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  • 1
    Online Resource
    Online Resource
    Wiley ; 2014
    In:  Rapid Communications in Mass Spectrometry Vol. 28, No. 4 ( 2014-02-28), p. 332-338
    In: Rapid Communications in Mass Spectrometry, Wiley, Vol. 28, No. 4 ( 2014-02-28), p. 332-338
    Abstract: Glycerol serves as the principal backbone moiety bound to various acyl/alkyl chains for membrane lipids of Eukarya , Bacteria , and Archaea . In this study, we report a suite of unusual tetraether lipids in which one of the two conventional glycerol backbones is substituted by butanetriol or pentanetriol. METHODS Identification of these lipids was achieved via diagnostic fragments and their expected acetylation products using liquid chromatography/mass spectrometry (LC/MS), and their diagnostic ether cleavage products using gas chromatography/mass spectrometry (GC/MS). RESULTS We observed structural variations in the polyol backbones and alkyl chains and term these core lipid derivatives: isoprenoidal butanetriol dialkyl glycerol tetraethers (iso‐BDGTs), isoprenoidal pentanetriol dialkyl glycerol tetraethers (iso‐PDGTs), and hybrid isoprenoidal/branched BDGTs and PDGTs (ib‐BDGTs, ib‐PDGTs). Of these, iso‐BDGTs were the most abundant with a methylation at either the sn ‐1 or sn ‐3 position of glycerol and were also found as part of intact polar lipids, adjoined to mono‐ or diglycosidic headgroups. Iso‐BDGTs and iso‐PDGTs are likely produced by Archaea , as indicated by the presence of the characteristic biphytanyl moieties. CONCLUSIONS Butanetriol‐ and pentanetriol‐based tetraether lipids occur in modern estuarine and deeply buried subseafloor sediments, suggesting the presence of alternative backbones in archaeal lipids. Copyright © 2013 John Wiley & Sons, Ltd.
    Type of Medium: Online Resource
    ISSN: 0951-4198 , 1097-0231
    URL: Issue
    Language: English
    Publisher: Wiley
    Publication Date: 2014
    detail.hit.zdb_id: 2002158-6
    detail.hit.zdb_id: 58731-X
    SSG: 11
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  • 2
    In: Climate of the Past, Copernicus GmbH, Vol. 17, No. 1 ( 2021-02-19), p. 469-490
    Abstract: Abstract. Extensive black shale deposits formed in the Early Cretaceous South Atlantic, supporting the notion that this emerging ocean basin was a globally important site of organic carbon burial. The magnitude of organic carbon burial in marine basins is known to be controlled by various tectonic, oceanographic, hydrological, and climatic processes acting on different temporal and spatial scales, the nature and relative importance of which are poorly understood for the young South Atlantic. Here we present new bulk and molecular geochemical data from an Aptian–Albian sediment record recovered from the deep Cape Basin at Deep Sea Drilling Project (DSDP) Site 361, which we combine with general circulation model results to identify driving mechanisms of organic carbon burial. A multimillion-year decrease (i.e., Early Aptian–Albian) in organic carbon burial, reflected in a lithological succession of black shale, gray shale, and red beds, was caused by increasing bottom water oxygenation due to abating hydrographic restriction via South Atlantic–Southern Ocean gateways. These results emphasize basin evolution and ocean gateway development as a decisive primary control on enhanced organic carbon preservation in the Cape Basin at geological timescales (〉 1 Myr). The Early Aptian black shale sequence comprises alternations of shales with high (〉 6 %) and relatively low (∼ 3.5 %) organic carbon content of marine sources, the former being deposited during the global Oceanic Anoxic Event (OAE) 1a, as well as during repetitive intervals before and after OAE 1a. In all cases, these short-term intervals of enhanced organic carbon burial coincided with strong influxes of sediments derived from the proximal African continent, indicating closely coupled climate–land–ocean interactions. Supported by our model results, we show that fluctuations in weathering-derived nutrient input from the southern African continent, linked to changes in orbitally driven humidity and aridity, were the underlying drivers of repetitive episodes of enhanced organic carbon burial in the deep Cape Basin. These results suggest that deep marine environments of emerging ocean basins responded sensitively and directly to short-term fluctuations in riverine nutrient fluxes. We explain this relationship using the lack of wide and mature continental shelf seas that could have acted as a barrier or filter for nutrient transfer from the continent into the deep ocean.
    Type of Medium: Online Resource
    ISSN: 1814-9332
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2021
    detail.hit.zdb_id: 2217985-9
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  • 3
    Online Resource
    Online Resource
    Geological Society of America ; 2023
    In:  Geology Vol. 51, No. 5 ( 2023-05-01), p. 476-480
    In: Geology, Geological Society of America, Vol. 51, No. 5 ( 2023-05-01), p. 476-480
    Abstract: The Cretaceous opening of the Equatorial Atlantic gateway (EAG) is considered a driver of major changes in global oceanography, carbon cycling, and climate. However, the early stages of EAG opening are poorly understood. We present seawater Nd-isotope, bulk geochemical, and micropaleontological data from two South Atlantic drill cores that constrain the onset of shallow ( & lt;500 m) and intermediate ( & lt;~1000 m) water mass exchange across the EAG to 113 Ma and 107 Ma, respectively. Deep water mass exchange ( & gt;2000 m) was enabled by at least ca. 100 Ma, as much as 10 m.y. earlier than previously estimated. In response to EAG opening, deep-water ventilation in the South Atlantic, North Atlantic, and Tethys basins intensified, thereby triggering basin-scale reductions in organic carbon burial. We propose that the consequent drop in carbon sequestration in concert with increased atmospheric CO2 fluxes from subduction zones acted as major amplifiers of global warming that culminated in peak greenhouse conditions during the mid-Cretaceous.
