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  • 1
    In: Pharmaceutical Research, Springer Science and Business Media LLC, Vol. 35, No. 6 ( 2018-6)
    Type of Medium: Online Resource
    ISSN: 0724-8741 , 1573-904X
    Language: English
    Publisher: Springer Science and Business Media LLC
    Publication Date: 2018
    detail.hit.zdb_id: 2036232-8
    SSG: 15,3
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  • 2
    In: Geochemistry, Elsevier BV, Vol. 72, No. 1 ( 2012-01), p. 85-89
    Type of Medium: Online Resource
    ISSN: 0009-2819
    RVK:
    Language: English
    Publisher: Elsevier BV
    Publication Date: 2012
    detail.hit.zdb_id: 1505-2
    detail.hit.zdb_id: 2082649-7
    SSG: 13
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  • 3
    Online Resource
    Online Resource
    Geological Society of America ; 2001
    In:  Geological Society of America Bulletin Vol. 113, No. 8 ( 2001-8), p. 1092-1104
    In: Geological Society of America Bulletin, Geological Society of America, Vol. 113, No. 8 ( 2001-8), p. 1092-1104
    Type of Medium: Online Resource
    ISSN: 0016-7606
    Language: Unknown
    Publisher: Geological Society of America
    Publication Date: 2001
    detail.hit.zdb_id: 2028776-8
    detail.hit.zdb_id: 2008165-0
    detail.hit.zdb_id: 449720-X
    detail.hit.zdb_id: 1351-1
    SSG: 13
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  • 4
    In: Clay Minerals, Mineralogical Society, Vol. 54, No. 1 ( 2019-03), p. 15-26
    Abstract: Clay mineral ‘Crystallinity Index Standards’ (CIS) composed of Palaeozoic mudrocks from southwest England were investigated systematically in five sub-fractions per sample for the first time. X-ray diffraction was used to determine mineral assemblages, calibrated 001 illite full-width-at-half-maximum (FWHM) values and illite polytype compositions, in addition to K–Ar isotopic analyses of all fine fractions. The FWHM results of the 〈 2 µm fraction are consistent with previous studies and reflect the range of diagenetic to epizonal grades covered by the sample set SW1 to SW7 (~0.61–0.26°2θ). Diagenetic and lower anchizone samples also show significant broadening of 001 illite reflections in the finer fractions and contain mixtures of authigenic 1 M + 1 M d illite and detrital 2 M 1 white mica polytypes suitable for illite age analysis. The estimated end-member ages of the Bude (SW1-1992) and younger Crackington (SW3-2000) mudstones yield detrital ages of Late Cambrian to Middle Ordovician (493–457 Ma) and a broad range of 1 M + 1 M d illite ages between Middle Permian and Early Jurassic (271–190 Ma). The detrital age of the stratigraphically older Crackington Formation mudrock (SW2-1992) is Late Devonian (384–364 Ma) with 1 M + 1 M d illite ages between Late Triassic and Early Jurassic (219–176 Ma). The origin of Mesozoic 1 M + 1 M d illite ages may represent neocrystallized illite associated with Mesozoic hydrothermal events or similar events that thermally reset older authigenic illite with partial loss of radiogenic argon and no renewed crystal growth. In contrast, upper anchizonal and epizonal Devonian slates (SW3-2012, SW4-1992, SW6-1992 and SW7-2012) contain only the 2 M 1 polytype, with K–Ar ages younger than the stratigraphic age. The three finest fractions of SW4-1992 yield consistent Late Carboniferous ages (331–304 ± 7 Ma) that are considered to date the neocrystallized 2 M 1 mica. Most fractions of epizonal slate (SW6-1992, SW7-2012) yield Early Permian ages (293.6–273 Ma) corresponding to published cooling ages of the Tintagel High-Strain Zone and the intrusion of the Bodmin granite (291.4 ± 0.8 Ma). These first K–Ar age constraints for the fine fractions of the CIS should provide useful reference values for testing analytical procedures of illite age analysis.
