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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 111 (1978), S. 1264-1274 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Bicyclofulvenes, IV: Syntheses of Methylenetricyclo[4.2.1.02,5]nonane- and -tricyclo[3.2.1.02,4]octane DerivativesThe synthesis of 9-methylenetricyclo[4.2.1.02,5]nonane (3), 8-methylenetricyclo[3.2.1.02,4]octane (2) and their derivatives as well as that of methylenehomocubane (37) and 9-methylenepentacyclo-[4.3.0.02,4.03,8.05,7]nonane (38) is described.
    Notes: Die Darstellung von 9-Methylentricyclo[4.2.1.02,5]nonan (3), 8-Methylentricyclo[3.2.1.02,4]octan (2) und ihrer Derivate, sowie von Methylenhomocuban (37) und 9-Methylenpentacyclo-[4.3.0.02,4.03,8.05,7]nonan (38) wird beschrieben.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 111 (1978), S. 1275-1283 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Bicyclofulvenes, V: Spectroscopic Studies of ω-Methylenetricyclo[4.2.1.02,5]nonane and -tricyclo[3.2.1.02,4]octane DerivativesInteraction of the semicyclic double bond in ω-methylene polycycles with suitably positioned endocyclic double bonds, endo-anellated cyclopropane or cyclobutane rings results in a polarisation of the semicyclic double bond. This is manifest from the 13C-NMR spectra, the ΔΔδ-values of which correlate with the interaction parameters Hij derived from the photoelectron spectra and the Δq-values calculated therefrom.
    Notes: Die Wechselwirkung der semicyclischen Doppelbindung in ω-Methylenpolycyclen mit geeignet angeordneten endocyclischen Doppelbindungen, endo-ständigen Drei- und Vierringen führt zu einer Polarisierung der semicyclischen Doppelbindung. Dies wird aus den 13C-NMR-Spektren deutlich, wobei die Maßzahl, ΔΔδ, mit den aus den Photoelektronenspektren entnommenen Wechselwirkungsparametern Hij und den daraus berechneten Δq-Werten korreliert.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Vertical or Nonvertical Stabilization in the 9-Pentacyclo[4.3.0.02,4.03,8.05,7]nonyl Cation? The 9-Methylenepentacyclononane Radical Cation1)A photoelectron spectroscopic investigation of the radical cation of methylenehomocuneane 8, together with the sterically rigid bicyclopropyls 5, 6, 7 and 9, reveals a vertical stabilization of comparable order (β ≈ —0.3 eV) in the radical cations of 5 and 8. The differences in solvolysis rate enhancements of 17/18 (a factor of 20) and 3/1 (a factor of 10(12) therefore cannot be accounted for by vertical stabilization effects but demonstrate impressively the homoaromatic stabilization in a distorted bridged transition state on the reaction coordinate between 3 and 4.
    Notes: Durch eine photoelektronenspektroskopische Untersuchung des Radikalkations des Methylenhomocuneans 8 in Verbindung mit den sterisch fixierten Bicyclopropylen 5, 6, 7 und 9 wird gezeigt, daß die vertikale Stabilisierung in den Radikalionen von 5 und 8 von vergleichbarer Größenordnung ist (β ≈ —0.3 eV). Der Unterschied in den Solvolysebeschleunigungen 17/18 (Faktor 20) und 3/1 (Faktor 10(12)) kann deshalb nicht auf vertikale Stabilisierungseffekte zurückgeführt werden, sondern demonstriert eindringlich die homoaromatische Stabilisierung in einem verzerrten, überbrückten Übergangszustand auf der Reaktionskoordinate zwischen 3 und 4.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 0075-4617
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Addition of Diphenylketene to Quadricyclane DerivativesDiphenylketene adds to quadricyclane and its 3-substituted derivatives to give the [1:1]-adducts 4, 12, 16 having cyclobutanone- and 5, 13, 17, 20 having oxetane structures.
