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  • 11
    Online Resource
    Online Resource
    Copernicus GmbH ; 2021
    In:  Earth System Science Data Vol. 13, No. 5 ( 2021-05-18), p. 2095-2110
    In: Earth System Science Data, Copernicus GmbH, Vol. 13, No. 5 ( 2021-05-18), p. 2095-2110
    Abstract: Abstract. Carbonyl sulphide (OCS) is the most abundant, long-lived sulphur gas in the atmosphere and a major supplier of sulphur to the stratospheric sulphate aerosol layer. The short-lived gas carbon disulphide (CS2) is oxidized to OCS and constitutes a major indirect source to the atmospheric OCS budget. The atmospheric budget of OCS is not well constrained due to a large missing source needed to compensate for substantial evidence that was provided for significantly higher sinks. Oceanic emissions are associated with major uncertainties. Here we provide a first, monthly resolved ocean emission inventory of both gases for the period 2000–2019 (available at https://doi.org/10.5281/zenodo.4297010) (Lennartz et al., 2020a). Emissions are calculated with a numerical box model (2.8∘×2.8∘ resolution at the Equator, T42 grid) for the oceanic surface mixed layer, driven by ERA5 data from ECMWF and chromophoric dissolved organic matter (CDOM) from Aqua MODIS. We find that interannual variability in OCS emissions is smaller than seasonal variability and is mainly driven by variations in CDOM, which influences both photochemical and light-independent production. A comparison with a global database of more than 2500 measurements reveals overall good agreement. Emissions of CS2 constitute a larger sulphur source to the atmosphere than OCS and equally show interannual variability connected to variability in CDOM. The emission estimate of CS2 is associated with higher uncertainties as process understanding of the marine cycling of CS2 is incomplete. We encourage the use of the data provided here as input for atmospheric modelling studies to further assess the atmospheric OCS budget and the role of OCS in climate.
    Type of Medium: Online Resource
    ISSN: 1866-3516
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2021
    detail.hit.zdb_id: 2475469-9
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  • 12
    Online Resource
    Online Resource
    Elsevier BV ; 2012
    In:  Current Opinion in Environmental Sustainability Vol. 4, No. 3 ( 2012-07), p. 323-330
    In: Current Opinion in Environmental Sustainability, Elsevier BV, Vol. 4, No. 3 ( 2012-07), p. 323-330
    Type of Medium: Online Resource
    ISSN: 1877-3435
    Language: English
    Publisher: Elsevier BV
    Publication Date: 2012
    detail.hit.zdb_id: 2514810-2
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  • 13
    In: Atmospheric Environment, Elsevier BV, Vol. 209 ( 2019-07), p. 86-91
    Type of Medium: Online Resource
    ISSN: 1352-2310
    Language: English
    Publisher: Elsevier BV
    Publication Date: 2019
    detail.hit.zdb_id: 216368-8
    detail.hit.zdb_id: 1499889-0
    SSG: 14
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  • 14
    In: Journal of Geophysical Research: Atmospheres, American Geophysical Union (AGU), Vol. 125, No. 15 ( 2020-08-16)
    Abstract: We develop an online air‐sea exchange module for acetone, with ocean biogeochemistry represented using data‐oriented machine learning Two separate global acetone simulations are compared to global‐scale multiseasonal airborne observations Global models consistently overestimate acetone in the upper troposphere over the Southern Ocean in austral winter
    Type of Medium: Online Resource
    ISSN: 2169-897X , 2169-8996
    Language: English
    Publisher: American Geophysical Union (AGU)
    Publication Date: 2020
    detail.hit.zdb_id: 710256-2
    detail.hit.zdb_id: 2016800-7
    detail.hit.zdb_id: 2969341-X
    SSG: 16,13
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  • 15
    In: Frontiers in Marine Science, Frontiers Media SA, Vol. 9 ( 2022-6-30)
    Abstract: The air-sea gas transfer velocity ( K 660 ) is typically assessed as a function of the 10-m neutral wind speed ( U 10n ), but there remains substantial uncertainty in this relationship. Here K 660 of CO 2 derived with the eddy covariance (EC) technique from eight datasets (11 research cruises) are reevaluated with consistent consideration of solubility and Schmidt number and inclusion of the ocean cool skin effect. K 660 shows an approximately linear dependence with the friction velocity ( u * ) in moderate winds, with an overall relative standard deviation (relative standard error) of about 20% (7%). The largest relative uncertainty in K 660 occurs at low wind speeds, while the largest absolute uncertainty in K 660 occurs at high wind speeds. There is an apparent regional variation in the steepness of the K 660 - u * relationships: North Atlantic ≥ Southern Ocean & gt; other regions (Arctic, Tropics). Accounting for sea state helps to collapse some of this regional variability in K 660 using the wave Reynolds number in very large seas and the mean squared slope of the waves in small to moderate seas. The grand average of EC-derived K 660 ( − 1.47   +   76.67 u * +   20.48 u * 2   o r   0.36   +   1.203 U 10 n +   0.167 U 10 n 2 ) is similar at moderate to high winds to widely used dual tracer-based K 660 parametrization, but consistently exceeds the dual tracer estimate in low winds, possibly in part due to the chemical enhancement in air-sea CO 2 exchange. Combining the grand average of EC-derived K 660 with the global distribution of wind speed yields a global average transfer velocity that is comparable with the global radiocarbon ( 14 C) disequilibrium, but is ~20% higher than what is implied by dual tracer parametrizations. This analysis suggests that CO 2 fluxes computed using a U 10 n 2 dependence with zero intercept (e.g., dual tracer) are likely underestimated at relatively low wind speeds.
