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  • 1
    Online Resource
    Online Resource
    Springer Science and Business Media LLC ; 2023
    In:  Scientific Reports Vol. 13, No. 1 ( 2023-05-08)
    In: Scientific Reports, Springer Science and Business Media LLC, Vol. 13, No. 1 ( 2023-05-08)
    Type of Medium: Online Resource
    ISSN: 2045-2322
    Language: English
    Publisher: Springer Science and Business Media LLC
    Publication Date: 2023
    detail.hit.zdb_id: 2615211-3
    Location Call Number Limitation Availability
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  • 2
    In: Mineralium Deposita, Springer Science and Business Media LLC, Vol. 57, No. 5 ( 2022-06), p. 725-741
    Abstract: Stibnite was mined until the end of the twentieth century in the Schlaining ore district, Austria, near the easternmost border of the Eastern Alps where windows of Penninic ophiolites and metasediments are exposed below Austroalpine tectonic units. In Early Miocene, structurally controlled small vein and metasomatic stibnite-quartz deposits were formed in Penninic Mesozoic calcareous marbles and calcite schists. Fluid inclusion studies identified two fluids involved in the mineralization: (i) a low-salinity, low-CO 2 metamorphic fluid that precipitated quartz at approximately 240 °C and (ii) a stibnite-forming ore fluid that had a meteoric origin. There is no evidence of boiling or that the fluids mixed during mineralization. The ore components Sb and H 2 S were leached by fluid/rock interaction from buried rock units. Stibnite mineralization occurred by cooling the ore fluid to below 300 °C, at less than 2000 m depth. Quartz precipitated at slightly lower temperatures, approximately contemporaneous with stibnite. Fluid migration and ore deposition are probably related to high heat flow during the exhumation of the Rechnitz Window in response to Neogene extension and/or shallow Early Miocene andesitic magmatism. The study emphasizes that data obtained from the analyses of gangue minerals alone cannot routinely be used to infer the origin and depositional conditions of the associated ore minerals.
    Type of Medium: Online Resource
    ISSN: 0026-4598 , 1432-1866
    RVK:
    Language: English
    Publisher: Springer Science and Business Media LLC
    Publication Date: 2022
    detail.hit.zdb_id: 1462046-7
    detail.hit.zdb_id: 1679-2
    SSG: 13
    Location Call Number Limitation Availability
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  • 3
    Online Resource
    Online Resource
    Springer Science and Business Media LLC ; 2023
    In:  Scientific Reports Vol. 13, No. 1 ( 2023-03-07)
    In: Scientific Reports, Springer Science and Business Media LLC, Vol. 13, No. 1 ( 2023-03-07)
    Abstract: Ore precipitation in porphyry copper systems is generally characterized by metal zoning (Cu–Mo to Zn–Pb–Ag), which is suggested to be variably related to solubility decreases during fluid cooling, fluid-rock interactions, partitioning during fluid phase separation and mixing with external fluids. Here, we present new advances of a numerical process model by considering published constraints on the temperature- and salinity-dependent solubility of Cu, Pb and Zn in the ore fluid. We quantitatively investigate the roles of vapor-brine separation, halite saturation, initial metal contents, fluid mixing and remobilization as first-order controls of the physical hydrology on ore formation. The results show that the magmatic vapor and brine phases ascend with different residence times but as miscible fluid mixtures, with salinity increases generating metal-undersaturated bulk fluids. The release rates of magmatic fluids affect the location of the thermohaline fronts, leading to contrasting mechanisms for ore precipitation: higher rates result in halite saturation without significant metal zoning, lower rates produce zoned ore shells due to mixing with meteoric water. Varying metal contents can affect the order of the final metal precipitation sequence. Redissolution of precipitated metals results in zoned ore shell patterns in more peripheral locations and also decouples halite saturation from ore precipitation.
    Type of Medium: Online Resource
    ISSN: 2045-2322
    Language: English
    Publisher: Springer Science and Business Media LLC
    Publication Date: 2023
    detail.hit.zdb_id: 2615211-3
    Location Call Number Limitation Availability
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  • 4
    In: Mineralium Deposita, Springer Science and Business Media LLC, Vol. 57, No. 5 ( 2022-06), p. 801-825
    Abstract: Deep hydrothermal Mo, W, and base metal mineralization at the Sweet Home mine (Detroit City portal) formed in response to magmatic activity during the Oligocene. Microthermometric data of fluid inclusions trapped in greisen quartz and fluorite suggest that the early-stage mineralization at the Sweet Home mine precipitated from low- to medium-salinity (1.5–11.5 wt% equiv. NaCl), CO 2 -bearing fluids at temperatures between 360 and 415 °C and at depths of at least 3.5 km. Stable isotope and noble gas isotope data indicate that greisen formation and base metal mineralization at the Sweet Home mine was related to fluids of different origins. Early magmatic fluids were the principal source for mantle-derived volatiles (CO 2 , H 2 S/SO 2 , noble gases), which subsequently mixed with significant amounts of heated meteoric water. Mixing of magmatic fluids with meteoric water is constrained by δ 2 H w –δ 18 O w relationships of fluid inclusions. The deep hydrothermal mineralization at the Sweet Home mine shows features similar to deep hydrothermal vein mineralization at Climax-type Mo deposits or on their periphery. This suggests that fluid migration and the deposition of ore and gangue minerals in the Sweet Home mine was triggered by a deep-seated magmatic intrusion. The findings of this study are in good agreement with the results of previous fluid inclusion studies of the mineralization of the Sweet Home mine and from Climax-type Mo porphyry deposits in the Colorado Mineral Belt.
    Type of Medium: Online Resource
    ISSN: 0026-4598 , 1432-1866
    RVK:
    Language: English
    Publisher: Springer Science and Business Media LLC
    Publication Date: 2022
    detail.hit.zdb_id: 1462046-7
    detail.hit.zdb_id: 1679-2
    SSG: 13
    Location Call Number Limitation Availability
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