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  • Severe storms - Forecasting.  (1)
  • porous carbons  (1)
  • 1
    Online Resource
    Online Resource
    Cambridge :Cambridge University Press,
    Keywords: Severe storms - Forecasting. ; Electronic books.
    Description / Table of Contents: This book covers important research issues related to high-impact weather and extreme climate events, and examines the dynamical linkages between these and various atmospheric and ocean phenomena. Highlighting recent research and new advances in the field, this timely volume is ideal for professionals, policymakers, graduate students and academic researchers.
    Type of Medium: Online Resource
    Pages: 1 online resource (404 pages)
    Edition: 1st ed.
    ISBN: 9781316469248
    Series Statement: Special Publications of the International Union of Geodesy and Geophysics Series ; v.Series Number 2
    DDC: 551.55
    Language: English
    Note: Cover -- Half-title -- Series information -- Title page -- Copyright information -- Table of contents -- Preface -- Acknowledgments -- List of contributors -- Part I Diagnostics and prediction of high-impact weather -- 1 Global prediction of high-impact weather: diagnosis and performance -- 1.1 Introduction -- 1.2 Global NWP: how it is done today -- 1.3 The need for dynamical understanding: getting things right for the right reasons -- 1.4 The need for uncertainty information: assessing the degree of confidence -- 1.5 Summary -- 1.6 Opportunities for further progress -- References -- 2 Severe weather diagnosis from the perspective of generalized slantwise vorticity development -- 2.1 Introduction -- 2.2 Generalized slantwise vorticity development -- 2.2.1 Revisiting slantwise vorticity development -- 2.2.2 Diabatic vorticity development -- Impacts on vertical vorticity development of the vertical non-uniformity of diabatic heating -- Impacts on vertical vorticity development of the horizontal non-uniformity of diabatic heating -- 2.2.3 Adiabatic vorticity development -- Slantwise vorticity development on a sloping isentropic surface -- Slantwise vorticity development from a Lagrangian perspective -- Vorticity development (VD) -- Slantwise vorticity development (SVD) -- Relationship between PV2PV2 and SVD -- 2.3 Application of generalized slantwise vorticity development -- 2.3.1 Data and computational method -- Data -- Computational method -- 2.3.2 Description of the TPV in 2008 -- Track of the TPV and associated precipitation -- Large-scale circulation associated with the TPV -- 2.3.3 Diabatic vorticity development due to inhomogeneous heating -- Relative contributions to vertical vorticity development of the changes in PVePVe, PV2PV2, and thetazthetaz -- Effect of the vertical gradient of diabatic heating. , Effect of the horizontal gradient of diabatic heating -- 2.3.4 Adiabatic vorticity development due to slantwise vorticity development -- 2.4 Discussion and conclusions -- References -- 3 Probabilistic extreme event attribution -- 3.1 Introduction -- 3.2 Concepts -- 3.2.1 Weather versus climate -- 3.2.2 Risk versus probability -- 3.2.3 Metrics of attributable risk -- Risk ratio (RR) -- Fraction of attributable risk (FAR) -- Fraction of attributable increase and decrease in risk (FAIR and FADR) -- 3.2.4 Atmosphere-only modelling approaches -- Targeted probabilistic extreme event attribution -- Systematic probabilistic extreme event attribution -- 3.2.5 Coupled atmosphere-ocean modelling approaches -- 3.3 Examples: seasonal-mean extremes -- 3.3.1 Hot season -- 3.3.2 Flood -- 3.4 Current issues -- 3.4.1 Selection bias -- 3.4.2 Computational constraints -- 3.5 Summary -- References -- 4 Observed and projected changes in temperature and precipitation extremes -- 4.1 Introduction -- 4.2 Statistical characterization of extremes -- 4.2.1 Extreme value analysis -- 4.2.2 Estimation of trends -- 4.2.3 Detection and attribution -- 4.3 Temperature extremes -- 4.3.1 