    Type of Medium: Online Resource
    ISSN: 2296-7745
    Language: Unknown
    Publisher: Frontiers Media SA
    Publication Date: 2022
    detail.hit.zdb_id: 2757748-X
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  • 16
    In: Global Biogeochemical Cycles, American Geophysical Union (AGU), Vol. 35, No. 6 ( 2021-06)
    Abstract: Surface seawater dimethylsulfide (DMS) concentrations remain unchanged after sea ice retreat in the western Canada Basin Increased wind speed is a critical factor driving the enhancement of dimethylsulfide (DMS) flux after sea ice retreat at high latitudes in the Arctic Ocean Nutrient supply is hypothesized to significantly impact dimethylsulfide (DMS) distribution in the western Arctic Ocean
    Type of Medium: Online Resource
    ISSN: 0886-6236 , 1944-9224
    Language: English
    Publisher: American Geophysical Union (AGU)
    Publication Date: 2021
    detail.hit.zdb_id: 2021601-4
    SSG: 12
    SSG: 13
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  • 17
    Online Resource
    Online Resource
    Copernicus GmbH ; 2016
    In:  Ocean Science Vol. 12, No. 4 ( 2016-07-04), p. 861-873
    In: Ocean Science, Copernicus GmbH, Vol. 12, No. 4 ( 2016-07-04), p. 861-873
    Abstract: Abstract. A strong El Niño developed in early 2015. Measurements from a research cruise on the R/V Sonne in October 2015 near the Equator east of the Galapagos Islands and off the shelf of Peru are used to investigate changes related to El Niño in the upper ocean in comparison with earlier cruises in this region. At the Equator at 85°30′ W, a clear temperature increase leading to lower densities in the upper 350 m had developed in October 2015, despite a concurrent salinity increase from 40 to 350 m. Lower nutrient concentrations were also present in the upper 200 m, and higher oxygen concentrations were observed between 40 and 130 m. In the equatorial current field, the Equatorial Undercurrent (EUC) east of the Galapagos Islands almost disappeared in October 2015, with a transport of only 0.02 Sv in the equatorial channel between 1° S and 1° N, and a weak current band of 0.78 Sv located between 1 and 2°30′ S. Such near-disappearances of the EUC in the eastern Pacific seem to occur only during strong El Niño events. Off the Peruvian shelf at  ∼  9° S, characteristics of upwelling were different as warm, saline, and oxygen-rich water was upwelled. At  ∼  12,  ∼  14, and  ∼  16° S, the upwelling of cold, low-salinity, and oxygen-poor water was still active at the easternmost stations of these three sections, while further west on these sections a transition to El Niño conditions appeared. Although from early 2015 the El Niño was strong, the October measurements in the eastern tropical Pacific only showed developing El Niño water mass distributions. In particular, the oxygen distribution indicated the ongoing transition from “typical” to El Niño conditions progressing southward along the Peruvian shelf.
