Description: The data published here were gathered in the framework of a multi-proxy-based study of paleotemperature (both marine and terrestrial), -salinity, and -ecosystem changes from the Little Belt (Site M0059). They cover the past ~8,000 years and contain only material from the uppermost subunits 1a and 1b encountered at Site M0059 (see e.g. Andrén et al. 2015). Four environmental zones (EZ1: oldest, freshwater conditions; EZ2 to EZ4 reflecting following salinity and ecosystem changes in the region) were identified in Kotthoff et al. (2017). The age model and the sedimentology are discussed in Kotthoff et al. (2017). The datasets comprise data for salinity proxies (diatoms, aquatic palynomorphs, diol index) and for water temperature proxies (foraminiferal Mg/Ca-ratios, long chain diol index and TEXL86) as well as temperature reconstruction based on pollen grains. It is discussed in Kotthoff et al. (2017) that applying and interpreting proxies in coastal environments and marginal seas needs particular caution. For example, foraminiferal Mg/Ca-ratios may have been influenced by contamination by authigenic coatings in the deeper intervals of the record. Lipid paleothermometers were probably influenced by significant changes in depositional settings in the Little Belt. References: Andrén, T., Jørgensen, B.B., Cotterill, C., and the Expedition 347 Scientists: Baltic Sea Paleoenvironment. Proceedings IODP, 347. College Station, TX (Integrated Ocean Drilling Program), https://doi.org/10.2204/iodp.proc.347.101.2015, 2015. Kotthoff, U., Groeneveld, J., Ash, J. L., Fanget, A.-S., Krupinski, N. Q., Peyron, O., Stepanova, A., Warnock, J., Van Helmond, N. A. G. M., Passey, B. H., Clausen, O. R., Bennike, O., Andrén, E., Granoszewski, W., Andrén, T., Filipsson, H. L., Seidenkrantz, M.-S., Slomp, C. P., and Bauersachs, T.: Reconstructing Holocene temperature and salinity variations in the western Baltic Sea region: a multi-proxy comparison from the Little Belt (IODP Expedition 347, Site M0059), Biogeosciences, 14, 5607–5632, https://doi.org/10.5194/bg-14-5607-2017, 2017.

Description: Oscillations in ice sheet extent during early and middle Miocene are intermittently preserved in the sedimentary record from the Antarctic continental shelf, with widespread erosion occurring during major ice sheet advances, and open marine deposition during times of ice sheet retreat. Data from seismic reflection surveys and drill sites from Deep Sea Drilling Project Leg 28 and International Ocean Discovery Program Expedition 374, located across the present-day middle continental shelf of the central Ross Sea (Antarctica), indicate the presence of expanded early to middle Miocene sedimentary sections. These include the Miocene climate optimum (MCO ca. 17−14.6 Ma) and the middle Miocene climate transition (MMCT ca. 14.6−13.9 Ma). Here, we correlate drill core records, wireline logs and reflection seismic data to elucidate the depositional architecture of the continental shelf and reconstruct the evolution and variability of dynamic ice sheets in the Ross Sea during the Miocene. Drill-site data are used to constrain seismic isopach maps that document the evolution of different ice sheets and ice caps which influenced sedimentary processes in the Ross Sea through the early to middle Miocene. In the early Miocene, periods of localized advance of the ice margin are revealed by the formation of thick sediment wedges prograding into the basins. At this time, morainal bank complexes are distinguished along the basin margins suggesting sediment supply derived from marine-terminating glaciers. During the MCO, biosiliceous-bearing sediments are regionally mapped within the depocenters of the major sedimentary basin across the Ross Sea, indicative of widespread open marine deposition with reduced glacimarine influence. At the MMCT, a distinct erosive surface is interpreted as representing large-scale marine-based ice sheet advance over most of the Ross Sea paleo-continental shelf. The regional mapping of the seismic stratigraphic architecture and its correlation to drilling data indicate a regional transition through the Miocene from growth of ice caps and inland ice sheets with marine-terminating margins, to widespread marine-based ice sheets extending across the outer continental shelf in the Ross Sea.

