). However, these effects and the error reductions are relatively small, which suggests that most conclusions from previous studies using a one-to-one relationship remain robust. The remaining standard error of the regression is generally σ ≅ 0.25‰, with larger values found in the southeast Atlantic and Antarctic (σ ≅ 0.4‰) and for species other than Cibicides wuellerstorfi. Discussion of species effects and possible sources of the remaining errors may aid future attempts to improve the use of the benthic δ13C record.

Description: U.S. National Science Foundation Grant Numbers: 1634719, 0926735, 1125181; Swiss National Science Foundation Grant Numbers: PP00P2_144811, 200021_163003; Canadian Institute for Advanced Research (CIFAR); Canadian Foundation for Innovation (CFI); Natural Sciences and Engineering Research Council (NSERC)

Description: 2017-12-03

Description: The transfer of vast amounts of carbon from a deep oceanic reservoir to the atmosphere is considered to be a dominant driver of the deglacial rise in atmospheric CO2. Paleoceanographic reconstructions reveal evidence for the existence of CO2-rich waters in the mid to deep Southern Ocean. These water masses ventilate to the atmosphere south of the Polar Front, releasing CO2 prior to the formation and subduction of intermediate-waters. Changes in the amount of CO2 in the sea water directly affect the oceanic carbon chemistry system. Here we present B/Ca ratios, a proxy for delta carbonate ion concentrations Δ[CO32−], and stable isotopes (δ13C) from benthic foraminifera from a sediment core bathed in Antarctic Intermediate Water (AAIW), offshore New Zealand in the Southwest Pacific. We find two transient intervals of rising [CO32−] and δ13C that that are consistent with the release of CO2 via the Southern Ocean. These intervals coincide with the two pulses in rising atmospheric CO2at ~ 17.5–14.3 ka and 12.9–11.1 ka. Our results lend support for the release of sequestered CO2 from the deep ocean to surface and atmospheric reservoirs during the last deglaciation, although further work is required to pin down the detailed carbon transfer pathways.

Description: © The Author(s), 2012. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Geochimica et Cosmochimica Acta 96 (2012): 174-192, doi:10.1016/j.gca.2012.08.002.

Description: Despite a growing body of work that uses diatom δ30Si to reconstruct past changes in silicic acid utilisation, few studies have focused on calibrating core top data with modern oceanographic conditions. In this study, a microfiltration technique is used to divide Southern Ocean core top silica into narrow size ranges, separating components such as radiolaria, sponge spicules and clay minerals from diatoms. Silicon isotope analysis of these components demonstrates that inclusion of small amounts of non-diatom material can significantly offset the measured from the true diatom δ30Si. Once the correct size fraction is selected (generally 2–20 μm), diatom δ30Si shows a strong negative correlation with surface water silicic acid concentration (R2 = 0.92), highly supportive of the qualitative use of diatom δ30Si as a proxy for silicic acid utilisation. The core top diatom δ30Si matches well with mixed layer filtered diatom δ30Si from published in situ studies, suggesting little to no effect of either dissolution on export through the water column, or early diagenesis, on diatom δ30Si in sediments from the Southern Ocean. However, the core top diatom δ30Si shows a poor fit to simple Rayleigh or steady state models of the Southern Ocean when a single source term is used. The data can instead be described by these models only when variations in the initial conditions of upwelled silicic acid concentration and δ30Si are taken into account, a caveat which may introduce some error into quantitative reconstructions of past silicic acid utilisation from diatom δ30Si.

Description: The Oxford isotope geochemistry lab is supported by an ERC grant to Halliday. This work was carried out as part of Natural Environmental Research Council (NERC) Grant NE/F005296/1, and Antarctic Peninsula core tops collected thanks to the Antarctic Funding Initiative Grant AFI4-02.

Description: 〈jats:p〉Abstract. We present a global atlas of downcore foraminiferal oxygen and carbon isotope ratios available at https://doi.org/10.1594/PANGAEA.936747 (Mulitza et al., 2021a). The database contains 2106 published and previously unpublished stable isotope downcore records with 361 949 stable isotope values of various planktic and benthic species of Foraminifera from 1265 sediment cores. Age constraints are provided by 6153 uncalibrated radiocarbon ages from 598 (47 %) of the cores. Each stable isotope and radiocarbon series is provided in a separate netCDF file containing fundamental metadata as attributes. The data set can be managed and explored with the free software tool PaleoDataView. The atlas will provide important data for paleoceanographic analyses and compilations, site surveys, or for teaching marine stratigraphy. The database can be updated with new records as they are generated, providing a live ongoing resource into the future. 〈/jats:p〉

