In:
Zeitschrift für Naturforschung B, Walter de Gruyter GmbH, Vol. 48, No. 10 ( 1993-10-1), p. 1365-1371
Abstract:
A simple method is described which allows the growth of large transparent single crystals of tris[bis(trimethylsilyl)amido]lanthanide(III) complexes (lanthanide = Pr, Nd, Sm, Eu, Er, Tm, Yb). We have used these single crystals as starting material for a number of chemical reactions and detected no contamination with THF containing by-products. The superior quality of the crystals grown is demonstrated by optical polarization experiments. From the spectra a large negative crystal field parameter B 2 0 could be concluded
Type of Medium:
Online Resource
ISSN:
1865-7117
,
0932-0776
DOI:
10.1515/znb-1993-1010
Language:
English
Publisher:
Walter de Gruyter GmbH
Publication Date:
1993
detail.hit.zdb_id:
2078109-X
detail.hit.zdb_id:
124635-5
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