    Type of Medium: Online Resource
    ISSN: 0091-7613 , 1943-2682
    Language: English
    Publisher: Geological Society of America
    Publication Date: 2023
    detail.hit.zdb_id: 184929-3
    detail.hit.zdb_id: 2041152-2
    SSG: 13
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  • 4
    In: Nature Communications, Springer Science and Business Media LLC, Vol. 9, No. 1 ( 2018-09-10)
    Abstract: The mobilization of glacial permafrost carbon during the last glacial–interglacial transition has been suggested by indirect evidence to be an additional and significant source of greenhouse gases to the atmosphere, especially at times of rapid sea-level rise. Here we present the first direct evidence for the release of ancient carbon from degrading permafrost in East Asia during the last 17 kyrs, using biomarkers and radiocarbon dating of terrigenous material found in two sediment cores from the Okhotsk Sea. Upscaling our results to the whole Arctic shelf area, we show by carbon cycle simulations that deglacial permafrost-carbon release through sea-level rise likely contributed significantly to the changes in atmospheric CO 2 around 14.6 and 11.5 kyrs BP.
    Type of Medium: Online Resource
    ISSN: 2041-1723
    Language: English
    Publisher: Springer Science and Business Media LLC
    Publication Date: 2018
    detail.hit.zdb_id: 2553671-0
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  • 5
    Online Resource
    Online Resource
    Elsevier BV ; 2020
    In:  Earth and Planetary Science Letters Vol. 539 ( 2020-06), p. 116184-
    In: Earth and Planetary Science Letters, Elsevier BV, Vol. 539 ( 2020-06), p. 116184-
    Type of Medium: Online Resource
    ISSN: 0012-821X
    RVK:
    Language: English
    Publisher: Elsevier BV
    Publication Date: 2020
    detail.hit.zdb_id: 300203-2
    detail.hit.zdb_id: 1466659-5
    SSG: 16,13
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  • 6
    In: Radiocarbon, Cambridge University Press (CUP), Vol. 62, No. 1 ( 2020-02), p. 207-218
    Abstract: Compound-specific radiocarbon ( 14 C) dating often requires working with small samples of 〈 100 µg carbon (µgC). This makes the radiocarbon dates of biomarker compounds very sensitive to biases caused by extraneous carbon of unknown composition, a procedural blank, which is introduced to the samples during the steps necessary to prepare a sample for radiocarbon analysis by accelerator mass spectrometry (i.e., isolating single compounds from a heterogeneous mixture, combustion, gas purification and graphitization). Reporting accurate radiocarbon dates thus requires a correction for the procedural blank. We present our approach to assess the fraction modern carbon (F 14 C) and the mass of the procedural blanks introduced during the preparation procedures of lipid biomarkers (i.e. n -alkanoic acids) and lignin phenols. We isolated differently sized aliquots (6–151 µgC) of n -alkanoic acids and lignin phenols obtained from standard materials with known F 14 C values. Each compound class was extracted from two standard materials (one fossil, one modern) and purified using the same procedures as for natural samples of unknown F 14 C. There is an inverse linear relationship between the measured F 14 C values of the processed aliquots and their mass, which suggests constant contamination during processing of individual samples. We use Bayesian methods to fit linear regression lines between F 14 C and 1/mass for the fossil and modern standards. The intersection points of these lines are used to infer F 14 C blank and m blank and their associated uncertainties. We estimate 4.88 ± 0.69 μgC of procedural blank with F 14 C of 0.714 ± 0.077 for n -alkanoic acids, and 0.90 ± 0.23 μgC of procedural blank with F 14 C of 0.813 ± 0.155 for lignin phenols. These F 14 C blank and m blank can be used to correct AMS results of lipid and lignin samples by isotopic mass balance. This method may serve as a standardized procedure for blank assessment in small-scale radiocarbon analysis.
    Type of Medium: Online Resource
    ISSN: 0033-8222 , 1945-5755
    Language: English
    Publisher: Cambridge University Press (CUP)
    Publication Date: 2020
    detail.hit.zdb_id: 2028560-7
    SSG: 11
    SSG: 13
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  • 7
    In: Nature Communications, Springer Science and Business Media LLC, Vol. 12, No. 1 ( 2021-09-13)
    Abstract: The Weissert Event ~133 million years ago marked a profound global cooling that punctuated the Early Cretaceous greenhouse. We present modelling, high-resolution bulk organic carbon isotopes and chronostratigraphically calibrated sea surface temperature (SSTs) based on an organic paleothermometer (the TEX 86 proxy), which capture the Weissert Event in the semi-enclosed Weddell Sea basin, offshore Antarctica (paleolatitude ~54 °S; paleowater depth ~500 meters). We document a ~3–4 °C drop in SST coinciding with the Weissert cold end, and converge the Weddell Sea data, climate simulations and available worldwide multi-proxy based temperature data towards one unifying solution providing a best-fit between all lines of evidence. The outcome confirms a 3.0 °C ( ±1.7 °C) global mean surface cooling across the Weissert Event, which translates into a ~40% drop in atmospheric p CO 2 over a period of ~700 thousand years. Consistent with geologic evidence, this p CO 2 drop favoured the potential build-up of local polar ice.
    Type of Medium: Online Resource
    ISSN: 2041-1723
    Language: English
    Publisher: Springer Science and Business Media LLC
    Publication Date: 2021
    detail.hit.zdb_id: 2553671-0
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