Description: Long sediment cores were collected in spring 2006 from Lake Petén Itzá, northern Guatemala, in water depths ranging from 30 to 150 m, as part of an International Continental Scientific Drilling Program project. The sediment records from deep water consist mainly of alternating clay, gypsum and carbonate units and, in at least two drill sites, extend back 〉200 kyr. Most of the lithostratigraphic units are traceable throughout the basin along seismic reflections that serve as seismic stratigraphic boundaries and suggest that the lithostratigraphy can be used to infer regional palaeoenvironmental changes. A revised seismic stratigraphy was established on the basis of integrated lithological and seismic reflection data from the basin. From ca 200 to ca 85 ka, sediments are dominated by carbonate-clay silt, often interbedded with sandy turbidites, indicating a sediment regime dominated by detrital sedimentation in a relatively humid climate. At ca 85 ka, an exposure horizon consisting of gravels, coarse sand and terrestrial gastropods marks a lake lowstand or partial basin desiccation, indicating dry climate conditions. From ca 85 to ca 48 ka, transgressive carbonate-clay sediments, overlain by deep-water clays, suggest a lake level rise and subsequent stabilization at high stage. From ca 48 ka to present, the lithology is characterized by alternating clay and gypsum units. Gypsum deposition correlates with Heinrich Events (i.e. dry climate), whereas clay units coincide with more humid interstadials.

Description: Be and Nd isotope compositions and metal concentrations (Mn, Fe, Co, Ni, and Cu) of surface and subsurface ferromanganese hardground crusts from Ocean Drilling Program Leg 194 Marion Plateau Sites 1194 and 1196 provide new insights into the crusts' genesis, growth rates, and ages. Metal compositions indicate that the hardgrounds, which have grown on erosional surfaces in water depths of 〈400 m because of strong bottom currents, are not pure hydrogenetic precipitates. Nevertheless, the ratios between cosmogenic 10Be and stable 9Be in hardgrounds from the present-day seafloor at Site 1196 between 1 x 10–7 and 1.5 x 10–7 are within the range of values expected for Pacific seawater, which shows that the hardgrounds recorded the isotope composition of ambient seawater. This is also confirmed by their Nd isotope composition (Nd between –3 and 0). The 10Be/9Be ratios in the up to 30-mm-thick and partly laminated hardgrounds do not show a decrease with depth, which suggests high growth rates on the present-day seafloor. The subsurface crust at Site 1194 (117 m below the seafloor) grew during a sedimentation hiatus, when bottom currents in the late Miocene prevented sediment accumulation on the carbonate platform during a sea level lowstand. The age of 8.65 ± 0.50 Ma for this crust obtained from 10Be-based dating agrees well with the combined seismostratigraphic and biostratigraphic evidence, which suggests an age for the hiatus between 7.7 and 11.8 Ma.

Description: Sedimentary archives host a wealth of information that can be used to reconstruct paleoclimate as well as the tectonic and volcanic histories of specific regions. Long and continuous archives from the oceans have been collected in thousands of locations by scientific ocean drilling programs over the past 40 years. In contrast, suitable continental archives are rare because terrestrial environments are generally nondepositional and/or subject to erosion. Lake sediments provide ideal drilling targets to overcome this limitation if suitable lakes at key locations have existed continuously for a long time.

Description: Lake Van is the fourth largest terminal lake in the world (volume 607 km3, area 3,570 km2, maximum depth 460 m), extending for 130 km WSW-ENE on the Eastern Anatolian High Plateau, Turkey. Within the sensitive climate region of north-eastern Anatolia, the Lake Van record, partly laminated, represents an excellent continental climate archive between the Black Sea, the Arabian Sea and the Red Sea that covers several glacial-interglacial cycles. Therefore, Lake Van is a key site within the International Continental Scientific Drilling Program (ICDP) for the investigation of the Quaternary climate evolution in the Near East. The ICDP drilling operation was carried out from July 2 to August 23, 2010. DOSECC, as operator of the deep drilling, has built the new Deep Lake Drilling System (DLDS), which was specifically designed for sampling sediments from deep lakes and which made its maiden voyage on Lake Van. The DSDL was operated at water depths of up to 360 m. Two sites were drilled and cores of 140 m (Northern Basin) and 220 m (Ahlat Ridge) depth were retrieved. The sediments of the very bottom document the initial phase of the lake formation, which was characterized by fresh water conditions. We collected a total recovered sediment core length of over 800 m, which allow an unprecedented look back in time at the scale of at least three glacial-interglacial cycles. Several meter thick tephra layers originating from volcanoes surrounding the lake were also recovered, allowing reconstructions of larger volcanic events and related environmental impacts. Furthermore, they offer through tephrachronology and radiogenic-isotope analyses the means to date the stratigraphic section beyond the range of radiocarbon. We will be able to present the first results of this campaign during the INQUA congress. This contribution is co-authored by the entire ‘PaleoVan’ scientific drilling party.