    Type of Medium: Online Resource
    ISSN: 0009-8558 , 1471-8030
    RVK:
    Language: English
    Publisher: Mineralogical Society
    Publication Date: 2019
    detail.hit.zdb_id: 2036186-5
    detail.hit.zdb_id: 961059-5
    SSG: 13
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  • 5
    Online Resource
    Online Resource
    Copernicus GmbH ; 2016
    In:  Solid Earth Vol. 7, No. 4 ( 2016-07-22), p. 1145-1156
    In: Solid Earth, Copernicus GmbH, Vol. 7, No. 4 ( 2016-07-22), p. 1145-1156
    Abstract: Abstract. The goal of this study is to better understand the porosity and permeability in shales to improve modelling fluid and gas flow related to shale diagenesis. Two samples (WIC and HAD) were investigated, both mid-Jurassic organic-rich Posidonia shales from Hils area, central Germany of different maturity (WIC R0 0.53 % and HAD R0 1.45 %). The method for image collection was focused ion beam (FIB) microscopy coupled with scanning electron microscopy (SEM). For image and data analysis Avizo and GeoDict was used. Porosity was calculated from segmented 3-D FIB based images and permeability was simulated by a Navier Stokes–Brinkman solver in the segmented images. Results show that the quantity and distribution of pore clusters and pores (≥  40 nm) are similar. The largest pores are located within carbonates and clay minerals, whereas the smallest pores are within the matured organic matter. Orientation of the pores calculated as pore paths showed minor directional differences between the samples. Both samples have no continuous connectivity of pore clusters along the axes in the x, y, and z direction on the scale of 10 to 20 of micrometer, but do show connectivity on the micrometer scale. The volume of organic matter in the studied volume is representative of the total organic carbon (TOC) in the samples. Organic matter does show axis connectivity in the x, y, and z directions. With increasing maturity the porosity in organic matter increases from close to 0 to more than 5 %. These pores are small and in the large organic particles have little connection to the mineral matrix. Continuous pore size distributions are compared with mercury intrusion porosimetry (MIP) data. Differences between both methods are caused by resolution limits of the FIB-SEM and by the development of small pores during the maturation of the organic matter. Calculations show no permeability when only considering visible pores due to the lack of axis connectivity. Adding the organic matter with a background permeability of 1 × 10−21 m2 to the calculations, the total permeability increased by up to 1 order of magnitude for the low mature and decreases slightly for the overmature sample from the gas window. Anisotropy of permeability was observed. Permeability coefficients increase by 1 order of magnitude if simulations are performed parallel to the bedding. Our results compare well with experimental data from the literature suggesting that upscaling may be possible in the future as soon as maturity dependent organic matter permeability coefficients can be determined.
    Type of Medium: Online Resource
    ISSN: 1869-9529
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2016
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  • 6
    In: Minerals, MDPI AG, Vol. 11, No. 9 ( 2021-09-18), p. 1017-
    Abstract: Pilot sites are currently used to test the performance of bentonite barriers for sealing high-level radioactive waste repositories, but the degree of mineral stability under enhanced thermal conditions remains a topic of debate. This study focuses on the SKB ABM5 experiment, which ran for 5 years (2012 to 2017) and locally reached a maximum temperature of 250 °C. Five bentonites were investigated using XRD with Rietveld refinement, SEM-EDX and by measuring pH, CEC and EC. Samples extracted from bentonite blocks at 0.1, 1, 4 and 7 cm away from the heating pipe showed various stages of alteration related to the horizontal thermal gradient. Bentonites close to the contact with lower CEC values showed smectite alterations in the form of tetrahedral substitution of Si4+ by Al3+ and some octahedral metal substitutions, probably related to ferric/ferrous iron derived from corrosion of the heater during oxidative boiling, with pyrite dissolution and acidity occurring in some bentonite layers. This alteration was furthermore associated with higher amounts of hematite and minor calcite dissolution. However, as none of the bentonites showed any smectite loss and only displayed stronger alterations at the heater–bentonite contact, the sealants are considered to have remained largely intact.
    Type of Medium: Online Resource
    ISSN: 2075-163X
    Language: English
    Publisher: MDPI AG
    Publication Date: 2021
    detail.hit.zdb_id: 2655947-X
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  • 7
    Online Resource
    Online Resource
    Scientific Research Publishing, Inc. ; 2013
    In:  Engineering Vol. 05, No. 03 ( 2013), p. 251-267
    In: Engineering, Scientific Research Publishing, Inc., Vol. 05, No. 03 ( 2013), p. 251-267
    Type of Medium: Online Resource
    ISSN: 1947-3931 , 1947-394X
    Language: Unknown
    Publisher: Scientific Research Publishing, Inc.
