ISSN:
0887-624X
Keywords:
polyether
;
polyester
;
aryl ether
;
nucleophilic substitution
;
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Arene-iron chemistry was applied in the synthesis of a novel liquid crystalline polymer. The chemistry, which is based on iron cyclopentadienyl (FeCp) arene complexes, allows sequential nucleophilic substitution of the chlorides from 1,3-dichlorobenzene-FeCp complex and photolytic decomplexation of the products to afford asymmetrical aryl ethers. This methodology provides easy access to novel polyether-esters, and is potentially useful in the synthesis of various functional polyarylates. © 1997 John Wiley & Sons, Inc.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
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