Observed changes -- 4.3.2 Understanding the causes -- 4.3.3 Future changes -- 4.4 Precipitation extremes -- 4.4.1 Observed changes -- 4.4.2 Understanding the causes -- 4.4.3 Future changes -- 4.5 Summary and discussion -- References -- Part II High-impact weather in mid latitudes -- 5 Rossby wave breaking: climatology, interaction with low-frequency climate variability, and links to extreme weather events -- 5.1 Introduction -- 5.2 Rossby wave breaking: definition and upper-level signature -- 5.3 Climatological occurrence of RWB and link to patterns of low-frequency variability -- 5.3.1 Climatological occurrence of RWB -- 5.3.2 RWB and patterns of low-frequency variability -- 5.4 RWB and surface weather. , 5.5 Link to high-impact weather events -- References -- 6 The influence of jet stream regime on extreme weather events -- 6.1 Introduction -- 6.2 Dynamical regimes of the large-scale circulation -- 6.3 Methods -- 6.3.1 Diagnostics of extreme events -- 6.3.2 The idealized models -- 6.4 The relation between jet stream type and the distribution and evolution of extreme weather events -- 6.4.1 Observed extreme upper level cyclonic vorticity events -- 6.4.2 Extreme events in the idealized models -- 6.4.3 The distribution of observed extreme temperature anomalies -- 6.5 Discussion -- 6.6 Acknowledgments -- References -- 7 Forecasting high-impact weather using ensemble prediction systems -- 7.1 Introduction -- 7.2 Quantifying uncertainty -- 7.2.1 An ideal ensemble prediction system -- 7.2.2 Initial condition uncertainty -- 7.2.3 Uncertainty due to model error -- 7.3 Practical ensemble prediction systems -- 7.3.1 Global EPS -- 7.3.2 Convective-scale EPS -- 7.4 Probabilistic forecast verification -- 7.4.1 Proper scoring rules -- 7.4.2 Proper score decomposition -- 7.5 Calibration and postprocessing -- 7.5.1 Postprocessing for extremes -- 7.6 Communicating uncertainty -- 7.7 Conclusion -- 7.8 Acknowledgements -- References -- 8 Storm tracks, blocking, and climate change: a review -- 8.1 Introduction -- 8.2 Climate models and a historical perspective -- 8.3 Mechanisms causing storm track change -- 8.4 Storm track projections -- 8.5 Blocking changes -- 8.6 Outlook -- References -- 9 The North Atlantic and Arctic Oscillations: climate variability, extremes, and stratosphere-troposphere interaction -- 9.1 What is the North Atlantic Oscillation and how is it related to the Arctic Oscillation? -- 9.2 The NAO as a governor of extreme weather -- 9.3 Degeneracy in the response to different drivers -- 9.4 Chaotic 'noise' or predictable signal? -- 9.5 Summary. , References -- Part III Tropical cyclones -- 10 Opportunities and challenges in dynamical and predictability studies of tropical cyclone events -- 10.1 Introduction -- 10.2 Extended-range predictions of western North Pacific tropical cyclone events -- 10.3 Extended-range predictions of Atlantic tropical cyclone events -- 10.4 Seasonal prediction of Atlantic tropical cyclone events -- 10.5 Seasonal forecasts for western North Pacific tropical cyclone events -- 10.6 Concluding remarks -- 10.7 Acknowledgments -- References -- 11 Predictability of severe weather and tropical cyclones at the mesoscales -- 11.1 Introduction -- 11.2 Mesoscale predictability of mid-latitude winter snowstorms and moist baroclinic waves -- 11.3 Mesoscale predictability of warm season severe weather events -- 11.4 Mesoscale predictability of tropical cyclones -- 11.5 Concluding remarks -- References -- 12 Dynamics, predictability, and high-impact weather associated with the extratropical transition of tropical cyclones -- 12.1 Introduction -- 12.2 Physical processes -- 12.2.1 Extratropical transition -- 12.2.2 Impacts on the mid-latitude circulation -- 12.2.3 Downstream development -- 12.3 Predictability -- 12.4 Recurving TC Oscar and extreme weather downstream over North America -- 12.4.1 Overview and life cycle -- 12.4.2 Tropical cyclone-extratropical flow interaction -- 12.4.3. Downstream