    Publication Date: 2013
    detail.hit.zdb_id: 2568911-3
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  • 8
    Online Resource
    Online Resource
    International Union of Crystallography (IUCr) ; 2008
    In:  Journal of Applied Crystallography Vol. 41, No. 2 ( 2008-04-01), p. 402-415
    In: Journal of Applied Crystallography, International Union of Crystallography (IUCr), Vol. 41, No. 2 ( 2008-04-01), p. 402-415
    Abstract: This work reports the structural characterization of illite-1M from northern Hungary, with the first attempt to refine the structure model and locate the interlayer water molecule. Structural characterization was accomplished using state-of-the-art analytical methods available for clays. The results illustrate the status of techniques for clay structure determination, as well as providing a structural model for illite. The chemical formula for the illite-1M under investigation can be written as K 0.78 Ca 0.02 Na 0.02 (Mg 0.34 Al 1.69 Fe III 0.02 )[Si 3.35 Al 0.65 ]O 10 (OH) 2 · n H 2 O. Structure simulations with WILDFIRE yielded a model with 30% of cis -vacant layers and an expandability percentage of 10%. The value of the percentage of expandability was confirmed with NEWMOD , with which the best simulation was obtained with 90% of di-octahedral mica with K (80% site population) in the interlayer region and 10% of expandable layers. The best structure simulation obtained with DIFFaX was also obtained with a population of K atoms of 80%, six cells along c (in agreement with the results of a transmission electron microscopy study) and an average dimension of the particles in the ab plane of 300 nm. Besides the determination of the basic structure unit (the results are consistent with those obtained with the local information provided by a fit of the pair distribution function data) and the model of disorder, refinement with DIFFaX + allowed the calculation of a possible position for the interlayer water molecule. Although physically sound, both the observed tetrahedral layer corrugation and the location of the water molecule need further experimental evidence, because the final fit of the observed pattern is still imperfect. The reasons for this misfit are discussed.
    Type of Medium: Online Resource
    ISSN: 0021-8898
    RVK:
    Language: Unknown
    Publisher: International Union of Crystallography (IUCr)
    Publication Date: 2008
    detail.hit.zdb_id: 2020879-0
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  • 9
    In: Clays and Clay Minerals, Cambridge University Press (CUP), Vol. 70, No. 1 ( 2022-02), p. 84-105
    Abstract: Diagenetic illite growth in porous sandstones leads to significant modifications of the initial pore system which result in tight reservoirs. Understanding and quantifying these changes provides insight into the porosity-permeability history of the reservoir and improves predictions on petrophysical behavior. To characterize the various stages of diagenetic alteration, a focused ion beam – scanning electron microscopy (FIB-SEM) study was undertaken on aeolian sandstones from the Bebertal outcrop of the Parchim Formation (Early Permian Upper Rotliegend group). Based on 3D microscopic reconstructions, three different textural types of illite crystals occur, common to many tight Rotliegend sandstones, namely (1) feldspar grain alterations and associated illite meshworks, (2) tangential grain coats, and (3) pore-filling laths and fibers. Reaction textures, pore structure quantifications, and numerical simulations of fluid transport have revealed that different generations of nano-porosity are connected to the diagenetic alteration of feldspars and the authigenic growth of pore-filling illites. The latter leads to the formation of microstructures that range from authigenic compact tangential grain coatings to highly porous, pore-filling structures. K-feldspar replacement and initial grain coatings of illite are composed primarily of disordered 1 M d illite whereas the epitaxially grown illite lath- and fiber-shaped crystals occurring as pore-filling structures are of the trans -vacant 1 M tv polytype. Although all analyzed 3D structures offer connected pathways, the largest reduction in sandstone permeability occurred during the initial formation of the tangential illite coatings that sealed altered feldspars and the subsequent growth of pore-filling laths and fibrous illites. Analyses of both illite pore-size and crystallite-size distributions indicate that crystal growth occurred by a continuous nucleation and growth mechanism probably controlled by the multiple influx of potassium-rich fluids during late Triassic and Jurassic times. The detailed insight into the textural varieties of illite crystal growth and its calculated permeabilities provides important constraints for understanding the complexities of fluid-flow in tight reservoir sandstones.
    Type of Medium: Online Resource
    ISSN: 0009-8604 , 1552-8367
    Language: English
    Publisher: Cambridge University Press (CUP)
    Publication Date: 2022
    detail.hit.zdb_id: 2045991-9
    detail.hit.zdb_id: 221428-3
    SSG: 13
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  • 10
    In: SpringerPlus, Springer Science and Business Media LLC, Vol. 3, No. 1 ( 2014-12)
    Type of Medium: Online Resource
    ISSN: 2193-1801
    Language: English
    Publisher: Springer Science and Business Media LLC
    Publication Date: 2014
    detail.hit.zdb_id: 2661116-8
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