    Notes: Diphenylketen addiert sich an Quadricyclan und 3-substituierte Quadricyclane unter Bildung der [1:1]-Addukte 4, 12, 16 mit Cyclobutanon- und 5, 13, 17, 20 mit Oxetan-Struktur.
    Type of Medium: Electronic Resource
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  • 5
    Publication Date: 2023-05-22
    Description: Objectives: It was intended to investigate the meso-scale and sub-meso-scale dynamics of the upper layers (upper 80 m) in the central Baltic Sea, using towed instruments and acoustic profilers, to better understand the physical conditions for cyanobacteria blooms. Under optimal weather conditions, we intended to carry out 10 one-day quasi-synoptic surveys by cruising in large meandering patterns (see fig. 1) covering areas of 15 X 15 nautical miles or 8 X 8 nautical miles, depending on the survey mode, see below. This cruise was the meso-scale component of the two-ship SUMMIX experiment together with RV Meteor (Physical and biochemical exchange-, mixing- and transformation processes in the central Baltic Sea during summer stratification and their controls on the cyanobacterial summer bloom) which was intended to be located at a fixed position nearby RV Elisabeth Mann Borgese in order to survey the water column in high vertical, spatial and parameter resolution, including biogeochemical experiments on board. In addition to the physical parameters, also vertical and horizontal zooplankton net tows as well as water samples taken by CTD bottles were planned.
    Type: Report , NonPeerReviewed
    Format: text
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  • 6
    Publication Date: 2023-01-26
    Description: Glider observations show a subsurface chlorophyll maximum (SCM) at the base of the seasonal pycnocline in the North Sea during stable summer conditions. A colocated peak in the dissipation rate of turbulent kinetic energy suggests the presence of active turbulence that potentially generates a nutrient flux to fuel the SCM. A one‐dimensional turbulence closure model is used to investigate the dynamics behind this local maximum in turbulent dissipation at the base of the pycnocline (PCB) as well as its associated nutrient fluxes. Based on a number of increasingly idealized forcing setups of the model, we are able to draw the following conclusions: (a) only turbulence generated inside the stratified PCB is able to entrain a tracer (e.g., nutrients) from the bottom mixed layer into the SCM region; (b) surface wind forcing only plays a secondary role during stable summer conditions; (c) interfacial shear from the tide accounts for the majority of turbulence production at the PCB; (d) in stable summer conditions, the strength of the turbulent diapycnal fluxes at the PCB is set by the strength of the anticyclonic component of the tidal currents.
    Description: Plain Language Summary: Many midlatitude shelf seas are vertically stratified in summer, where a warm surface layer sits on top of a cold, dense bottom layer. Both of these layers are unproductive environments for phytoplankton—the bottom layer is light limited, and the surface layer is nutrient‐limited. However, abundant phytoplankton is observed directly at the interface between surface and bottom layers. In order to sustain this phytoplankton, nutrient‐rich bottom water needs to be mixed with interface water. While both wind and tides are major causes for mixing in the coastal ocean, we find that the tides alone provide sufficient stirring at the right place to potentially act as an effective fuel pump for the phytoplankton. Interestingly, it is not the strength of the tides alone that counts, rather the sense of rotation of the tidal currents; rotation opposite to the Earth's spin causes more stirring than rotation along with it.
    Description: Key Points: Turbulence and chlorophyll both peak at the base of the pycnocline on a mid‐latitude shelf. Locally generated turbulence at the pycnocline base is a fuel pump for the subsurface chlorophyll maximum. Amplitude and polarity of the M2 tide govern the local generation of turbulence at the pycnocline base.
    Description: Helmholtz Association
    Description: https://doi.org/10.5281/zenodo.3525787
    Description: https://oceancolor.gsfc.nasa.gov/l3/
    Description: https://www.cen.uni-hamburg.de/icdc/data/ocean/nsbc.html
    Keywords: ddc:551.46 ; shelf seas ; storms ; North Sea ; turbulence ; straification ; marginal stability ; subsurface chlorophyll maximum ; fuel pump ; modeling
    Language: English
    Type: doc-type:article
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