Description: A model is presented for hemipelagic siliciclastic and carbonate sedimentation during the last glacial-interglacial cycle in the Capricorn Channel, southern Great Barrier Reef (GBR). Stable isotope ratios, grainsize, carbonate content and mineralogy were analysed for seven cores in a depth transect from 166 to 2892 m below sea level (mbsl). Results show variations in the flux of terrigenous, neritic and pelagic sediments to the continental slope over the last sea level cycle. During the glacial lowstand terrigenous sediment influenced all the cores down to 2000 mbsl. The percentages of quartz and feldspar in the cores decreased with water depth, while the percentage of clay increased. X-ray diffraction analysis of the glacial lowstand clay mineralogy suggests that the siliciclastic sediment was primarily sourced from the Fitzroy River, which debouched directly into the northwest sector of the Capricorn Channel at this time. The cores also show a decrease in pelagic calcite and an increase in aragonite and high magnesium calcite (HMC) during the glacial. The influx of HMC and aragonite is most likely from reworking of coral reefs exposed on the continental shelf during the glacial, and also from HMC ooids precipitated at the head of the Capricorn Channel at this time. Mass accumulation rates (MARs) are high (13.5 g/cm**/kyr) during the glacial and peak at ~20 g/cm** 3/kyr in the early transgression (16-14 ka BP). MARs then decline with further sea level rise as the Fitzroy River mouth retreats from the edge of the continental shelf after 13.5 ka BP. MARs remain low (4 g/cm**3/kyr) throughout the Holocene highstand. Data for the Holocene highstand indicate there is a reduction in siliciclastic influx to the Capricorn Channel with little quartz and feldspar below 350 mbsl. However, fine-grained fluvial sediments, presumably from the Fitzroy River, were still accumulating on the mid slope down to 2000 mbsl. The proportion of pelagic calcite in the core tops increases with water depth, while HMC decreases, and is present only in trace amounts in cores below 1500 mbsl. The difference in the percentage of HMC in the deeper cores between the glacial and Holocene may reflect differences in supply or deepening of the HMC lysocline during the glacial. Sediment accumulation rates also vary between cores in the Capricorn Channel and do not show the expected exponential decrease with depth. This may be due to intermediate or deep water currents reworking the sediments. It is also possible that present bathymetry data are too sparse to detect the potential role that submarine channels may play in the distribution and accumulation of sediments. Comparison of the Capricorn Channel MARs with those for other mixed carbonate/siliciclastic provinces from the northeast margin of Australia indicates that peak MARs in the early transgression in the Capricorn Channel precede those from the central GBR and south of Fraser Island. The difference in the timing of the carbonate and siliciclastic MAR peaks along the northeast margin is primarily related to differences in the physiography and climate of the provinces. The only common trend in the MARs from the northeast margin of Australia is the near synchronicity of the carbonate and siliciclastic MAR peaks in individual sediment cores, which supports a coeval sedimentation model.

Description: This study fills an important gap in our understanding of past changes in the Southern Subtropical Front (S-STF) in the southwest Pacific Ocean. Paleo-sea surface temperatures (SST) were estimated from planktic foraminiferal census counts from cores straddling the modern S-STF in the Solander Trough, south of New Zealand. The estimated SST were compared for 6 time slices; glacial period (25-21 ka), Last Glacial Maximum (LGM; 21-18 ka), early deglaciation (18-16 ka), late deglacial/early Holocene period (14-8 ka), mid-Holocene period (8-4 ka), and late Holocene period (4-0 ka). The position of the S-STF was determined by two methods: (1) the location of the 10°C isotherm and (2) the location of the highest SST gradients. These new results suggest that the S-STF was not continuous between east and west of New Zealand during the glacial period. Steep SST gradients indicate that a strong S-STF rapidly shifted south during the LGM and early deglaciation. During the late deglacial and Holocene periods the position of the S-STF differs between the two methods with reduced SST gradients, suggesting a more diffuse S-STF in the Solander Trough at this time. The glacial SST data suggest that the S-STF shifted north to the west of New Zealand, while to the east there was a stronger SST gradient across the front. This was possibly the result of an increased wind stress curl, which could have been caused by stronger, or more northerly Southern Hemisphere westerly winds (SHWW), or a merging of the SHWW split jet in this region.