    Type of Medium: Online Resource
    ISSN: 1812-0792
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2016
    detail.hit.zdb_id: 2183769-7
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  • 18
    Online Resource
    Online Resource
    Copernicus GmbH ; 2022
    In:  Biogeosciences Vol. 19, No. 20 ( 2022-10-28), p. 5021-5040
    In: Biogeosciences, Copernicus GmbH, Vol. 19, No. 20 ( 2022-10-28), p. 5021-5040
    Abstract: Abstract. Climate-relevant trace gas air–sea exchange exerts an important control on air quality and climate, especially in remote regions of the planet such as the Southern Ocean. It is clear that polar regions exhibit seasonal trends in productivity and biogeochemical cycling, but almost all of the measurements there are skewed to summer months. If we want to understand how the Southern Ocean affects the balance of climate through trace gas air–sea exchange, it is essential to expand our measurement database over greater temporal and spatial scales, including all seasons. Therefore, in this study, we report measured concentrations of dimethylsulfide (DMS, as well as related sulfur compounds) and isoprene in the Atlantic sector of the Southern Ocean during the winter to understand the spatial and temporal distribution in comparison to current knowledge and climatological calculations for the Southern Ocean. The observations of isoprene are the first in the winter season in the Southern Ocean. We found that the concentrations of DMS from the surface seawater and air in the investigated area were 1.03 ± 0.98 nmol−1 and 28.80 ±  12.49 pptv, respectively. The concentrations of isoprene in surface seawater were 14.46 ± 12.23 pmol−1. DMS and isoprene fluxes were 4.04 ± 4.12 µmol m−2 d−1 and 80.55 ± 78.57 nmol m−2 d−1, respectively. These results are generally lower than the values presented or calculated in currently used climatologies and models. More data are urgently needed to better interpolate climatological values and validate process-oriented models, as well as to explore how finer measurement resolution, both spatially and temporally, can influence air–sea flux calculations.
    Type of Medium: Online Resource
    ISSN: 1726-4189
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2022
    detail.hit.zdb_id: 2158181-2
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  • 19
    In: Earth System Science Data, Copernicus GmbH, Vol. 12, No. 1 ( 2020-03-17), p. 591-609
    Abstract: Abstract. Carbonyl sulfide (OCS) and carbon disulfide (CS2) are volatile sulfur gases that are naturally formed in seawater and exchanged with the atmosphere. OCS is the most abundant sulfur gas in the atmosphere, and CS2 is its most important precursor. They have attracted increased interest due to their direct (OCS) or indirect (CS2 via oxidation to OCS) contribution to the stratospheric sulfate aerosol layer. Furthermore, OCS serves as a proxy to constrain terrestrial CO2 uptake by vegetation. Oceanic emissions of both gases contribute a major part to their atmospheric concentration. Here we present a database of previously published and unpublished (mainly shipborne) measurements in seawater and the marine boundary layer for both gases, available at https://doi.org/10.1594/PANGAEA.905430 (Lennartz et al., 2019). The database contains original measurements as well as data digitalized from figures in publications from 42 measurement campaigns, i.e., cruises or time series stations, ranging from 1982 to 2019. OCS data cover all ocean basins except for the Arctic Ocean, as well as all months of the year, while the CS2 dataset shows large gaps in spatial and temporal coverage. Concentrations are consistent across different sampling and analysis techniques for OCS. The database is intended to support the identification of global spatial and temporal patterns and to facilitate the evaluation of model simulations.
    Type of Medium: Online Resource
    ISSN: 1866-3516
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2020
    detail.hit.zdb_id: 2475469-9
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  • 20
    In: Atmospheric Chemistry and Physics, Copernicus GmbH, Vol. 16, No. 18 ( 2016-09-22), p. 11807-11821
    Abstract: Abstract. We use isoprene and related field measurements from three different ocean data sets together with remotely sensed satellite data to model global marine isoprene emissions. We show that using monthly mean satellite-derived chl a concentrations to parameterize isoprene with a constant chl a normalized isoprene production rate underpredicts the measured oceanic isoprene concentration by a mean factor of 19 ± 12. Improving the model by using phytoplankton functional type dependent production values and by decreasing the bacterial degradation rate of isoprene in the water column results in only a slight underestimation (factor 1.7 ± 1.2). We calculate global isoprene emissions of 0.21 Tg C for 2014 using this improved model, which is twice the value calculated using the original model. Nonetheless, the sea-to-air fluxes have to be at least 1 order of magnitude higher to account for measured atmospheric isoprene mixing ratios. These findings suggest that there is at least one missing oceanic source of isoprene and, possibly, other unknown factors in the ocean or atmosphere influencing the atmospheric values. The discrepancy between calculated fluxes and atmospheric observations must be reconciled in order to fully understand the importance of marine-derived isoprene as a precursor to remote marine boundary layer particle formation.
    Type of Medium: Online Resource
    ISSN: 1680-7324
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2016
    detail.hit.zdb_id: 2092549-9
    detail.hit.zdb_id: 2069847-1
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