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  • 1
    Publication Date: 2021-07-04
    Description: First reported in the 1960s, offshore freshened groundwater (OFG) has now been documented in most continental margins around the world. In this review we compile a database documenting OFG occurrences and analyze it to establish the general characteristics and controlling factors. We also assess methods used to map and characterize OFG, identify major knowledge gaps, and propose strategies to address them. OFG has a global volume of 1 × 106 km3; it predominantly occurs within 55 km of the coast and down to a water depth of 100 m. OFG is mainly hosted within siliciclastic aquifers on passive margins and recharged by meteoric water during Pleistocene sea level lowstands. Key factors influencing OFG distribution are topography‐driven flow, salinization via haline convection, permeability contrasts, and the continuity/connectivity of permeable and confining strata. Geochemical and stable isotope measurements of pore waters from boreholes have provided insights into OFG emplacement mechanisms, while recent advances in seismic reflection profiling, electromagnetic surveying, and numerical models have improved our understanding of OFG geometry and controls. Key knowledge gaps, such as the extent and function of OFG, and the timing of their emplacement, can be addressed by the application of isotopic age tracers, joint inversion of electromagnetic and seismic reflection data, and development of three‐dimensional hydrological models. We show that such advances, combined with site‐specific modeling, are necessary to assess the potential use of OFG as an unconventional source of water and its role in sub‐seafloor geomicrobiology.
    Description: Plain Language Summary: This review paper considers offshore freshened groundwater (OFG), which is water hosted in sediments and rocks below the seafloor, with a total dissolved solid concentration lower than seawater. We have compiled 〉300 records to demonstrate that freshened groundwater occurs offshore on most continents around the world and has a global volume of 1 × 106 km3. The majority of OFG was deposited when sea level was lower than today and is hosted in sandy sub‐seafloor layers that are located within 55 km of coasts in water depths less than 100 m. We present a range of geochemical, geophysical, and modeling approaches that have successfully been used to investigate OFG systems. We also propose approaches to address key scientific questions related to OFG, including whether it may be used as an unconventional source of potable water in coastal areas.
    Description: Key Points: Most known OFG is located at water depths of 〈100 m within 55 km of the coast, hosted in siliciclastic aquifers in passive margins. Key gaps in knowledge include the extent and function of OFG systems, as well as the mechanism and timing of emplacement. Isotopic tracers, jointly inverted geophysical data and 3‐D hydrological models can help address these knowledge gaps.
    Description: EC | H2020 | H2020 Priority Excellent Science | H2020 European Research Council (ERC) http://dx.doi.org/10.13039/100010663
    Description: National Science Foundation (NSF) http://dx.doi.org/10.13039/100000001
    Keywords: 551 ; offshore freshened groundwater ; continental margin ; marine hydrogeology ; geochemistry ; geophysics ; modeling
    Type: article
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  • 2
    Publication Date: 2022-04-04
    Description: Focused fluid flow shapes the evolution of marine sedimentary basins by transferring fluids and pressure across geological formations. Vertical fluid conduits may form where localized overpressure breaches a cap rock (permeability barrier) and thereby transports overpressured fluids towards shallower reservoirs or the surface. Field outcrops of an Eocene fluid flow system at Pobiti Kamani and Beloslav Quarry (ca 15 km west of Varna, Bulgaria) reveal large carbonate‐cemented conduits, which formed in highly permeable, unconsolidated, marine sands of the northern Tethys Margin. An uncrewed aerial vehicle with an RGB sensor camera produces ortho‐rectified image mosaics, digital elevation models and point clouds of the two kilometre‐scale outcrop areas. Based on these data, geological field observations and petrological analysis of rock/core samples, fractures and vertical fluid conduits were mapped and analyzed with centimetre accuracy. The results show that both outcrops comprise several hundred carbonate‐cemented fluid conduits (pipes), oriented perpendicular to bedding, and at least seven bedding‐parallel calcite cemented interbeds which differ from the hosting sand formation only by their increased amount of cementation. The observations show that carbonate precipitation likely initiated around areas of focused fluid flow, where methane entered the formation from the underlying fractured subsurface. These first carbonates formed the outer walls of the pipes and continued to grow inward, leading to self‐sustaining and self‐reinforcing focused fluid flow. The results, supported by literature‐based carbon and oxygen isotope analyses of the carbonates, indicate that ambient seawater and advected fresh/brackish water were involved in the carbonate precipitation by microbial methane oxidation. Similar structures may also form in modern settings where focused fluid flow advects fluids into overlying sand‐dominated formations, which has wide implications for the understanding of how focusing of fluids works in sedimentary basins with broad consequences for the migration of water, oil and gas.
    Description: Integrated School of Ocean Sciences (ISOS) Kiel
    Description: European Union’s Horizon 2020 http://dx.doi.org/10.13039/100010661
    Description: Bulgarian Science Fund
    Keywords: ddc:551
    Language: English
    Type: doc-type:article
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