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  • structural mechanism  (1)
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    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 38 (1992), S. 131-139 
    ISSN: 1572-8943
    Keywords: amorphous solids ; crystalline ; structural mechanism
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Zusammenfassung Es werden Strukturmechanismen von internen thermischen Reaktionen von Dehydratation und Dehydroxylierung sowie der Kristallisierung der entstehenden amorphen Reaktionsprodukte betrachtet. Dabei handelt es sich um mehrstufige Prozesse, die über kleine translative Verschiebungen von polimerisierten Elementen des Anionennetzwerkes und durch Diffusionsverschiebung von Kationen ablaufen. Dies ist der Weg zum Gleichgewichtszustand mit dem geringsten Energieverbrauch und der niedrigsten, zu überwindenden Energiebarriere.
    Notes: Abstract Structural mechanism of the internal thermal reactions of dehydration and dehydroxylation as of solids well as crystallization of their amorphous products and glasses are considered. They are multi-stage processes, realized through small translative displacements of polymerized anion network elements and diffusional shift of cations. It is the way to equilibrium state of the lowest energy consumption and the least energetic barrier to overcome.
    Type of Medium: Electronic Resource
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