Description: The repeated proximity of West Antarctic Ice Sheet (WAIS) ice to the eastern Ross Sea continental shelf break during past ice age cycles has been inferred to directly influence sedimentary processes occurring on the continental slope, such as turbidity current and debris flow activity; thus, the records of these processes can be used to study the past history of the WAIS. Ross Sea slope sediments may additionally provide an archive on the history and interplay of density-driven or geostrophic oceanic bottom currents with ice-sheet-driven depositional mechanisms. We investigate the upper 121 m of Hole U1525A, collected during International Ocean Discovery Program (IODP) Expedition 374 in 2018. Hole U1525A is located on the southwestern external levee of the Hillary Canyon (Ross Sea, Antarctica) and the depositional lobe of the nearby trough-mouth fan. Using core descriptions, grain size analysis, and physical properties datasets, we develop a lithofacies scheme that allows construction of a detailed depositional model and environmental history of past ice sheet-ocean interactions at the eastern Ross Sea continental shelf break/slope since ~2.4 Ma. The earliest Pleistocene interval (~2.4- ~ 1.4 Ma) represents a hemipelagic environment dominated by ice-rafting and reworking/deposition by relatively persistent bottom current activity. Finely interlaminated silty muds with ice-rafted debris (IRD) layers are interpreted as contourites. Between ~1.4 and ~0.8 Ma, geostrophic bottom current activity was weaker and turbiditic processes more common, likely related to the increased proximity of grounded ice at the shelf edge. Silty, normally-graded laminations with sharp bases may be the result of flow-stripped turbidity currents overbanking the canyon levee during periods when ice was grounded at or proximal to the shelf edge. A sandy, IRD- and foraminifera-bearing interval dated to ~1.18 Ma potentially reflects warmer oceanographic conditions and a period of stronger Antarctic Slope Current flow. This may have enhanced upwelling of warm Circumpolar Deep Water onto the shelf, leading to large-scale glacial retreat at that time. The thickest interval of turbidite interlamination was deposited after ~1 Ma, following the onset of the Mid-Pleistocene Transition, interpreted as a time when most ice sheets grew and glacial periods were longer and more extreme. Sedimentation after ~0.8 Ma was dominated by glacigenic debris flow deposition, as the trough mouth fan that dominates the eastern Ross Sea continental slope prograded and expanded over the site. These findings will help to improve estimations of WAIS ice extent in future Ross Sea shelf-based modelling studies, and provide a basis for more detailed analysis of the inception and growth of the WAIS under distinct oceanographic conditions.

Description: In this paper we analyze how oceanic circulation affects sediment deposition along a sector of the Ross Sea continental margin, between the Iselin Bank and the Hillary Canyon, and how these processes evolved since the Late Miocene. The Hillary Canyon is one of the few places around the Antarctic continental margin where the dense waters produced onto the continental shelf, mainly through brine rejection related to sea ice production, flow down the continental slope and reach the deep oceanic bottom layer. At the same time the Hillary Canyon represents a pathway for relatively warm waters, normally flowing along the continental slope within the Antarctic Slope Current, to reach the continental shelf. The intrusion of warm waters onto the continental shelf produces basal melting of the ice shelves, reduces their buttressing effect and triggers instabilities of the ice sheet that represent one of the main uncertainties in future sea level projections. For this study we use seismic, morpho-bathymetric and oceanographic data acquired in 2017 by the R/V OGS Explora. Seismic profiles and multibeam bathymetry are interpreted together with age models from two drilling sites (U1523 and U1524) of the International Ocean Discovery Program (IODP) Expedition 374. Oceanographic data, together with a regional oceanographic model, are used to support our reconstruction by showing the present-day oceanographic influence on sediment deposition. Regional correlation of the main seismic unconformities allows us to identify eight seismic sequences. Seismic profiles and multibeam bathymetry show a strong influence of bottom current activity on sediment deposition since the Early Miocene and a reduction in their intensity during the mid-Pliocene Warm Period. Oceanographic data and modelling provide evidence that the bottom currents are related to the dense waters produced on the Ross Sea continental shelf and flowing out through the Hillary Canyon. The presence of extensive mass transport deposits and detachment scarps indicate that also mass wasting participates in sediment transport. Through this integrated approach we regard the area between the Iselin Bank and the Hillary Canyon as a Contourite Depositional System (ODYSSEA CDS) that offers a record of oceanographic and sedimentary conditions in a unique setting. The hypotheses presented in this work are intended to serve as a framework for future reconstructions based on detailed integration of lithological, paleontological, geochemical and petrophysical data.