Description: Within the frame of the International Continental scientific Drilling Program (ICDP) project PALEOVAN, a long and continuous sediment record from Lake Van, a closed lake situated in a climatically sensitive semiarid and tectonically active region in Eastern Anatolia, has been drilled in summer 2010. At two sites, Ahlat Ridge and Northern Basin, sedimentary records of 220 and 140 m were recovered, respectively. With basal ages possibly around 500'000 years, these records span several glacial-interglacial cycles and reach back until the lake’s initial transgression in the Middle Pleistocene. First results from ongoing analysis of core-catcher samples and newly opened cores document the sedimentological and geochemical succession. Two composite profiles of the drill sites were defined. Core catcher-based geochemical data such as proxies of lake’s productivity and catchment alterations show large variations and reflect a rich paleoenvironmental history. Most of the 220 m thick succession consists of carbonate mud, mostly sub-mm-thick laminated and interbedded by either homogenous mud or pyroclastic cm-thick layers. The lowermost sediments from the Ahlat Ridge site represent the initial lake transition as the drilling could not penetrate further and the seismic data indicates coincidence with the ‘acoustic’ basement. Such an early transgressive state of the lake’s history is also supported by the lithology consisting of a gravel unit as an indicator of a beach-like environment, which is overlain by sand deposits containing fresh-water gastropods (Bithynia). Above 200 mblf, the laminated mud clearly indicates that the lake was already deep enough to form anoxic bottom water as the laminations were preserved. This unique paleoclimate archive indicates that great changes of the depositional conditions occurred that hint to a fascinating evolution of the environment and has ideal prerequisites for the investigation of the Quaternary climate evolution in the Near East.

Description: Highlights • Deglacial chemical weathering monitored by adsorbed isotopic and elemental signals • Resilience of authigenic geochemical signals towards variable lake redox conditions • Pronounced early deglacial weathering of labile accessory minerals • Remarkably congruent uranogenic and reduced thorogenic Pb isotope release • Anthropogenic, atmospherically deposited Pb pollution since over 2000 years Abstract Radiogenic Pb and Nd isotopes are well established tools in paleoceanographic science tracing ambient climate and continental runoff to the oceans down to sub-millennial timescales. Particularly in case of Pb isotopes, a clear climate dependency of continental isotopic runoff on glacial-interglacial transitions has been observed. Pb isotopes were reported to be released incongruently during initial chemical weathering. This incongruent release implies that Pb isotopic runoff compositions differ from the bulk catchment Pb isotopic signal. Yet only little is known about the processes leading to the incongruent release and the timescales of weathering on the continents. In this study we targeted the adsorbed trace metal signature in sediments from a Swiss high-Alpine lake that have accumulated since the retreat of the large Alpine ice domes during the last deglaciation to investigate initial Pb and Nd isotope weathering processes in a granitic environment. Additionally, selected adsorbed element concentrations and ratios were analysed to complement the isotopic physico-chemical weathering information. The integrity of the presented isotope records is supported by further investigation into the lake environment (e.g. oxic/anoxic conditions) and its potential influence on the isotopic record. The Pb isotope records during the early lake phase witnessed high-amplitude isotopic fluctuations linked to the initial chemical weathering of fine glacial substrate. This finding is also supported by the lithology of the core and rapidly decreasing adsorbed Th and U concentrations. Following this early lake phase, the majority of the Holocene traced congruent release of 207Pb/204Pb and 206Pb/204Pb and a significant depletion of 208Pb/204Pb in the adsorbed phase. These findings corroborate earlier suggestions of more effective weathering of uranogenic minerals yet also call for the presence of more weathering-resistant thorogenic minerals in the lake catchment. The latest 2.2 ka of the record are significantly overprinted by anthropogenic Pb deposition coinciding with the rise and fall of the Roman Empire. Finally, our data suggest that Nd isotopes are equally affected by incongruent weathering during the initial deglacial weathering processes, albeit at smaller magnitude than seen for Pb isotopes.