flow reconfiguration -- 12.4.4 Possible role of low-frequency tropical forcing -- 12.4.5 Predictability associated with TY Oscar -- 12.5 Summary and future directions -- 12.6 Acknowledgments -- References -- 13 Secondary eyewall formation in tropical cyclones -- 13.1 Introduction -- 13.2 Environmental conditions -- 13.3 Internal mechanisms of SEF -- 13.3.1 Vortex Rossby waves -- 13.3.2 Axisymmetrization process -- 13.3.3 Beta-skirt axisymmetrization formation hypothesis. , 13.3.4 Unbalanced boundary layer dynamics near the top of the TC boundary layer -- 13.3.5 Balanced response to diabatic heating in a region of enhanced inertial stability -- 13.4 Concluding remarks -- 13.5 Acknowledgment -- References -- 14 Seasonal forecasting of floods and tropical cyclones -- 14.1 Introduction -- 14.2 Seasonal forecasting -- 14.3 POAMA and the Beijing floods of 21 July 2012 -- 14.4 May 2010 POAMA forecast -- 14.5 Tropical cyclones during the 2010/2011 rainy season -- 14.6 Cyclone Yasi -- 14.7 Downscaling -- 14.8 Summary and conclusion -- References -- Part IV Heat waves and cold-air outbreaks -- 15 European heat waves: the effect of soil moisture, vegetation, and land use -- 15.1 Introduction -- 15.2 Climatology of European heat waves -- 15.3 Dynamical processes -- 15.4 Surface hydrology -- 15.5 Soil moisture - climate feedback -- 15.6 Mesoscale effects -- 15.7 Vegetation and land-use change effects -- 15.8 Concluding remarks -- References -- 16 Western North American extreme heat, associated large-scale synoptic-dynamics, and performance by a climate model -- 16.1 Introduction -- 16.2 California heat waves: upper air large-scale meteorological patterns (LSMPs) synoptics and dynamics -- 16.3 LSMPs as a predictor of surface extreme heat -- 16.4 How well are LSMPs captured by a climate model? -- 16.5 Conclusions -- 16.6 Acknowledgments -- References -- 17 Decadal to interdecadal variations of northern China heat wave frequency: impact of the Tibetan Plateau snow cover -- 17.1 Introduction -- 17.2 Data, model, and methodology -- 17.3 The China HWF and TPSC -- 17.4 Physical mechanisms -- 17.5 Conclusion and discussion -- 17.6 Acknowledgments -- References -- 18 Global warming targets and heat wave risk -- 18.1 Introduction -- 18.2 Data -- 18.3 Results -- 18.4 Plausibility of the upper estimates. , 18.5 Role of soil drying on range of regional warming.
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  • 2
    ISSN: 1572-8757
    Keywords: porous carbons ; activation ; oxidation ; surface oxygen groups ; LTPD
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Physics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Abstract A styrene/divinylbenzene copolymer has been used as precursor for making porous carbons with bimodal pore size distributions (i.e., with both microporosity and mesoporosity). Pretreatment of the as-received copolymer by mild oxidation in air, significantly increased the carbon yield after carbonization. Reactivity studies of the polymer-based chars to CO2 clearly show the influences of some important factors such as carbonization temperature, heating rate, soak time on char reactivities. Bimodal porous carbons were prepared by carbonization of the preoxidized styrene/divinylbenzene copolymer in N2, followed by activation in CO2 at different temperatures to different levels of burnoff. The pore structures of the porous carbons produced have been characterized by various techniques such as gas adsorption and mercury porosimetry. The surfaces of the porous carbons produced, and a commercial carbon adsorbent, have been modified with HNO3 and H2O2 treatment at various conditions. Characterization of the surface oxygen functionality, both quantitatively and qualitatively, has been achieved using techniques such as Linear Temperature Programed Desorption (LTPD) and selective neutralization of bases.
    Type of Medium: Electronic Resource
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