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  • 1
    Online Resource
    Online Resource
    EDP Sciences ; 2020
    In:  E3S Web of Conferences Vol. 146 ( 2020), p. 00001-
    In: E3S Web of Conferences, EDP Sciences, Vol. 146 ( 2020), p. 00001-
    Type of Medium: Online Resource
    ISSN: 2267-1242
    Language: English
    Publisher: EDP Sciences
    Publication Date: 2020
    detail.hit.zdb_id: 2755680-3
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  • 2
    Online Resource
    Online Resource
    EDP Sciences ; 2020
    In:  E3S Web of Conferences Vol. 146 ( 2020), p. 05004-
    In: E3S Web of Conferences, EDP Sciences, Vol. 146 ( 2020), p. 05004-
    Abstract: Adsorption isotherms of light hydrocarbons on reservoir rocks are key data used to quantify the total gas content in reservoirs and isotherms are now being used to improve our understanding of the processes affecting subsurface gas flow associated with gas injection from Enhanced Oil Recovery techniques. This project combined elements of the traditional pressure-volume gas adsorption isotherm technique and an NMR-based adsorption isotherm approach to determine the adsorption isotherms of light hydrocarbons on to tight rocks from oil and gas reservoirs. The new approach allows isotherms to be derived from NMR data. First, a T 2 distribution of the gas is determined over a range of gas pressures. Next, the volume of pore gas is estimated using the pore volume of the rock and the Van der Waals gas equation. The adsorbed gas content is then calculated by subtracting pore gas content from the total gas content. This is repeated for a range of gas pressures to determine the adsorption isotherm. This project used the NMR method described above and measured the gas pressure decay in the NMR cell. This combined approach includes the advantages of the NMR method but it also produces a pressure-time curve that can be used to identify when equilibrium is attained in low permeability rocks and can be used to compare adsorption kinetics of different gases. The advantages of our approach are that 1) the samples remain intact and the measurements provide information on the pore size distribution; 2) analyses can be carried out at reservoir pressures; 3) isotherms can be measured for any gas containing hydrogen atoms; and 4) the results can be used to examine the processes controlling gas flow through the rock. Future work to develop this technique will improve our quantification of the amount of pore gas in the cell, which will improve our partitioning between adsorbed gas and pore gas as well as allow for an improved analysis of the pressure response of the sample after degassing.
    Type of Medium: Online Resource
    ISSN: 2267-1242
    Language: English
    Publisher: EDP Sciences
    Publication Date: 2020
    detail.hit.zdb_id: 2755680-3
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  • 3
    Online Resource
    Online Resource
    EDP Sciences ; 2020
    In:  E3S Web of Conferences Vol. 146 ( 2020), p. 04001-
    In: E3S Web of Conferences, EDP Sciences, Vol. 146 ( 2020), p. 04001-
    Abstract: A novel method for permeability prediction is presented using multivariant structural regression. A machine learning based model is trained using a large number (2,190, extrapolated to 219,000) of synthetic datasets constructed using a variety of object-based techniques. Permeability, calculated on each of these networks using traditional digital rock approaches, was used as a target function for a multivariant description of the pore network structure, created from the statistics of a discrete description of grains, pores and throats, generated through image analysis. A regression model was created using an Extra-Trees method with an error of 〈 4% on the target set. This model was then validated using a composite series of data created both from proprietary datasets of carbonate and sandstone samples and open source data available from the Digital Rocks Portal ( www.digitalrocksporta.org ) with a Root Mean Square Fractional Error of 〈 25%. Such an approach has wide applicability to problems of heterogeneity and scale in pore scale analysis of porous media, particularly as it has the potential of being applicable on 2D as well as 3D data.
    Type of Medium: Online Resource
    ISSN: 2267-1242
    Language: English
    Publisher: EDP Sciences
    Publication Date: 2020
    detail.hit.zdb_id: 2755680-3
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  • 4
    In: E3S Web of Conferences, EDP Sciences, Vol. 146 ( 2020), p. 05002-
    Abstract: A recent proposed carbon dioxide (CO 2 ) storage scheme suggests solid CO 2 hydrate formation at the base of the hydrate stability zone to facilitate safe, long-term storage of anthropogenic CO 2 . These high-density hydrate structures consist of individual CO 2 molecules confined in cages of hydrogen-bonded water molecules. Solid-state storage of CO 2 in shallow aquifers can improve the storage capacity greatly compared to supercritical CO 2 stored at greater depths. Moreover, impermeable hydrate layers directly above a liquid CO 2 plume will significantly retain unwanted migration of CO 2 toward the seabed. Thus, a structural trap accompanied by hydrate layers in a zone of favorable kinetics are likely to mitigate the overall risk of CO 2 leakage from the storage site. Geophysical monitoring of the CO 2 storage site includes electrical resistivity measurements that relies on empirical data to obtain saturation values. We have estimated the saturation exponent in Archie’s equation, n ≈ 2.1 (harmonic mean) for CO 2 and brine saturated pore network, and for hydrate-bearing seal (SH 〈 0.4), during the process of storing liquid CO 2 in Bentheimer sandstone core samples. Our findings support efficient trapping of CO 2 by sedimentary hydrate formation and show a robust agreement between saturation values derived from PVT data and from modifying Archie’s equation.