Description: The West Antarctic Ice Sheet (WAIS) presently holds enough ice to raise global sea level by 4.3 m if completely melted. The unknown response of the WAIS to future warming remains a significant challenge for numerical models in quantifying predictions of future sea level rise. Sea level rise is one of the clearest planet-wide signals of human-induced climate change. The Sensitivity of the West Antarctic Ice Sheet to a Warming of 2 ∘C (SWAIS 2C) Project aims to understand past and current drivers and thresholds of WAIS dynamics to improve projections of the rate and size of ice sheet changes under a range of elevated greenhouse gas levels in the atmosphere as well as the associated average global temperature scenarios to and beyond the +2 ∘C target of the Paris Climate Agreement. Despite efforts through previous land and ship-based drilling on and along the Antarctic margin, unequivocal evidence of major WAIS retreat or collapse and its causes has remained elusive. To evaluate and plan for the interdisciplinary scientific opportunities and engineering challenges that an International Continental Drilling Program (ICDP) project along the Siple coast near the grounding zone of the WAIS could offer (Fig. 1), researchers, engineers, and logistics providers representing 10 countries held a virtual workshop in October 2020. This international partnership comprised of geologists, glaciologists, oceanographers, geophysicists, microbiologists, climate and ice sheet modelers, and engineers outlined specific research objectives and logistical challenges associated with the recovery of Neogene and Quaternary geological records from the West Antarctic interior adjacent to the Kamb Ice Stream and at Crary Ice Rise. New geophysical surveys at these locations have identified drilling targets in which new drilling technologies will allow for the recovery of up to 200 m of sediments beneath the ice sheet. Sub-ice-shelf records have so far proven difficult to obtain but are critical to better constrain marine ice sheet sensitivity to past and future increases in global mean surface temperature up to 2 ∘C above pre-industrial levels. Thus, the scientific and technological advances developed through this program will enable us to test whether WAIS collapsed during past intervals of warmth and determine its sensitivity to a +2 ∘C global warming threshold (UNFCCC, 2015).

Description: Early to Middle Miocene sea-level oscillations of approximately 40–60 m estimated from far-field records1–3 are interpreted to reflect the loss of virtually all East Antarctic ice during peak warmth2. This contrasts with ice-sheet model experiments suggesting most terrestrial ice in East Antarctica was retained even during the warmest intervals of the Middle Miocene4,5. Data and model outputs can be reconciled if a large West Antarctic Ice Sheet (WAIS) existed and expanded across most of the outer continental shelf during the Early Miocene, accounting for maximum ice-sheet volumes. Here we provide the earliest geological evidence proving large WAIS expansions occurred during the Early Miocene (~17.72–17.40 Ma). Geochemical and petrographic data show glacimarine sediments recovered at International Ocean Discovery Program (IODP) Site U1521 in the central Ross Sea derive from West Antarctica, requiring the presence of a WAIS covering most of the Ross Sea continental shelf. Seismic, lithological and palynological data reveal the intermittent proximity of grounded ice to Site U1521. The erosion rate calculated from this sediment package greatly exceeds the long-term mean, implying rapid erosion of West Antarctica. This interval therefore captures a key step in the genesis of a marine-based WAIS and a tipping point in Antarctic ice-sheet evolution.

Description: Stable isotope compositions of methane (δ13C and δD) and of short-chain alkanes are commonly used to trace the origin and fate of carbon in the continental crust. In continental sedimentary systems, methane is typically produced through thermogenic cracking of organic matter and/or through microbial methanogenesis. However, secondary processes such as mixing, migration or biodegradation can alter the original isotopic and composition of the gas, making the identification and the quantification of primary sources challenging. The recently resolved methane 'clumped' isotopologues Δ13CH3D and Δ12CH2D2 are unique indicators of whether methane is at thermodynamic isotopic equilibrium or not, thereby providing insights into formation temperatures and/or into kinetic processes controlling methane generation processes, including microbial methanogenesis. In this study, we report the first systematic use of methane Δ13CH3D and Δ12CH2D2 in the context of continental sedimentary basins. We investigated sedimentary formations from the Southwest Ontario and Michigan Basins, where the presence of both microbial and thermogenic methane was previously proposed. Methane from the Silurian strata coexist with highly saline brines, and clumped isotopologues exhibit large offsets from thermodynamic equilibrium, with Δ12CH2D2 values as low as -23‰. Together with conventional δ13C and δD values, the variability in Δ13CH3D and Δ12CH2D2 to first order reflects a mixing relationship between near-equilibrated thermogenic methane similar to gases from deeper Cambrian and Middle Ordovician units, and a source characterized by a substantial departure from equilibrium that could be associated with microbial methanogenesis. In contrast, methane from the Devonian-age Antrim Shale, associated with less saline porewaters, reveals Δ13CH3D and Δ12CH2D2 values that are approaching low temperature thermodynamic equilibrium. While microbial methanogenesis remains an important contributor to the methane budget in the Antrim Shale, it is suggested that Anaerobic Oxidation of Methane (AOM) could contribute to reprocessing methane isotopologues, yielding Δ13CH3D and Δ12CH2D2 signatures approaching thermodynamic equilibrium.