In:
Magnetic Resonance in Chemistry, Wiley, Vol. 33, No. 13 ( 1995-12)
Abstract:
The radical anions and radical cations of two alkyl‐substituted non‐alternant hydrocarbons, 1,3,5,7‐tetra‐ tert ‐butyl‐ s ‐indacene and 2,7‐di‐ tert ‐butyldicyclopenta [ a,e ] cyclooctene, were characterized by their proton coupling constants with the use of ESR and, in part, ENDOR spectroscopy. Considering the unusual electronic structures of the π‐systems in question, these values agree fairly well with those predicted by simple MO theory. Also reported are the proton hyperfine data for the radical ions of the likewise alkyl‐substituted non‐alternant 8,16‐diisopropyl‐ s ‐indaceno [1,2,3‐ cd :5,6,7‐ c′ d′ ] diphenalene.
Type of Medium:
Online Resource
ISSN:
0749-1581
,
1097-458X
DOI:
10.1002/mrc.1260331311
Language:
English
Publisher:
Wiley
Publication Date:
1995
detail.hit.zdb_id:
1475029-6
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