    Type of Medium: Online Resource
    ISSN: 2267-1242
    Language: English
    Publisher: EDP Sciences
    Publication Date: 2020
    detail.hit.zdb_id: 2755680-3
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  • 5
    In: E3S Web of Conferences, EDP Sciences, Vol. 146 ( 2020), p. 01003-
    Abstract: To make efficient use of image-based rock physics workflow, it is necessary to optimize different criteria, among which: quantity, representativeness, size and resolution. Advances in artificial intelligence give insights of databases potential. Deep learning methods not only enable to classify rock images, but could also help to estimate their petrophysical properties. In this study we prepare a set of thousands high-resolution 3D images captured in a set of four reservoir rock samples as a base for learning and training. The Voxilon software computes numerical petrophysical analysis. We identify different descriptors directly from 3D images used as inputs. We use convolutional neural network modelling with supervised training using TensorFlow framework. Using approximately fifteen thousand 2D images to drive the classification network, the test on thousand unseen images shows any error of rock type misclassification. The porosity trend provides good fit between digital benchmark datasets and machine learning tests. In a few minutes, database screening classifies carbonates and sandstones images and associates the porosity values and distribution. This work aims at conveying the potential of deep learning method in reservoir characterization to petroleum research, to illustrate how a smart image-based rock physics database at industrial scale can swiftly give access to rock properties.
    Type of Medium: Online Resource
    ISSN: 2267-1242
    Language: English
    Publisher: EDP Sciences
    Publication Date: 2020
    detail.hit.zdb_id: 2755680-3
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  • 6
    In: E3S Web of Conferences, EDP Sciences, Vol. 146 ( 2020), p. 03002-
    Abstract: The phenomenology of steady-state two-phase flow in porous media is recorded in SCAL relative permeability diagrams. Conventionally, relative permeabilities are considered to be functions of saturation. Yet, this has been put into challenge by theoretical, numerical and laboratory studies that have revealed a significant dependency on the flow rates. These studies suggest that relative permeability models should include the functional dependence on flow intensities. Just recently a general form of dependence has been inferred, based on extensive simulations with the DeProF model for steady-state two-phase flows in pore networks. The simulations revealed a systematic dependence of the relative permeabilities on the local flow rate intensities that can be described analytically by a universal scaling functional form of the actual independent variables of the process, namely, the capillary number, Ca , and the flow rate ratio, r . In this work, we present the preliminary results of a systematic laboratory study using a high throughput core-flood experimentation setup, whereby SCAL measurements have been taken on a sandstone core across different flow conditions -spanning 6 orders of magnitude on Ca and r . The scope is to provide a preliminary proof-of-concept, to assess the applicability of the model and validate its specificity. The proposed scaling opens new possibilities in improving SCAL protocols and other important applications, e.g. field scale simulators.
    Type of Medium: Online Resource
    ISSN: 2267-1242
    Language: English
    Publisher: EDP Sciences
    Publication Date: 2020
    detail.hit.zdb_id: 2755680-3
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  • 7
    Online Resource
    Online Resource
    EDP Sciences ; 2020
    In:  E3S Web of Conferences Vol. 146 ( 2020), p. 03007-
    In: E3S Web of Conferences, EDP Sciences, Vol. 146 ( 2020), p. 03007-
    Abstract: Many modelling and theoretical studies have shown that diffusion can be a significant transport mechanism in low-permeability porous media. Understanding the process allows engineers to better predict reservoir performance during both primary production and enhanced recovery in unconventional reservoirs. Direct measurement of effective diffusion in tight rocks is difficult, due to small pore volumes and the lack of techniques to actually monitor the process. Conventional diffusion measurements generally require fluid sampling, which induces a pressure transient which changes the mass transfer mechanism. Previously, we introduced a novel technique to measure tortuosity in nano-porous media by simultaneously monitoring methane versus nitrogen concentrations at high pressure using transmission Infrared Spectroscopy (IR). To complete the estimation of effective diffusion, bulk fluid diffusion coefficient also needs to be measured. In this study, we demonstrate the usage of Nuclear Magnetic Resonance (NMR) 1-D imaging to examine the dynamic change of Hydrogen Index (HI) across the interface between two bulk fluids. The experiment was conducted between a crude oil sample and methane; fluid samples were pressurized within an NMR transparent ZrO 2 pressure cell which operates at pressures up to 10,000 psi. The Hydrogen Index (HI) profile was continuously measured and recorded for 7 days. The results provided oil the swelling factor and the concentration profile as a function of both time and distance. These data then were fitted with Maxwell-Stefan equation to precisely back calculate the diffusion coefficient between oil and gas samples at high pressure. Accurate estimation of tortuosity and fluid diffusion is critical for the gas injection strategy in a shale formation. Greater tortuosity and smaller fluid diffusion rate lead to longer injection and production times for desirable economic recovery.
    Type of Medium: Online Resource
    ISSN: 2267-1242
    Language: English
    Publisher: EDP Sciences
    Publication Date: 2020
    detail.hit.zdb_id: 2755680-3
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  • 8
    Online Resource
    Online Resource
    EDP Sciences ; 2020
    In:  E3S Web of Conferences Vol. 146 ( 2020), p. 03008-
    In: E3S Web of Conferences, EDP Sciences, Vol. 146 ( 2020), p. 03008-
    Abstract: The estimation of total hydrocarbons (HCs) in place is one of the most important economic challenges in unconventional resource plays. Nuclear magnetic resonance (NMR) has proven to be a valuable tool in directly quantifying both hydrocarbons and brines in the laboratory and the field. Some major applications of NMR interpretation include pore body size distributions, wettability, fluid types, and fluid properties. However, for tight formations, the effects of the factors on NMR relaxation data are intertwined. One purpose of this study is to review the interpretation of NMR response of HCs in a tight rock matrix through illustrated examples. When comparing NMR data between downhole wireline and laboratory measurement, three important elements need to be considered: 1) temperature differences, 2) system response differences, and 3) pressure (mainly due to the lost gasses.) The effect of temperature on HCs would be presented with experimental results for bulk fluids. Whereas, the effect of pressure is investigated by injecting gas back into rock matrix saturated with original fluids. The experiments were performed within an NMR transparent Daedalus ZrO 2 pressure cell, which operates at pressures up to 10,000 psi. The results show that, at ambient temperature and pressure, NMR responds to a fraction of HCs, which is volatile enough to be observed as an NMR relaxation sequence. The invisible fraction of HCs to NMR sequence at ambient condition can be up to 20% of the total extractable HCs. Molecular relaxation is impacted by fluid viscosity, pore size, and surface affinity. In other words, the fluid with higher viscosity (either due to temperature or gas loss), presenting in smaller pore, or highly affected by the pore surface, will relax faster, and would be partially invisible to NMR, especially in the field. This is critical to the interpretation of NMR response for liquid rich source rocks, in which all of the above molecular relaxing restrictions can be found. Thus, engineers can underestimate movable HCs by using routine core analysis data.
    Type of Medium: Online Resource
    ISSN: 2267-1242
    Language: English
    Publisher: EDP Sciences
    Publication Date: 2020
    detail.hit.zdb_id: 2755680-3
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  • 9
    Online Resource
    Online Resource
    EDP Sciences ; 2020
    In:  E3S Web of Conferences Vol. 146 ( 2020), p. 03005-
    In: E3S Web of Conferences, EDP Sciences, Vol. 146 ( 2020), p. 03005-
    Abstract: We present a newly developed high-pressure nuclear magnetic resonance (NMR) flow cell, which allows for the simultaneous determination of water saturation, effective gas permeability and NMR relaxation time distribution in two-phase fluid flow experiments. We introduce both the experimental setup and the experimental procedure on a tight Rotliegend sandstone sample. The initially fully water saturated sample is systematically drained by a stepwise increase of gas (Nitrogen) inlet pressure and the drainage process is continuously monitored by low field NMR relaxation measurements. After correction of the data for temperature fluctuations, the monitored changes in water saturation proved very accurate. The experimental procedure provides quantitative information about the total water saturation as well as about its distribution within the pore space at defined differential pressure conditions. Furthermore, the relationship between water saturation and relative (or effective) apparent permeability is directly determined.
    Type of Medium: Online Resource
    ISSN: 2267-1242
    Language: English
    Publisher: EDP Sciences
    Publication Date: 2020
    detail.hit.zdb_id: 2755680-3
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  • 10
    In: E3S Web of Conferences, EDP Sciences, Vol. 146 ( 2020), p. 03003-
    Abstract: Standard test methods for measuring imbibition gas-brine relative permeability on reservoir core samples often lead to non-uniform brine saturation. During co-current flow, the brine tends to bank up at the sample inlet and redistributes slowly, even with fractional flow of gas to brine of 400:1 or more. The first reliable Rel Perm point is often only attained after a brine saturation of around S w =40% is achieved, leaving a data gap between Swirr and this point. The consequent poor definition of the shape of the Rel Perm function can lead to uncertainty in the performance of gas reservoirs undergoing depletion drive with an encroaching aquifer or subjected to a water flood. We have developed new procedures to pre-condition brine saturation outside of the test rig and progress it in small increments to fill in the data gap at low S w , before continuing with a co-current flood to the gas permeability end-point. The method was applied to series of sandstone samples from gas reservoirs from the NW Shelf of Australia, and a Berea standard. We found that the complete imbibition relative permeability curve is typically ‘S’ shaped or has a rolling over, convex-up shape that is markedly different from the concave-up, Corey Rel Perm curve usually fitted to SCAL test data. This finding may have an economic upside if the reservoir produces gas at a high rate for longer than was originally predicted based on the old Rel Perm curves.
    Type of Medium: Online Resource
    ISSN: 2267-1242
    Language: English
    Publisher: EDP Sciences
    Publication Date: 2020
    detail.hit.zdb_id: 2755680-3
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